Open Access. Powered by Scholars. Published by Universities.®
- Discipline
Articles 1 - 3 of 3
Full-Text Articles in Mechanical Engineering
Redox Stable Anodes For Solid Oxide Fuel Cells, Guoliang Xiao, Fanglin Chen
Redox Stable Anodes For Solid Oxide Fuel Cells, Guoliang Xiao, Fanglin Chen
Faculty Publications
Solid oxide fuel cells (SOFCs) can convert chemical energy from the fuel directly to electrical energy with high efficiency and fuel flexibility. Ni-based cermets have been the most widely adopted anode for SOFCs. However, the conventional Ni-based anode has low tolerance to sulfur-contamination, is vulnerable to deactivation by carbon build-up (coking) from direct oxidation of hydrocarbon fuels, and suffers volume instability upon redox cycling. Among these limitations, the redox instability of the anode is particularly important and has been intensively studied since the SOFC anode may experience redox cycling during fuel cell operations even with the ideal pure hydrogen as …
Influence Of Crystal Structure On The Electrochemical Performance Of A-Site-Deficient Sr1-SNb0.1Co0.9O3-Δ Perovskite Cathodes, Yinlong Zhu, Ye Lin, Xuan Shen, Jaka Sunarso, Wei Zhou, Shanshan Jiang, Dong Su, Fanglin Chen, Zongping Shao
Influence Of Crystal Structure On The Electrochemical Performance Of A-Site-Deficient Sr1-SNb0.1Co0.9O3-Δ Perovskite Cathodes, Yinlong Zhu, Ye Lin, Xuan Shen, Jaka Sunarso, Wei Zhou, Shanshan Jiang, Dong Su, Fanglin Chen, Zongping Shao
Faculty Publications
The creation of A-site cation defects within a perovskite oxide can substantially alter the structure and properties of its stoichiometric analogue. In this work, we demonstrate that by vacating 2 and 5% of Asite cations from SrNb0.1Co0.9O3-δ (SNC1.00) perovskites (Sr1-sNb0.1Co0.9O3-δ,s = 0.02 and 0.05; denoted as SNC0.98 and SNC0.95, respectively), a Jahn–Teller (JT) distortion with varying extents takes place, leading to the formation of a modified crystal lattice within a the perovskite framework. Electrical conductivity, electrochemical performance, chemical compatibility and microstructure of Sr1-sNb0.1Co …
The Effect Of Isostatic Pressing On The Dielectric Properties Of Screen Printed Ba0.5Sr0.5Tio3 Thick Films, Siwei Wang, Lingling Zhang, Jiwei Zhai, Fanglin Chen
The Effect Of Isostatic Pressing On The Dielectric Properties Of Screen Printed Ba0.5Sr0.5Tio3 Thick Films, Siwei Wang, Lingling Zhang, Jiwei Zhai, Fanglin Chen
Faculty Publications
Ba0.5Sr0.5TiO3 thick films with B2O3–Li2O glass sintering aid were prepared by the screen printing method on Al2O3 substrates. A 200 MPa isostatic pressure was applied to the films before sintering. After being sintered at 950∘C, lower porosity and denser microstructure was obtained compared with the films without isostatic pressing. The dielectric constant and dielectric loss were 238 and 0.0028, respectively. A tunability of 61.7% was obtained for the isostatic pressed films, a 27.8% enhancement compared to unpressurized films. These results suggest that isostatic pressing …