Mechanical Engineering Commons^™

Predictive Computational Materials Modeling With Machine Learning: Creating The Next Generation Of Atomistic Potential Using Neural Networks, Mashroor Shafat Nitol

Theses and Dissertations

Machine learning techniques using artificial neural networks (ANNs) have proven to be effective tools to rapidly mimic first principles calculations. These tools are capable of sub meV/atom accuracy while operating with linear scaling with respect to the system size. Here novel interatomic potentials are constructed based on the rapid artificial neural network (RANN) formalism. This approach generates precise force fields for various metals that have historically been difficult to describe at the atomic scale. These force fields can be utilized in molecular dynamics simulations to provide new physical insights. The RANN formalism, which is incorporated into a LAMMPS molecular dynamics …

Development Of Superior Energy Absorbing Devices With Adaptive Capabilities Utilizing Hybrid Cutting/Clamping Deformation Modes, John Magliaro

Electronic Theses and Dissertations

The primary objective of this research was to investigate cutting deformation modes, employing higher-bladed cutters (i.e. 6 or more evenly space blades), with an emphasis on superior energy absorbing capabilities in comparison to axial crushing, the current state-of-the-art. A series of test cases involving AA6061 extrusions were identified utilizing analytical models of the steady-state cutting force and mean crushing force and selecting geometries where the ratio of the former force normalized with respect to the latter exceeded unity. Quasi-static testing confirmed that the total energy absorbing capacity could be exceeded while simultaneously reducing the peak force under quasi-static loading for …

Development Of Superior Energy Absorbing Devices With Adaptive Capabilities Utilizing Hybrid Cutting/Clamping Deformation Modes, John Magliaro

Electronic Theses and Dissertations

The primary objective of this research was to investigate cutting deformation modes, employing higher-bladed cutters (i.e. 6 or more evenly space blades), with an emphasis on superior energy absorbing capabilities in comparison to axial crushing, the current state-of-the-art. A series of test cases involving AA6061 extrusions were identified utilizing analytical models of the steady-state cutting force and mean crushing force and selecting geometries where the ratio of the former force normalized with respect to the latter exceeded unity. Quasi-static testing confirmed that the total energy absorbing capacity could be exceeded while simultaneously reducing the peak force under quasi-static loading for …

Reducing Corrosion Of Additive Manufactured Magnesium Alloys By Interlayer Ultrasonic Peening, M. P. Sealy, R. Karunakaran, S. Ortgies, G. Madireddy, A. P. Malshe, K. P. Rajurkar

Department of Mechanical and Materials Engineering: Faculty Publications

Additive manufad (AM) magn alloys corrode rapidly due to tensile stress and coarse microstructures. Cyclically combining (hybridizing) additive manufacturing with interlayer ultrasonic peening was proposed as a solution to improve corrosion resistance of additive manufactured magnesium WE43 alloy through strengthening mechanisms and compressive residual stress. Applying interlayer peening work hardened discrete layers and formed a glocal integrity of regional grain refinement and subsurface compressive residual stress barriers. Tensile residual stress that typically accelerates corrosion decreased 90%. Results showed time-resolved control over corrosion was attainable by interlayer peening, and local corrosion within print cells decreased 57% with respect to as-printed WE43.

Additive Manufacturing Of Magnesium Alloys, Rakeshkumar Karunakaran, Sam Ortgies, Ali Tamayol, Florin Bobaru, Michael P. Sealy

Department of Mechanical and Materials Engineering: Faculty Publications

Magnesium alloys are a promising new class of degradable biomaterials that have a similar stiffness to bone, which minimizes the harmful effects of stress shielding. Use of biodegradable magnesium implants eliminates the need for a second surgery for repair or removal. There is a growing interest to capitalize on additive manufacturing's unique design capabilities to advance the frontiers of medicine. However, magnesium alloys are difficult to 3D print due to the high chemical reactivity that poses a combustion risk. Furthermore, the low vaporization temperature of magnesium and common biocompatible alloying elements further increases the difficulty to print fully dense structures …

In Silico Analysis Of Advanced Processing Methods For Light-Weight Alloys Powders, Marjan Nezafati

