Mechanical Engineering Commons^™

Study Of Nanocomposite Materials Using Molecular Dynamics, Prashik Sunil Gaikwad

Dissertations, Master's Theses and Master's Reports

There is an increase in demand for new lightweight structural materials in the aerospace industry for more efficient and affordable human space travel. Polymer matrix composites (PMCs) with reinforcement material as carbon nanotubes (CNTs) have shown exceptional increase in the mechanical properties. Flattened carbon nanotubes (flCNTs) are a primary component of many carbon nanotube (CNT) yarn and sheet materials, which are promising reinforcements for the next generation of ultra-strong composites for aerospace applications. These flCNT/polymer materials are subjected to extreme pressure and temperature during curing process. Therefore there is a need to investigate the evolution of properties during the curing …

Molecular Modeling Of High-Performance Thermoset Polymer Matrix Composites For Aerospace Applications, Prathamesh P. Deshpande

Dissertations, Master's Theses and Master's Reports

The global efforts from major space agencies to transport humans to Mars will require a novel lightweight and ultra-high strength material for the spacecraft structure. Three decades of research with the carbon nanotubes (CNTs) have proved that the material can be an ideal candidate for the composite reinforcement if certain shortcomings are overcome. Also, the rapid development of the polymer resin industry has introduced a wide range of high-performance resins that show high compatibility with the graphitic surface of the CNTs. This research explores the computational design of these materials and evaluates their efficacy as the next generation of aerospace …

Development Of The Carbon Nanotube Thermoacoustic Loudspeaker, Troy Bouman

Dissertations, Master's Theses and Master's Reports

Traditional speakers make sound by attaching a coil to a cone and moving that coil back and forth in a magnetic field (aka moving coil loudspeakers). The physics behind how to generate sound via this velocity boundary condition has largely been unchanged for over a hundred years. Interestingly, around the time moving coil loudspeakers were first investigated the idea of using heat to generate sound was also known. These thermoacoustic speakers heat and cool a thin material at acoustic frequencies to generate the pressure wave (i.e. they use a thermal boundary condition). Unfortunately, when the thermoacoustic principle was initially discovered …

3d Interdigitated Vertically Aligned Carbon Nanotube Electrodes For Electrochemical Impedimetric Biosensing, Benjamin J. Brownlee, Jonathan C. Claussen, Brian D. Iverson

Faculty Publications

Advances in nanomaterials, combined with electrochemical impedance spectroscopy (EIS), have allowed electrochemical biosensors to have high sensitivity while remaining labe-lfree, enabling the potential for portable diagnosis at the point-of-care. We report porous, 3D vertically aligned carbon nanotube (VACNT) electrodes with underlying chromium electrical leads for impedance-based biosensing. The electrodes are characterized by electrode height (5, 25, and 80 μm), gap width (15 and 25 μm), and geometry (interdigitated and serpentine) using scanning electron microscopy, cyclic voltammetry, and EIS. The protein streptavidin is functionalized onto VACNT electrodes for detection of biotin, as confirmed by fluorescence microscopy. EIS is used to measure …

Composite Gel Polymer Electrolytes For Extended Cyclability Of Lithium-Oxygen Batteries, Marcus Carlton Herndon

FIU Electronic Theses and Dissertations

In lithium-oxygen (Li-O₂) batteries, addressing challenges like electrode degradation, cell stability and electrolyte decomposition are key to creating more practical applications. Despite many attempts to minimize anode oxidation and cathode byproduct formation, the electrolyte remains the leading source for rapid capacity fading and poor cyclability in Li-O₂batteries. Understanding the loss of functionality in electrolytes, carbon nanotube (CNT) fillers and redox mediators (RM), during cycling within Li-O₂battery systems, could be the solution to prolonging battery lifetime. Determining the efficiency of these battery components and additives will push the medium towards lifelong, rechargeable and safe battery …

Advanced Techniques For Carbon Nanotube Templated Microfabrication, Jason Matthew Lund

