Mechanical Engineering Commons^™

Chemical And Physical Interaction Mechanisms And Multifunctional Properties Of Plant Based Graphene In Carbon Fiber Epoxy Composites, Daniel W. Mulqueen

Mechanical & Aerospace Engineering Theses & Dissertations

Graphene has generated substantial interest as a filler due to its exceptional strength, flexibility, and conductivity but faces obstacles in supply and implementation. A renewable, plant-based graphene nanoparticle (pGNP) presents a more accessible and sustainable filler with the same properties as mineral graphenes. In this study, the mechanisms of graphene reinforcement in carbon fiber reinforced plastic (CFRP) were examined, along with the resulting improvements to mechanical strength, resistance to crack propagation, electrical and thermal conductivity at elevated temperatures. pGNP, produced from renewable biomass, was shown to have a graphitic structure with flakes 3-10 layers thick and a median lateral size …

Numerical Study Of The Time-Periodic Electroosmotic Flow Of Viscoelastic Fluid Through A Short Constriction Microchannel, Jianyu Ji, Shizhi Qian, Armani Marie Parker, Xiaoyu Zhang

Mechanical & Aerospace Engineering Faculty Publications

Electroosmotic flow (EOF) is of utmost significance due to its numerous practical uses in controlling flow at micro/nanoscales. In the present study, the time-periodic EOF of a viscoelastic fluid is statistically analyzed using a short 10:1 constriction microfluidic channel joining two reservoirs on either side. The flow is modeled using the Oldroyd-B (OB) model and the Poisson-Boltzmann model. The EOF of a highly concentrated polyacrylamide (PAA) aqueous solution is investigated under the combined effects of an alternating current (AC) electric field and a direct current (DC) electric field. Power-law degradation is visible in the energy spectra of the velocity fluctuations …

Electroosmotic Flow Of Viscoelastic Fluid In A Nanochannel Connecting Two Reservoirs, Lanju Mei, Shizhi Qian

Mechanical & Aerospace Engineering Faculty Publications

Electroosmotic flow (EOF) of viscoelastic fluid with Linear Phan-Thien–Tanner (LPTT) constitutive model in a nanochannel connecting two reservoirs is numerically studied. For the first time, the influence of viscoelasticity on the EOF and the ionic conductance in the micro-nanofluidic interconnect system, with consideration of the electrical double layers (EDLs), is investigated. Regardless of the bulk salt concentration, significant enhancement of the flow rate is observed for viscoelastic fluid compared to the Newtonian fluid, due to the shear thinning effect. An increase in the ionic conductance of the nanochannel occurs for the viscoelastic fluid. The enhancement of the ionic conductance is …

Numerical Simulation Of Viscoelastic Flow In Micro/Nanochannels, Lanju Mei

Mechanical & Aerospace Engineering Theses & Dissertations

Micro/Nanofluidic devices often involve use of biological fluids or polymeric solutions that cannot be simply treated as Newtonian fluids. The numerical simulation for the complex fluids at micro/nanoscale presents a significant computational challenge, and the inclusion of electrokinetic body force further increases the complexity. Specifically, the well-known High Weissenberg Number Problem (HWNP) has become a challenge for the numerical simulation of viscoelastic fluid. This dissertation is aimed to develop a numerical tool to simulate the behavior of viscoelastic fluid in the micro/nanochannel. The most popular log-conformation reformulation to solve the HWNP is presented and implemented in a finite volume scheme. …

Numerical Study On The Dynamic Process Of Single Plume Flow In Thermal Convection With Polymers, Jian-Ping Cheng, Wei-Hua Cai, Hong-Na Zhang, Feng-Chen Li, Lian Shen, Shi-Zhi Qian

Mechanical & Aerospace Engineering Faculty Publications

A direct numerical simulation of single plume flow in thermal convection with polymers was carried out in a domain with 1:3 as the width to height ratio. The heat transport ability is weakened by adding polymers within the here-investigated governing parameter range. However, it is promoted when the maximum polymer extension L is increased. The distribution of vertical velocity and temperature indicates that the plume in the polymer solution case is speeded up and widens bigger as compared to that in the Newtonian fluid case. Inside the plume, polymer chains tend to release energy at the position where the …

Electroosmotic Flow Of Viscoelastic Fluid In A Nanoslit, Lanju Mei, Hongna Zhang, Hongxia Meng, Shizhi Qian

Mechanical & Aerospace Engineering Faculty Publications

The electroosmotic flow (EOF) of viscoelastic fluid in a long nanoslit is numerically studied to investigate the rheological property effect of Linear Phan-Thien-Tanner (LPTT) fluid on the fully developed EOF. The non-linear Poisson-Nernst-Planck equations governing the electric potential and the ionic concentration distribution within the channel are adopted to take into account the effect of the electrical double layer (EDL), including the EDL overlap. When the EDL is not overlapped, the velocity profiles for both Newtonian and viscoelastic fluids are plug-like and increase sharply near the charged wall. The velocity profile resembles that of pressure-driven flow when the EDL is …

