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Combined Experimental And Theoretical Studies On Methane Photolysis At 121.6 Nm And 248 Nm- Implications On A Program Of Laboratory Simulations Of Titan’S Atmosphere, C. Romanzin, E. Arzoumanian, Et. Es-Sebbar, A. Jolly, S. Perrier, M.-C. Gazeau, Y. Bénilan Jul 2010

Combined Experimental And Theoretical Studies On Methane Photolysis At 121.6 Nm And 248 Nm- Implications On A Program Of Laboratory Simulations Of Titan’S Atmosphere, C. Romanzin, E. Arzoumanian, Et. Es-Sebbar, A. Jolly, S. Perrier, M.-C. Gazeau, Y. Bénilan

Dr. Et-touhami Es-sebbar

Methane is, together with N2, the main precursor of Titan’s atmospheric chemistry. In our laboratory, we are currently developing a program of laboratory simulations of Titan’s atmosphere, where methane is intended to be dissociated by multiphotonic photolysis at 248 nm. A preliminary study has shown that multiphotonic absorption of methane at 248 nm is efficient and leads to the production of hydrocarbons such as C2H2 (Romanzin et al., 2008). Yet, at this wavelength, little is known about the branching ratios of the hydrocarbon radicals (CH3, CH2 and CH) and their following photochemistry. This paper thus aims at investigating methane photochemistry …


Effects Of Multiple Scattering And Surface Albedo On The Photochemistry Of The Troposphere, Tommy Reinhold Robert Augustsson Apr 1981

Effects Of Multiple Scattering And Surface Albedo On The Photochemistry Of The Troposphere, Tommy Reinhold Robert Augustsson

Mechanical & Aerospace Engineering Theses & Dissertations

A one-dimensional photochemical model of the troposphere containing the species of the nitrogen, oxygen, carbon, hydrogen, and sulfur families has been developed and used to investigate the vertical profiles and the natural (including atmospheric chemical reactions) and anthropogenic sources and sinks of these species. The species continuity equations are solved numerically applying prescribed boundary conditions. The vertical flux is simulated by use of the parameterized eddy diffusion coefficients. Heterogeneous losses (e.g. rainout, gas-to-particle chemistry, and dry deposition), are parameterized to make calculated profiles consistent with measurements. The photochemical model is coupled to a radiative transfer model that calculates the radiation …