Theses and Dissertations

Carbon nanotube templated microfabrication (CNT-M) is a term describing a grouping of processes where carbon nanotubes (CNTs) serve a structural role in the fabrication of a material or device. In its basic form, CNT-M is comprised of two steps: produce a template made from carbon nanotubes and infiltrate the porous template with an additional material. Vertically aligned carbon nanotube (VACNT) templates can be grown to heights ranging from microns to millimeters and lithographically patterned to a desired form. Deposition of an existing thin film material onto a CNT template will coat all template surfaces and can produce a near solid …

Electrostatically Actuated Double Wall Carbon Nanotubes To Include Intertube Van Der Waals Forces, Ezequiel Juarez Ocanas

Theses and Dissertations

This work deals with the amplitude-frequency and amplitude-voltage responses of parametric and primary resonances of electrostatically actuated double-walled carbon nanotubes (DWCNTs). Nonlinear forces acting on the DWCNT are intertube van der Waals and electrostatic forces. Soft AC excitation and small viscous damping are assumed. In coaxial vibration, the outer and inner carbon nanotubes move together (in-phase), maintaining their geometric concentricity; while in noncoaxial vibration, the CNTs move in opposite direction (out-of-phase). Modal coordinate transformation is formulated. The Harmonic Balance Method (HBM) is used to find the free response solutions of the DWCNT. The Reduced Order Model (ROM) method is also …

Functional Porous Polydimethlysiloxane As Piezoresistive And Piezoelectric Materials, Taissa Rose Michel

Theses and Dissertations

In this paper, polydimethylsiloxane (PDMS), carbon nanotubes (CNTs), and zinc oxide (ZnO) were combined to create functionalized piezoresistive and piezoelectric sensors for pressure sensing and energy harvesting. Samples were foamed to show that the increased deformability of the foam sensors makes them suitable for a range of applications including dexterous robotics, tactile sensing, energy harvesting, and biosensing. Uniform dispersion of CNTs was achieved with chloroform as the solvent. Samples were foamed using chemical blowing and scaffolding but granulated sugar at 70% porosity resulted in foamed samples with the most consistent mechanical properties. Samples underwent tensile and compressive testing for their …

Electrical Properties And Electromagnetic Interference Shielding Effectiveness Of Interlayered Systems Composed By Carbon Nanotube Filled Carbon Nanofiber Mats And Polymer Composites, Claudia A. Ramirez-Herrera, Homero Gonzalez, Felipe De La Torre, Laura Benitez, Jose G. Cabanas-Moreno, Karen Lozano

Mechanical Engineering Faculty Publications and Presentations

The demand for multifunctional requirements in aerospace, military, automobile, sports, and energy applications has encouraged the investigation of new composite materials. This study focuses on the development of multiwall carbon nanotube (MWCNT) filled polypropylene composites and carbon nanofiber composite mats. The developed systems were then used to prepare interlayered composites that exhibited improved electrical conductivity and electromagnetic interference (EMI) shielding efficiency. MWCNT-carbon nanofiber composite mats were developed by centrifugally spinning mixtures of MWCNT suspended in aqueous poly(vinyl alcohol) solutions. The developed nanofibers were then dehydrated under sulfuric acid vapors and then heat treated. Interlayered samples were fabricated using a nanoreinforced …

Cip2a Immunosensor Comprised Of Vertically-Aligned Carbon Nanotube Interdigitated Electrodes Towards Point-Of-Care Oral Cancer Screening, Shaowei Ding, Suprem R. Das, Benjamin J. Brownlee, Kshama Parate, Taylor Davis, Loreen R. Stromberg, Edward K.L. Chan, Joseph Katz, Brian D. Iverson, Jonathan C. Claussen