An Examination Of The Indentation Size Effect In Fcc Metals And Alloys From A Kinetics Based Perspective Using Nanoindentation, David Earl Stegall

Mechanical & Aerospace Engineering Theses & Dissertations

The indentation size effect (ISE) in metals is described as the rise in hardness with decreasing depth of indentation and contradicts conventional plasticity behavior. The goal of this dissertation is to further examine the fundamental dislocation mechanisms that may be contributing to the so-called indentation size effect. In this work, we examined several metals and alloys including 99.999% Aluminum (SFE ~200 mJ/m²), 99.95% Nickel (SFE ~125 mJ/m²), 99.95% Silver (SFE ~22 mJ/m²⁾, and three alloys, alpha brass 70/30 (SFE >10 mJ/m²), 70/30 nickel copper (SFE ~100 mJ/ …

Electrokinetic Phenomena In Pencil Lead-Based Microfluidics, Yashar Bashirzadeh, Venkat Maruthamuthu, Shizhi Qian

Mechanical & Aerospace Engineering Faculty Publications

Fabrication of microchannels and associated electrodes to generate electrokinetic phenomena often involves costly materials and considerable effort. In this study, we used graphite pencil-leads as low cost, disposable 3D electrodes to investigate various electrokinetic phenomena in straight cylindrical microchannels, which were themselves fabricated by using a graphite rod as the microchannel mold. Individual pencil-leads were employed as the micro-electrodes arranged along the side walls of the microchannel. Efficient electrokinetic phenomena provided by the 3D electrodes, including alternating current electroosmosis (ACEO), induced-charge electroosmosis (ICEO), and dielectrophoresis (DEP), were demonstrated by the introduced pencil-lead based microfluidic devices. The electrokinetic phenomena were characterized …

Nano Scale Mechanical Analysis Of Biomaterials Using Atomic Force Microscopy, Diganta Dutta

Mechanical & Aerospace Engineering Theses & Dissertations

The atomic force microscope (AFM) is a probe-based microscope that uses nanoscale and structural imaging where high resolution is desired. AFM has also been used in mechanical, electrical, and thermal engineering applications. This unique technique provides vital local material properties like the modulus of elasticity, hardness, surface potential, Hamaker constant, and the surface charge density from force versus displacement curve. Therefore, AFM was used to measure both the diameter and mechanical properties of the collagen nanostraws in human costal cartilage. Human costal cartilage forms a bridge between the sternum and bony ribs. The chest wall of some humans is deformed …

Role Of Surface Chemistry In Nanoscale Electrokinetic Transport, Secuk Atalay

Mechanical & Aerospace Engineering Theses & Dissertations

This dissertation work presents the efforts to study the electrofluidics phenomena, with a focus on surface charge properties in nanoscale systems with the potential applications in imaging, energy conversion, ultrafiltration, DNA analysis/sequencing, DNA and protein transport, drug delivery, biological/chemical agent detection and micro/nano chip sensors.

Since the ion or molecular or particle transport and also liquid confinement in nano-structures are strongly dominated by the surface charge properties, in regards of the fundamental understanding of electrofluidics at nanoscale, we have used surface charge chemistry properties based on 2-pK charging mechanism. Using this mechanism, we theoretically and analytically showed the surface charge …

Manipulating Particles For Micro- And Nano-Fluidics Via Floating Electrodes And Diffusiophoresis, Sinan Eren Yalcin

Mechanical & Aerospace Engineering Theses & Dissertations

The ability to accurately control micro- and nano-particles in a liquid is fundamentally useful for many applications in biology, medicine, pharmacology, tissue engineering, and microelectronics. Therefore, first particle manipulations are experimentally studied using electrodes attached to the bottom of a straight microchannel under an imposed DC or AC electric field. In contrast to a dielectric microchannel possessing a nearly-uniform surface charge, a floating electrode is polarized under the imposed electric field.

The purpose is to create a non-uniform distribution of the induced surface charge, with a zero-net-surface charge along the floating electrode's surface. Such a field, in turn, generates an …

Direct Current Electrokinetic Particle Transport In Micro/Nano-Fluidics, Ye Ai

Mechanical & Aerospace Engineering Theses & Dissertations

Electrokinetics has been widely used to propel and manipulate particles in micro/nano-fluidics. The first part of this dissertation focuses on numerical and experimental studies of direct current (DC) electrokinetic particle transport in microfluidics, with emphasis on dielectrophoretic (DEP) effect. Especially, the electrokinetic transports of spherical particles in a converging-diverging microchannel and an L-shaped microchannel, and cylindrical algal cells in a straight microchannel have been numerically and experimentally studied. The numerical predictions are in quantitative agreement with our own and other researchers' experimental results. It has been demonstrated that the DC DEP effect, neglected in existing numerical models, plays an important …