Mechanical Engineering Commons^™

Solute Concentration Effects On Microstructure And The Compressive Strength Of Ice-Templated Sintered Lithium Titanate, Rohan Parai, Ziyang Nie, Raina Hempley, Gary M. Koenig Jr., Dipankar Ghosh

Mechanical & Aerospace Engineering Faculty Publications

This work investigated the role of sucrose and cationic dispersant (1‐hexadecyl)trimethylammonium bromide concentration on ice‐templated sintered lithium titanate microstructure and compressive strength, to enable a comprehensive understanding of composition selection and elucidate processing–microstructure–mechanical property relationships. Sucrose and dispersant concentrations were varied to change total solute concentration in suspensions and viscosity. Dispersant was more effective in reducing viscosity than sucrose; however, their combination had an even greater impact on reducing viscosity. Based on viscosity measurements, a total of 12 suspension compositions were developed, and materials were fabricated at two different freezing front velocity (FFV) regimes. Solute concentration greatly influenced ice‐templated microstructure …