Faculty Publications

Vertically aligned carbon nanotube array (VANTA) coatings have recently garnered much attention due in part to their unique material properties including light absorption, chemical inertness, and electrical conductivity. Herein we report the first use of VANTAs grown via chemical vapor deposition in a 2D interdigitated electrode (IDE) footprint with a high height-to-width aspect ratio (3:1 or 75:25 µm). The VANTA-IDE is functionalized with an antibody (Ab) specific to the human cancerous inhibitor PP2A (CIP2A)—a alivary oncoprotein that is associated with a variety of malignancies such as oral, breast, and multiple myeloma cancers. The resultant immunosensor is capable of detecting CIP2A …

Functional Optimization Of Carbon Nanotubes, Taylor Davis, Sr. Brian Iverson

Journal of Undergraduate Research

The objective of this project was to create, characterize, and optimize carbon nanotube (CNT) films as a surface functionalization strategy through modifying the growth, infiltration, and patterning during fabrication.

Carbon nanotubes have drawn attention in various disciplines in the scientific community because of their incredible strength, hardness, wettability (hydrophobicity), as well as their kinetic and electrical properties. At BYU specifically, they are being used in diverse applications including fabrication of superhydrophobic surfaces and interdigitated electrode biosensors.

Carbon nanotubes can be delicate with a diameter of only a few nanometers when grown. However, the process of carbon infiltration can be used …

An Experimental Study On Static And Dynamic Strain Sensitivity Of Embeddable Smart Concrete Sensors Doped With Carbon Nanotubes For Shm Of Large Structures, Andrea Meoni, Antonella D'Alessandro, Austin Downey, Enrique García-Macías, Marco Rallini, A. Luigi Materazzi, Luigi Torre, Simon Laflamme, Rafael Castro-Triguero, Filippo Ubertini

Faculty Publications

The availability of new self-sensing cement-based strain sensors allows the development of dense sensor networks for Structural Health Monitoring (SHM) of reinforced concrete structures. These sensors are fabricated by doping cement-matrix mterials with conductive fillers, such as Multi Walled Carbon Nanotubes (MWCNTs), and can be embedded into structural elements made of reinforced concrete prior to casting. The strain sensing principle is based on the multifunctional composites outputting a measurable change in their electrical properties when subjected to a deformation. Previous work by the authors was devoted to material fabrication, modeling and applications in SHM. In this paper, we investigate the …

Advanced Uses For Carbon Nanotubes: A Spherical Sound Source And Hot-Films As Microphones, Micaela M. Thiery

Dissertations, Master's Theses and Master's Reports

Super-aligned carbon nanotube (CNT) thin-film is used to create thermophones. The thermal properties of CNT film allow it to rapidly heat and cool when supplied AC power producing temperature and pressure gradients and, therefore, audible sound. The advantages of CNT thermophones include eliminating all moving components of traditional speakers and reducing the weight of the speaker itself by using CNT film, which is nearly weightless. Additionally, the flexibility of CNT film provides the unique opportunity to construct loudspeakers of various sizes and geometries. In this work, a spherical CNT thermophone is designed, manufactured, and tested for directivity with the overall …

Atomistic And Mesoscopic Simulations Of Heat Transfer Across Heterogeneous Material Interfaces, Sridhar Sadasivam

Open Access Dissertations

The study of heat transfer and the associated thermal interface resistance at heterogeneous material interfaces is over 70 years old since the first measurements of thermal interface resistance by Kapitza in 1941. However, recent developments in experimental metrology techniques that enable spectrally-resolved phonon transport measurements at the nanoscale along with the development of high-fidelity simulation methods have provided a renewed interest in the fundamental physics of heat transfer across interfaces. Miniaturized electronic devices and nanostructured materials for energy applications are among technologies that would benefit from a fundamental understanding of interfacial thermal transport. This dissertation focuses on the study of …

Nonlinear Dynamics Of Electrostatically Actuated Nanotweezers, Bin Liu

Theses and Dissertations

Bin Liu, Nonlinear Dynamics of Electrostatically Actuated Nanotweezers. Master of Science (MS), May 2016, 77 pp, 6 tables, 59 figures, references, 25 titles. The amplitude-frequency response of electrostatic nanotube nanotweezer device system is investigated; soft alter current was setting at near half natural frequency impulse on nanotubes which are referred to as two arms, parametric and primary resonances will be shown in the results, respectively. Firstly we are using the Method of Multiple Scales (MMS) analytical model; results will be compared with Reduced Order Model (ROM). By variation and comparison of multiple parameters including van der wall molecular forces, electrostatic …

