Mechanical Engineering Commons^™

On The Thermogravimetric Analysis Of Polymers: Polyethylene Oxide Powder And Nanofibers, Oriretan Omosola, Dorina M. Chipara, Mohammed Jasim Uddin, Karen Lozano, Mataz Alcoutlabi, Victoria Padilla-Gainza, Mircea Chipara

Mechanical Engineering Faculty Publications and Presentations

Thermogravimetric analysis of polyethylene oxide (powder and nanofibers obtained by force spinning water or chloroform solutions of polyethylene oxide) was studied using different theoretical models such as Friedman and Flynn-Wall-Ozawa. A semiempirical approach for estimating the “sigmoid activation energy” from the thermal degradation was suggested and confirmed by the experimental data on PEO powder and nanofibers' mats. The equation allowed for calculating a “sigmoid activation energy” from a single thermogram using a single heating rate without requiring any model for the actual complex set of chemical reactions involved in the thermal degradation process. For PEO (powder and nanofibers obtained from …

Influence Of Polyethylene Glycol (Peg) In Cmc-Nh4br Based Polymer Electrolytes: Conductivity And Electrical Study, Nur Khalidah Zainuddin, Ahmad Salihin Samsudin

Makara Journal of Technology

The present work was carried with new type and promising polymer electrolytes system by development of carboxyl methylcellulose (CMC) doped NH4Br and plasticized with polyethylene glycol (PEG). The sample was successfully prepared via solution casting with no separation phase and good mechanical properties. The electrical conductivity and thermal conductivity of CMC-NH4Br-PEG based PEs system have been measured by the electrical impedance spectroscopy method in the temperature range of 303–373 K. The highest ionic conductivity gained is 2.48 x 10-3 Scm-1 at ambient temperature for sample contain with 8 wt. % PEG. It can be concluded that the plasticized is accountable …

Sr3<−3xNa3xSi3O9−1.5x (X = 0.45) As A Superior Solid Oxide-Ion Electrolyte For Intermediate Temperature-Solid Oxide Fuel Cells, Tao Wei, Preetam Singh, Yunhui Gong, John Goodenough, Yunhui Huang, Kevin Huang

Kevin Huang

We here report that a newly discovered superior oxide-ion conductor Sr_3−3xNa_3xSi₃O_9−1.5x (x = 0.45) (SNS) demonstrates full potential to be a practical solid electrolyte for intermediate temperature-solid oxide fuel cells (IT-SOFCs). It exhibits the highest oxide-ion conductivity with the lowest activation energy among all the chemically stable solid oxide-ion conductors reported. The ionic conductivity is stable over a broad range of partial pressures of oxygen (10⁻³⁰ to 1 atm) for an extended period of time. A SOFC based on a 294 μm thick SNS-electrolyte produces peak power densities …

Quantification Of Auto-Ignition In Diesel Engines, Umashankar M. Joshi

Wayne State University Dissertations

Efforts have been made previously by researchers to quantify the auto-ignition quality of fuels by calculating global activation energy using Arrhenius plots with data measured for the ignition delay period (ID). Large variation in the activation energy of fuels has been observed even for fuels with closer CN values. More recently, the activation energy values obtained by Kook et al in (2005) on an optical engine do not agree with data obtained in an identical metallic engine by Jayakumar using fuels of same CN.

The disparity in their results can be attributed to the differences in ignition delay (ID) and …

Sr3<−3xNa3xSi3O9−1.5x (X = 0.45) As A Superior Solid Oxide-Ion Electrolyte For Intermediate Temperature-Solid Oxide Fuel Cells, Tao Wei, Preetam Singh, Yunhui Gong, John B. Goodenough, Yunhui Huang, Kevin Huang

Faculty Publications

We here report that a newly discovered superior oxide-ion conductor Sr_3−3xNa_3xSi₃O_9−1.5x (x = 0.45) (SNS) demonstrates full potential to be a practical solid electrolyte for intermediate temperature-solid oxide fuel cells (IT-SOFCs). It exhibits the highest oxide-ion conductivity with the lowest activation energy among all the chemically stable solid oxide-ion conductors reported. The ionic conductivity is stable over a broad range of partial pressures of oxygen (10⁻³⁰ to 1 atm) for an extended period of time. A SOFC based on a 294 μm thick SNS-electrolyte produces peak power densities …

