Mechanical Engineering Commons^™

Design Of Efficient Carbon-Based Adsorbents For The Removal Of Organic And Inorganic Water Contaminants, Sayedeh Soroosh Mortazavian Dehkordi

UNLV Theses, Dissertations, Professional Papers, and Capstones

Granular activated carbon (AC) and biochar (BC) are two carbon-based adsorbents commonly used for water and wastewater treatment. However, these adsorbents have drawbacks that suppress their aqueous contaminants removal efficiency. Their major disadvantages are that AC has low selectivity and reusability potential, and BC has a hydrophobic nature.

The scope of this dissertation is to enhance the performance of commonly-used carbon-based adsorbents for the removal of organic and inorganic water contaminants and to understand the interactive mechanism of contaminants’ ions/molecules with adsorbents. Hexavalent chromium (Cr(VI)) and trichloroethylene (TCE) are two types of inorganic and organic water contaminants, respectively, which are …

Adsorption Of Heavy Metal Ions By Oil Palm Decanter Cake Activated Carbon, Mohd. Ezreeza Mohamed Yusoff, Juferi Idris, Nahrul Hayawin Zainal, Mohamad Faizal Ibrahim, Suraini Abd-Aziz

Makara Journal of Technology

Adsorption processes are widely used for the removal of heavy metals from waste streams. Oil palm decanter cake (OPDC) is used as a bioadsorbent because of its compositional properties for activated carbon production; moreover, it is a readily available raw material produced in palm oil mills and is thus abundant and cheap. In this study, the OPDC was carbonized at 700 °C and activated using steam at 700 °C to produce oil palm decanter cake activated carbon (AC-OPDC). Batch adsorption experiments were carried out to compare the adsorption capacities of the raw OPDC and the AC-OPDC for heavy metals removal. …

Performance Of C2H4 Reductant In Activated-Carbon-Supported Mnox-Based Scr Catalyst At Low Temperatures, Guangli Liu, Dongtai Han, Jie Cheng, Yongshi Feng, Wenbin Quan, Li Yang, Kozo Saito

Mechanical Engineering Faculty Publications

Hydrocarbons as reductants show promising results for replacing NH₃ in SCR technology. Therefore, considerable interest exists for developing low-temperature (< 200 °C) and environmentally friendly HC-SCR catalysts. Hence, C₂H₄ was examined as a reductant using activated-carbon-supported MnOx-based catalyst in low-temperature SCR operation. Its sensitivity to Mn concentration and operating temperature was parametrically studied, the results of which showed that the catalyst activity followed the order of 130 °C > 150 °C > 180 °C with an optimized Mn concentration near 3.0 wt.%. However, rapid deactivation of catalytic activity also occurred when using C₂H₄ as the reductant. The mechanism of deactivation was explored and is …

Activated Carbon Fixed-Bed Adsorber Design For Treating Chromium Hexavalent Wastewater, Tedi Hudaya, Velicia Rachmat

Makara Journal of Technology

Pollution caused by industrial wastewater containing heavy metals is a major issue, primarily due to its toxic nature. A cheap yet effective method to deal with such wastewater is activated carbon adsorption. The purpose of this research is to evaluate and design a fixed bed adsorber with granular activated carbon as an adsorbent to process wastewater-containing chromium hexavalent (Cr 6+). Experiments show that the Langmuir isotherm fits the equilibrium data as effectively as the Freundlich isotherm. Activated carbon used in this research is Jacobi 2000® derived from bituminous coal. The lab scale inlet volumetric flow is 100 mL/h with different …

Adsorption Of Cu(Ii) Ions In Aqueous Solution Onto Limonia Acidissima Shellbased Activated Carbon: Kinetic And Isotherm Studies, Abrar Muslim, Syahiddin Dahlan Said, Gita Suci Hariati, Siti Fajar Karina, Fauzi Muhammad Djuned, Rizka Mulyawan

Makara Journal of Technology

Adsorption of Cu(II) ions from aqueous solution using activated carbon prepared from Limonia acidissima fruit shell (LAFS-AC) was conducted in batch mode experiments at pH 5 (±0.15), 100 rpm and 1 atm. The effects of contact time, initial Cu(II) ions concentration, KOH concentration, and adsorption temperature on Cu(II) ions adsorption capacity were investigated. Fourier Transform Infrared Spectroscopy and Scanning Electron Microscopy analyses were performed to investigate the active site and surface morphology of the LAFS-AC, respectively. The Cu(II) ions adsorption was fitted very well (R2 = 0.94 on average) to the pseudo second-order adsorption kinetic with the adsorption capacity and …

Development Of Bamboo‐Derived Sorbents For Mercury Removal In Gas Phase, Naved Siddiqui, Jarlen Don, Kanchan Mondal, Ajay Mahajan

Dr. Ajay Mahajan

Activated carbon sorbents were synthesized from bamboo precursors by carbonization in an inert atmosphere followed by physiochemical activation with carbon dioxide and finally acidulation in hydrochloric acid. Bamboo strips with and without the epidermal tissue (bark) were used. The morphology and specific surface area changes due to the treatment were analysed. The adsorption characteristics of these sorbents after each stage of treatment were also analysed and the data were correlated to the changes in the physical characteristics of the sorbents. Kinetic studies were conducted on these samples. The adsorption equilibrium and kinetics of elemental mercury adsorption on these carbons were …

Digestibility Of Betung Bamboo Fiber Following Fungal Pretreatment, Widya Fatriasari, Wasrin Syafii, Nyoman J. Wistara, Khaswar Syamsu, Bambang Prasetya

Makara Journal of Technology

This research evaluated the effect of fungal pretreatment of betung bamboo fibers and enzymatic- and microwaveassisted hydrolysis on the reducing sugar yield. The enzymatic hydrolysis of the pretreated biomass was carried out with cellulase and 10 and 20 FPU/g of substrate in a shaking incubator at 50 °C and 150 rpm for 48 h. The sulfuric acid concentration used in the microwave-assisted acid hydrolysis was 1.0, 2.5, and 5%, either with or without the addition of activated carbon. Microwave irradiation (330 Watt) was applied for 5–12.5 min. The yield of reducing sugar was better with the microwave-assisted acid hydrolysis, and …