Experimental And Numerical Investigation Of Heat Transfer In Cnt Nanofluids

Faculty of Engineering University of Malaya

Nanofluids with their enhanced thermal conductivity are believed to be a promising coolant in heat transfer applications. In this study, carbon nanotube (CNT) nanofluids of 0.01wt%, stabilised by 1.0wt% gum arabic were used as a cooling liquid in a concentric tube laminar flow heat exchanger. The flow rate of cold fluid varied from 10 to 50g/s. Both experimental and numerical simulations were carried out to determine the heat transfer enhancement using CNT nanofluids. Computational fluid dynamics (CFD) simulations were carried out using Fluent v 6.3 by assuming single-phase approximation. Thermal conductivity, density and rheology of the nanofluid were also measured …

Direction Of Slip Detection For A Biomimetic Tactile Sensor, Erik Engeberg, Morteza Vatani, Jae-Won Choi

Dr. Jae-Won Choi

A biomimetic tactile sensor (BTS) is developed from strips of electrically conductive carbon nanotubes (CNTs) mixed in a polymer matrix that is embedded within a flexible polyurethane shell. The mechanical compliance of the BTS is similar to the human fingertip. Experiments are performed which show that the BTS can be used to detect slip and the direction that slip occurs by examining the relative timing among force signals from adjacent strips of CNTs and the frequency content of the force signals. The BTS can also detect forces applied at distinct points on the surface of the BTS.

Electrical Conductivity And Transport Properties Of Gold Decorated Amorphous Carbon Nanotubes/Epoxy Composites

Faculty of Engineering University of Malaya

In this work, chemically synthesized, carboxyl groups functionalized, gold particles hybrid amorphous carbon nanotubes (a-CNT) were characterized. Transmission electron microscopy (TEM) shows that Au/a-CNT hybrid possesses smaller diameter of 10.2 nm than as-synthesized a-CNTs (40 nm). Moreover, even, well-ordered fringes formed on Au/a-CNT hybrid justified successful attachment of Au particles on a-CNT. Impedance plots shows lower resistivity on high Au content's Au/a-CNT hybrid. At the same time, Au/a-CNT hybrids possesses low electrical transference numbers as compared with as-synthesized a-CNTs. Au nanoparticles contribute conducting electrons to Au/a-CNT hybrids and tend to overcome the dominating ionic conduction of a-CNT as Au content …

Functionalization Of Amorphous Carbon Nanotubes For Au Nanoparticles Hybridization

Faculty of Engineering University of Malaya

Our study focuses on selection of nitric acid, sulfuric acid, citric acid, and hydrochloric acid as the most suitable oxidation agent for a-CNT. Nitric acid functionalized a-CNT has the highest value of zeta potential -142.9 mV, followed by H2SO4, citric acids, and HCl functionalized samples of -60.3 mV, -15.9 mV, and -3.2 mV, respectively. High values of zeta potential represents surface charges, which refers to carboxyl groups present on tubes' bodies. At the same time, auric chloride (AuCl3) solution treatment was applied on citric acid, nitric acid, hydrochloric acid, and sulfuric acid treated a-CNT at the same condition. Nitric acid …

Development Of Multifunctional Shape Memory Polymer And Shape Memory Polymer Composites, Sesha Spandana Pulla

Theses and Dissertations--Mechanical Engineering

Shape memory polymers (SMPs) are an emerging class of active polymers that can be used on a wide range of reconfigurable structures and actuation devices. The present study comprehensively examines the unconstrained shape recovery abilities of an epoxy-based SMP. In doing so, epoxy based SMP is synthesized and thermo-mechanically characterized. Results show that the present SMP exhibits excellent shape recoveries under unconstraint conditions, for a range of fixing strains and temperatures. Additionally, the stress-strain behavior of the SMP is determined to be nonlinear, finite deformation at all regions. The strain energy based models have been used to capture the complicate …

