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Full-Text Articles in Applied Mechanics

Advanced Materials Design Using Application-Based Processing Techniques, Daniel S. Camarda Oct 2021

Advanced Materials Design Using Application-Based Processing Techniques, Daniel S. Camarda

Doctoral Dissertations

This dissertation pertains to generating advanced materials using application-based processing techniques. First, billets consisting of PTFE sintering powders are evaluated using Thermomechancal Analysis. It was found that both shape change and volume change are associated with enthalpic and entropic recoil, respectively. These phenomena, due to melting and stored energy during the powder compaction process, were found to be molecular weight dependent. Additionally, kinetics of the recovery and sintering process were found to be slower in blended specimens than pure samples. Next, the creation of graft copolymers by selectively grafting a second polymer to the amorphous fraction of a semi-crystalline polymer …


Sensitivity And Uncertainty Quantification Of Continuum And Stochastic Bond Dissociation Kinetics Based Cohesive Laws, Rishabh Awasthi Jan 2020

Sensitivity And Uncertainty Quantification Of Continuum And Stochastic Bond Dissociation Kinetics Based Cohesive Laws, Rishabh Awasthi

Dissertations, Master's Theses and Master's Reports

Polymeric adhesives are being extensively used to develop light weight and durable Composite Materials which are have been employed in automotive, aeronautical, medical industry. Polymeric adhesives undergo failure due to relative opening sliding of bonded interfaces which requires a need to characterize the fracture mechanism. Numerous experiments are conducted to predict the fracture response for Mode-I, II,III and numerical simulations are employed to inversely calibrate the material parameters governing the constitutive laws. Cohesive zone models are largely employed in fracture mechanics to predict failure of interfaces undergoing large plastic deformations. The objective of this report is to employ the cohesive …