Theses and Dissertations

Light-weight Al and Mg-based metal-matrix nanocomposites (MMNCs) are lauded as one of the most promising structural materials for vehicle, military, and construction applications. These MMNCs are often synthesized using the powder metallurgy (PM) process under liquid nitrogen cryogenic environments to control the grain sizes. It is believed that proper incorporation of the nitrogen species into the bulk lattice during processing could strongly enhance the mechanical properties of MMNCs by forming N-rich dispersoids. In this work, using the density-functional theory (DFT), the adsorption, absorption and diffusion behavior of nitrogen molecule/atoms have been studied and related to t Al and Mg MMNC …

Interface Structure And Deformation Mechanisms Of Mg/Nb Multilayers, Xinyan Xie

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Magnesium (Mg) and its alloys, as the lightest structural materials, are very attractive for a range of weight sensitive applications, such as aircraft engine, transportation industry and so on. However, their further applications are limited due to the weak properties, such as the low strength and poor ductility. In recent years, advanced techniques aiming at the modification of the microstructures, have been developed to promote the properties of Mg and its alloys, such as modifying the texture, refining the grain size, forming the intermetallic phase, and introducing the interfaces or stacking faults into the systems. Constructing Mg/Nb multilayers, which introduces …

Evolution Of Mg Az31 Twin Activation With Strain: A Machine Learning Study, Andrew D. Orme

Undergraduate Honors Theses

Machine learning is being adopted in various areas of materials science to both create predictive models and to uncover correlations which reveal underlying physics. However, these two aims are often at odds with each other since the resultant predictive models generally become so complex that they can essentially be described as a black box, making them difficult to understand. In this study, complex relationships between microstructure and twin formation in AZ31 magnesium are investigated as a function of increasing strain. Supervised machine learning is employed, in the form of J-48 decision trees. In one approach, strain is incorporated as an …

Modifying Burning Rate And Agglomeration Size In Aluminized Composite Solid Propellants Using Mechanically Activated Metals, Hatem Mohamed Belal

Open Access Dissertations

Agglomeration reduction techniques are important field in solid propellant industry, Large agglomeration results in excessive two phase losses. Tailored composite particles has been applied to tailor aluminum particle ignition and combustion. In this research, mechanical activated aluminum magnesium powders are synthesized, tested in both laser ignition using CO2 and propellant. Prepared powders categorized into particle size that suitable for propellant application. Laser ignition tests showed that the prepared powder are more reactive than magnalium which has the same Al:Mg weight ratio. Agglomeration capturing showed that the prepared powder produce much less than neat aluminum or even similar physical mixture of …

Pulsed Laser Cutting Of Magnesium-Calcium For Biodegradable Stents, M. P. Sealy, Y. B. Guo, J. F. Liu, C. Li

Department of Mechanical and Materials Engineering: Faculty Publications

There is growing interests in the use of biodegradable magnesium implants for cardiovascular and pulmonary applications such as stents. Magnesium is a metal that has the ability to gradually dissolve and absorb into the human body after implantation. There is very little work discussing the relationship between process parameters and cut quality of magnesium stents by laser cutting. The objective of this research is to determine the effect of laser cutting conditions including peak laser power and cutting speed of a millisecond range pulsed laser on kerf geometry, surface topography, surface roughness, and microstructure. An assessment on the experimental work …

Magnesium-Based Combustion Synthesis Of Advanced Materials For Energy And Space Applications, Armando Delgado

Open Access Theses & Dissertations

As energy problems become more challenging, interest in low-energy-consuming methods for the fabrication of materials increases. Combustion synThesis is one such method because it is sustained by reaction heat release instead of external energy input. In the present work, combustion synThesis approaches are applied to the production of construction materials from lunar and Martian regolith and to the fabrication of magnesium silicide (Mg2Si), a promising thermoelectric material for high-temperature applications. In both cases, magnesium (Mg) was used as one of the main reactants and similar experimental approaches were employed.