Porphyrin Interaction With Dna-Based Carbon Nanotubes And Regeneration For Light Harvesting, Sawyer E. Morgan, Hanyu Zhang, Jong Hyun Choi

The Summer Undergraduate Research Fellowship (SURF) Symposium

Limitations to current solar cells include the high cost of pure silicon and poor current transfer within cells. An emerging alternative is single-walled carbon nanotubes (SWCNTs), which when combined with DNA and porphyrin chromophores can generate a current when absorbing light. We sought to find a chromophore and conditions that would promote bonding to the SWCNTs and improve light harvesting, while being able to regenerate on the film after being damaged. This was experimentally tested by first making SWCNT films on conducting glass slides. These were then functionalized in solutions of chromophore and spectra were measured to determine the bonding …

Nanomaterial-Mediated Biosensors For Monitoring Glucose, Eric S. Mclamore, Masashige Taguchi, Andre Ptitsyn, Jonathan C. Claussen

Jonathan C. Claussen

Real-time monitoring of physiological glucose transport is crucial for gaining new understanding of diabetes. Many techniques and equipment currently exist for measuring glucose, but these techniques are limited by complexity of the measurement, requirement of bulky equipment, and low temporal/spatial resolution. The development of various types of biosensors (eg, electrochemical, optical sensors) for laboratory and/or clinical applications will provide new insights into the cause(s) and possible treatments of diabetes. State-of-the-art biosensors are improved by incorporating catalytic nanomaterials such as carbon nanotubes, graphene, electrospun nanofibers, and quantum dots. These nanomaterials greatly enhance biosensor performance, namely sensitivity, response time, and limit of …

Dna Based Carbon Nanotube Porphyrin Nanohybrids Molecular Recognization And Regeneration, Molly M. Riccitelli, Hanyu Zhang, Jong Hyun Choi

The Summer Undergraduate Research Fellowship (SURF) Symposium

In the search to improve solar cells, scientists are exploring new materials that will provide better current transfer. One material that has emerged as a strong contender is the single walled carbon nanotube (SWNT). Current DNA-SWNT based films combined with chromophores have poor operational lifetimes compared to commercial solar cells. Once exposed to light the chromophore begins to degrade, eventually rendering the solar cell unusable. To solve this problem, we used a method involving multiple steps. First we found which DNA sequences formed structures around the SWNT that could hold the most chromophores by using a spectrophotometer to test the …

Synthesis And Characterization Of Nucleic Acid-Functionalized Nanomaterials, Brianna S. Carroll, Jong Hyun Choi

The Summer Undergraduate Research Fellowship (SURF) Symposium

Motor proteins such as kinesin move along microtubules in order to transport cellular cargos throughout the cell by obtaining energy from RNA hydrolysis which allows the cell to complete the tasks needed to stay alive. In this work, we developed synthetic molecular motors using DNA enzymes (DNAzyme) and fluorescent nanomaterials which mimic the functions and structures of motor proteins. A DNAzyme-capped CdS nanoparticle and a RNA-functionalized single-walled carbon nanotube (SWCNT) were used as a walker and a track in the motor platform, respectively. As a walking mechanism, the DNAzyme cleaved the RNA substrates in the presence of metal cations. The …

Design Exploration And Analysis Of Carbon-Infiltrated Carbon Nanotube Vascular Stents, Darrell John Skousen

Theses and Dissertations

The purpose of this research was to design, develop, and test coronary stent designs composed of carbon-infiltrated carbon nanotubes (CI-CNTs). Coronary stents currently have two major complications: restenosis and thrombosis. CI-CNT stents have potential to address both of these issues, and therefore may provide improved clinical outcomes. CI-CNT stent geometry is patterned using high-resolution photolithography that provide advantages in design possibilities.To develop a coronary stent, a standard design process was followed including: background, design specifications, concept generation, development, analysis, and testing. Background research was first completed and general design specifications for coronary stent performance were compiled. Multiple design concepts were …