Energetics And Kinetics Of Dislocation Initiation In The Stressed Volume At Small Scales, Tianlei Li

Doctoral Dissertations

Instrumented nanoindentation techniques have been widely used in characterizing mechanical behavior of materials in small length scales. For defect-free single crystals under nanoindentation, the onset of elastic-plastic transition is often shown by a sudden displacement burst in the measured load-displacement curve. It is believed to result from the homogeneous dislocation nucleation because the maximum shear stress at the pop-in load approaches the theoretical strength of the material and because statistical measurements agree with a thermally activated process of homogeneous dislocation nucleation. For single crystals with defects, the pop-in is believed to result from the sudden motion of pre-existing dislocations or …

The Decompositioning Of Volatile-Matter Of Tanjung Enim Coal By Using Thermogravimetry Analyzer (Tga), Nukman Nukman

Makara Journal of Technology

The Decompositioning of Volatile-Matter of Tanjung Enim Coal by using Thermogravimetry Analyzer (TGA). Coal is a nature material which a kind of energy source. The decompotition of coal could analyze by heat treated using thermogravimetry analyzer. The decomposition of the volatile matter for three kinds of Tanjung Enim coal could be known. The value of activation energy that be found diference, then for Semi Anthracite, Bitumonius and Sub Bituminous Coal, the initial temperatures are 60.8 oC, 70.7 oC, 97.8oC, and the last temperatures are 893.8 oC, 832 oC, 584.6oC.

Modeling Of The Effects Of Athermal Flow Strength And Activation Energy For Dislocation Glide On The Nanoindentation Creep Of Nickel Thin Film At Room Temperature

A.S. Md Abdul Haseeb

Nanoindentation creep behaviour of nickel at room temperature has been modeled based on the obstacle-controlled dislocation glide mechanism. Using the model, the effects of two important materials parameters viz. the activation free energy required by dislocation to overcome an obstacle without any aid from external stress, ΔF and the athermal flow strength, τ0, which is the flow strength of solids at 0 K are systematically studied. It has been found that ΔF plays a dominant role in room temperature creep properties of nickel. The role of ΔF is particularly dominant in determining the time dependent deformation. On the other hand, …

Modeling Of The Effects Of Athermal Flow Strength And Activation Energy For Dislocation Glide On The Nanoindentation Creep Of Nickel Thin Film At Room Temperature

A.S. Md Abdul Haseeb

Nanoindentation creep behaviour of nickel at room temperature has been modeled based on the obstacle-controlled dislocation glide mechanism. Using the model, the effects of two important materials parameters viz. the activation free energy required by dislocation to overcome an obstacle without any aid from external stress, ΔF and the athermal flow strength, τ0, which is the flow strength of solids at 0 K are systematically studied. It has been found that ΔF plays a dominant role in room temperature creep properties of nickel. The role of ΔF is particularly dominant in determining the time dependent deformation. On the other hand, …

Optimal Rate Of Freezing Biological Systems, Sreedhar Thirumala

LSU Master's Theses

This thesis addresses optimization techniques for cryopreservation of biological systems. A part of the thesis (Chapter 2) reports a simplified procedure to predict the optimal rate of freezing biological systems once the cell level parameters are known a priori. The key cell level parameters investigated were, reference permeability of the membrane to water (Lpg), apparent activation energy (ELp), inactive cell volume (Vb), diameter (D), and the ratio of the available surface area for water transport to the initial volume of intracellular water (SA/WV). The simplified procedure was developed by performing a thorough analysis of the water transport model over a …

Thermal Decomposition Study Of Electrodeposited Fe-C And Fe-Ni-C Alloys By Differential Scanning Calorimetry

A.S. Md Abdul Haseeb

Fe-0.96mass%C and Fe-15.4mass%Ni-0.70mass%C alloys with hardness of 810 and 750 HV respectively have been electrodeposited at 50°C from sulphate based baths containing a small amount of citric acid and L-ascorbic acid. Differential scanning calorimetry of the electrodeposited samples has been carried out in the temperature range of 293-725 K in argon atmosphere. Electrodeposited pure Fe is also investigated for comparison purposes. The DSC curves of both alloys contain two exothermic peaks: at about 411 K and 646 K for the Fe-C alloy, and 388 K and 639 K for the Fe-Ni-C alloy. These peaks are irreversible and do not appear …