Recently, it has been proposed to use combustion of lunar regolith …

Deformation Twin Nucleation And Growth Characterization In Magnesium Alloys Using Novel Ebsd Pattern Analysis And Machine Learning Tools, Travis Michael Rampton

Theses and Dissertations

Deformation twinning in Magnesium alloys both facilitates slip and forms sites for failure. Currently, basic studies of twinning in Mg are facilitated by electron backscatter diffraction (EBSD) which is able to extract a myriad of information relating to crystalline microstructures. Although much information is available via EBSD, various problems relating to deformation twinning have not been solved. This dissertation provides new insights into deformation twinning in Mg alloys, with particular focus on AZ31. These insights were gained through the development of new EBSD and related machine learning tools that extract more information beyond what is currently accessed.The first tool relating …

Increasing Power Density Of Lsgm-Based Solid Oxide Fuel Cells Using New Anode Materials, Kevin Huang, Jen-Hau Wan, John Goodenough

Kevin Huang

Chemical reactions between the superior perovskite oxide-ion conductor Sr- and Mg-doped LaGaO3 (LSGM), CeO2, and NiO have been studied by powder X-ray diffraction. The results showed that an extensive reactivity occurs as a result of La migration driven by a gradient of La chemical activity. La migration across the LSGM/electrode interfaces in a fuel cell leads to the formation of resistive phases at the interface, either LaSrGa3O7 or LaSrGaO4. Use of 40 mol % La2O3 -doped CeO2 as an interlayer between anode and electrolyte as well as in the NiO-containing anode prevents all reactions found. Consequently, the air-H2 cell maximum …

Corrosion Assessment And Enhanced Biocompatibility Analysis Of Biodegradable Magnesium-Based Alloys, Luis Enrique Pompa

Theses and Dissertations - UTB/UTPA

Magnesium alloys have raised immense interest to many researchers because of its evolution as a new third generation material. Due to their biocompatibility, density, and mechanical properties, magnesium alloys are frequently reported as prospective biodegradable implant materials. Moreover, magnesium based alloys experience a natural phenomena to biodegrade in aqueous solutions due to its corrosive activity, which is excellent for orthopedic and cardiovascular applications. However, major concerns with such alloys are fast and non-uniform corrosion degradation. Controlling the degradation rate in the physiological environment determines the success of an implant. In this investigation, three grades of magnesium alloys: AZ31B, AZ91E and …

Corrosion Of Magnesium And Aluminum In Palm Biodiesel: A Comparative Evaluation

A.S. Md Abdul Haseeb

The present study aims to investigate the comparative corrosion of light-weight metals such as aluminum and magnesium in palm biodiesel. Immersion test at room temperature was carried out for each metal for 1440 h. Sample characterization techniques employed include weight loss measurement, SEM (scanning electron microscope), XRD (X-ray diffraction), TAN (total acid number) and FTIR (Fourier transform infrared spectroscopy). Results showed that the corrosion rate of magnesium was much higher compared to that of aluminum. The surface morphology revealed a significant difference between the biodiesel exposed aluminum and magnesium specimens. Upon exposure to biodiesel, the magnesium surface was found to …

Effect Of Process Parameters On The Weld Quality In Laser Welding Of Az31b Magnesium Alloy In Lap Joint Configuration, Masoud Harooni, Blair Carlson, Radovan Kovacevic

Mechanical Engineering Research

Magnesium is the lightest structural metal; therefore it has been used in a variety of industries such as automotive, aerospace, electronics and defense. Among different joining processes, laser welding is advantageous due to its low heat input, high depth-to-width weld ratio and good mechanical properties. In this study, a fiber laser is used to weld AZ31B magnesium alloy in a lap joint configuration. Pores were formed in the weld bead that are caused by a thick oxide layer existing on the surface of as-received AZ31B samples. Process parameters including laser power and welding speed are studied to determine their effects …

Effect Of Doping On Β-Tricalcium Phosphate Bioresorbable Bulk Material And Thin Film Coatings, Suhaila Abdalla

Dissertations

Magnesium has emerged as a revolutionary biodegradable metal for use as an orthopedic material, it has several advantages over the permanent metallic materials currently in use, including eliminating the effects of stress shielding, improving biocompatibility and degradation properties, thus removing the requirement of a second surgery for implant removal. Due to the rapid degradation of magnesium, it is necessary to control the corrosion rates of the materials to match the rates of bone healing. This dissertation reports on the effect of doping on the properties of β-tricalcium phosphate (β-TCP). It also reports on its application as a thin film coating …

The Composition And Distribution Of Coal-Ash Deposits Under Reducing And Oxidizing Conditions From A Suite Of Eight Coals, David R. Brunner