Nonlinear Dynamics Of Carbon Nanotubes Under Soft Alternating Current Actuation, Le Luo

Theses and Dissertations - UTB/UTPA

This thesis work deals with electrostatically actuated Carbon Nanotubes (CNTs) cantilevers. Four forces are acting on the CNTs cantilever, namely damping, elastic, electrostatic and van der Waals forces. The van der Waals force is significant for values of 50 nm or lower of the gap between the CNTs and the ground substrate. As both electrostatic and van der Waals forces are nonlinear, and the CNTs electrostatic actuation is given by alternating current (AC) voltage, the CNTs undergo nonlinear parametric dynamics. The Method of Multiple Scales (MMS) and Reduced Order Model (ROM) are employed to investigate the system under soft excitation …

An Exploration Of Carbon-Filled Carbon Nanotubes As A Potential Material In Coronary Stents, Kristopher Neil Jones

Theses and Dissertations

The purpose of this research is to explore the potential of using carbon-infiltrated carbon nanotubes (CI-CNT) as a material for coronary artery stents. Stents are commonly fabricated from metal, which may not perform as well as many polymers and ceramics in biomedical applications. Pyrolytic carbon, a ceramic, is currently used in medical implant devices due to its preferrable biocompatibility properties. Micro-patterned pyrolytic carbon devices can be created by growing carbon nanotubes, and then filling the space between with amorphous carbon via chemical vapor deposition. We prepared multiple samples of two different planar stent-like flexible geometries and smaller cubic structures out …

Nanoenabled Microelectromechanical Sensor For Volatile Organic Chemical Detection, Chiara Zuniga, Matteo Rinaldi, Samuel M. Khamis, A. T. Johnson, Gianluca Piazza

Matteo Rinaldi

A nanoenabled gravimetric chemical sensor prototype based on the large scale integration of single-stranded DNA (ss-DNA) decorated single-walled carbon nanotubes (SWNTs) as nanofunctionalization layer for aluminum nitride contour-mode resonant microelectromechanical (MEM) gravimetric sensors has been demonstrated. The capability of two distinct single strands of DNA bound to SWNTs to enhance differently the adsorption of volatile organic compounds such as dinitroluene (simulant for explosive vapor) and dymethyl-methylphosphonate (simulant for nerve agent sarin) has been verified experimentally. Different levels of sensitivity (17.3 and 28 KHz µm^2/fg) due to separate frequencies of operation (287 and 450 MHz) on the same die have also …

Nano-Particles In Multi-Scale Composites And Ballistic Applications, Jason Gibson

Electronic Theses and Dissertations

Carbon nanotubes, graphene and nano sized core shell rubber particles have all been extensively researched for their capability to improve mechanical properties of thermoset resins. However, there has been a lack of research on their evaluation for energy absorption in high velocity impact scenarios, and the fundamental mechanics of their failure mechanisms during highly dynamic stress transfer through the matrix. This fundamental research is essential for laying the foundation for improvement in ballistic performance in composite armor. In hard armor applications, energy absorption is largely accomplished through delamination between plies of the composite laminate. This energy absorption is accomplished through …

Multiscale Modeling Of Liquid Crystalline/Nanotube Composites, Sharil Patrale

Dissertations, Master's Theses and Master's Reports - Open

The objective of this research is to synthesize structural composites designed with particular areas defined with custom modulus, strength and toughness values in order to improve the overall mechanical behavior of the composite. Such composites are defined and referred to as 3D-designer composites. These composites will be formed from liquid crystalline polymers and carbon nanotubes. The fabrication process is a variation of rapid prototyping process, which is a layered, additive-manufacturing approach. Composites formed using this process can be custom designed by apt modeling methods for superior performance in advanced applications. The focus of this research is on enhancement of Young's …