Theses and Dissertations

Eighteen elements, including: carbon, oxygen, sodium, magnesium, aluminum, silicon, phosphorus, sulfur, chlorine, potassium, calcium, titanium, chromium, manganese, iron, nickel, strontium, and barium were measured using a scanning electron microscope with energy dispersive spectroscopy from deposits. The deposits were collected by burning eight different coals in a 160 kWth, staged, down-fired, swirl-stabilized combustor. Both up-stream and down-stream deposits from an oxidizing region (equivalence ratio 0.86) and reducing region (equivalence ratio 1.15) were collected. Within the deposits, the particle size and morphology were studied. The average particle cross-sectional area from the up-stream deposits ranged from 10 - 75 µm2 and had a …

Combustion Of Lunar Regolith Mixed With Energetic Additives: Thermodynamic Calculations And Experimental Studies, Francisco Alvarez

Open Access Theses & Dissertations

The future of space exploration will require longer missions in order to better understand the conditions of near-Earth celestial objects, like the Moon or Mars. Future space missions will require the development of goods, such as propulsion fuel and structural materials, produced using the extraterrestrial resources available. The area that develops these technologies is called In-Situ Resource Utilization (ISRU). ISRU allows reducing the payload, and as a consequence reduces the energy consumption and cost of space travel. The production of structural materials on the Moon can be accomplished using Self-Propagating High-Temperature Synthesis (SHS). This work describes the combination of ISRU …

Experimental Investigation Of Magnesium/Regolith Combustion For In-Situ Production Of Materials On The Moon, Christopher White

Open Access Theses & Dissertations

Future settlements on the Moon will require that strong, cost-effective structural materials be developed in whole or in part from locally available resources. Such materials can be created in-situ from the lunar regolith using self-propagating high-temperature synthesis (SHS). By mixing the lunar regolith with metal additives, such as aluminum or magnesium, a combustible mixture is formed which, when ignited, can reach temperatures high enough to allow combustion to be self-sustaining, sintering the lunar regolith without further energy input and without the need for atmospheric oxygen. The resulting products may be strong enough for some structural applications, such as radiation shielding, …

Defect Detection Microscopy, Stuart Craig Rogers

Theses and Dissertations

The automotive industry's search for stronger lighter materials has been hampered in its desire to make greater use of Magnesium alloys by their poor formability below 150°C. One current challenge is to identify the complex structure and deformation mechanisms at work and determine which of these are primary contributors to the nucleation of defects. Orientation Imaging Microscopy has been the most accessible tool for microstructural analysis over the past 15 years. However, using OIM to analyze defect nucleation sites requires prior knowledge of where the defects will occur because once the defects nucleate the majority of microstructural information is destroyed. …

An Experimental Investigation Of Friction Bit Joining In Az31 Magnesium And Advanced High-Strength Automotive Sheet Steel, Rebecca Gardner

Theses and Dissertations

Friction Bit Joining (FBJ) is a recently developed spot joining technology capable of joining dissimilar metals. A consumable bit cuts through the upper layer of metal to be joined, then friction welds to the lower layer. The bit then snaps off, leaving a flange. This research focuses on FBJ using DP980 or DP590 steel as the lower layer, AZ31 magnesium alloy as the top layer, and 4140 or 4130 steel as the bit material. In order to determine optimal settings for the magnesium/steel joints, experimentation was performed using a purpose-built computer controlled welding machine, varying factors such as rotational speeds, …

Increasing Power Density Of Lsgm-Based Solid Oxide Fuel Cells Using New Anode Materials, Kevin Huang, Jen-Hau Wan, John B. Goodenough

Faculty Publications

Chemical reactions between the superior perovskite oxide-ion conductor Sr- and Mg-doped LaGaO₃ (LSGM), CeO₂, and NiO have been studied by powder X-ray diffraction. The results showed that an extensive reactivity occurs as a result of La migration driven by a gradient of La chemical activity. La migration across the LSGM/electrode interfaces in a fuel cell leads to the formation of resistive phases at the interface, either LaSrGa₃O₇ or LaSrGaO₄. Use of 40 mol % La₂O₃ -doped CeO₂ as an interlayer between anode and electrolyte as well as in …