Mechanical Engineering Commons^™

Atomic-Scale Analysis Of Solute Segregation Energy Into Grain Boundaries And Polycrystals, Tara Nenninger

Graduate College Dissertations and Theses

Solute segregation in grain boundaries (GBs) is used in design to stabilize nanocrystalline alloys. While analyzing GB segregation energy as a spectrum allows for a more in-depth analysis of the effects of GB atomic structure on solute segregation, this method inherently ignores solute-solute interaction by nature of considering one solute at a time. Here we develop an efficient molecular statics (MS) algorithm for determining the local effect of solute-solute interaction on GB segregation. We apply this algorithm to a Σ9 (221) symmetric tilt grain boundary in a bicrystal as well as a randomly oriented polycrystal for Ni and Cu solutes …

Medical Applications Of Ultrasound: T-Cell Drug Delivery, Osteoporosis Diagnosis, And Biofilm Mitigation, Alina Karki

Graduate College Dissertations and Theses

The ability of ultrasound to localize acoustic energy deposition and induce a biological effect within a target is examined in three novel biomedical applications: sonoporation, osteoporosis diagnosis, and biofilm mitigation.Ultrasound can excite encapsulated microbubbles, causing an acoustic cavitation effect in the vicinity of cells, temporarily increasing membrane permeability, and allowing cells to uptake foreign molecules. This non-viral transfection technique is called sonoporation. Our experimental study demonstrated that it could be effective for small interfering RNA (siRNA) delivery into an isolated mouse and human T-cells, which is a complex process despite its importance in treating numerous diseases. T-cells are non-proliferating, while …

Strengthening Mechanisms In Nanocrystalline Silver-Nickel Nanolayered Materials, Malcolm Ryan Pringle

Graduate College Dissertations and Theses

Among all metals, silver has the highest electrical conductivity but also is one of the softest materials under mechanical deformation. Therefore, developing means and methods for strengthening silver without reducing conductivity is critically important for its use as a conductive electrode material in various engineering applications such as solar cells and touchscreen displays. This thesis presents a molecular-dynamics simulation study of strengthening mechanisms by intercalating nanocrystalline silver films with amorphous nickel layers, characterizing the structure of nanolayered material prototypes obtained by sputtering deposition technique. The objectives of the thesis are three-fold: To study the effects of Ni layer thickness and …

Using Dielectric Characterization To Study Transport And Thermal Properties Of Gas/Supercritical Fluid Embedded Polymer Solution, Xiangxiao Yao

Graduate College Dissertations and Theses

Gas/supercritical fluid (SCF) and polymer mixtures are applied broadly in industry, such as rigid and light foam products for aircraft use, foamed cushion in chairs or shoes, and gas separation membranes for capturing methane from landfill gas. To understand the gas transport properties and polymer thermal properties of the mixture, we detected the dielectric properties of the mixture at two conditions and developed a novel self-designed system for high temperature and high pressure measurement.

The transport properties of physical blowing agents in polymers is viewed as a critical parameter controlling the final foam product’s foam density, cell density, and cell …

Experimental And Computational Studies Of Heat Transfer In Flexible Two-Dimensional Woven Fiber Ceramic Materials, Rodrigo Penide Fernandez

Graduate College Dissertations and Theses

Flexible thermal protection materials made from two-dimensional woven ceramics fibers are of significant interest for hypersonic inflatable aerodynamic decelerators being developed by NASA for future missions on Mars and other planets. A key component of the thermal shield is a heat-resistant outer ceramic fabric that must withstand harsh aero-thermal atmospheric entry conditions. However, a predictive understanding of heat conduction processes in complex woven-fiber ceramic materials under deformation is currently lacking. This dissertation presents a combined experimental and computational study of thermal conductivity in alumina-based Nextel-440 and silicon carbide Hi-Nicalon 5-harness-satin woven fabrics, using the hot-disk transient plane source method and …

Design, Prototyping And Fabrication Of Powder Spray Device For Dehydrated Biological Particulates, James Reilly

Graduate College Dissertations and Theses

Tissue sealants of a liquid based formulation are widely studied in biomedical research with many starting to gain FDA approval. To date, little investigation has been put toward methods of application for tissue sealant materials, more specifically a powder based formulation. The focus of this research was to develop and prototype a powder spray device capable of administering powder based formulations with a long-term goal of integrating the device within the clinical setting. Powders can be administered in a variety of dry forms. These forms can range from non-homogenous nanoscale particles to homogeneous micro and nano-scale spheres. Incorporation of therapeutics …

Fabrication And Thermoelectric Characterization Of Stretchable Conductive Latex-Based Composites, Cory Michael Arcovitch

Graduate College Dissertations and Theses

Miniaturized stretchable electronic devices that can be bent and strained elastically without breaking, have drawn considerable research interest in recent years for wearable computers and integrated bio-sensor applications. Portable electrical power harvesting remains a critical challenge in flexible electronics materials. One proposed solution has been to convert waste heat from the human body into electricity using thermoelectric materials. Traditionally, however, these materials are brittle ceramic semiconductors with limited fracture resistance under deformation. The primary objective of this thesis is to address this challenge by fabricating and studying the mechanical, thermal and electrical performance of stretchable composites combining natural latex polymer …

Aero-Thermal Characterization Of Silicon Carbide Flexible Tps Using A 30kw Icp Torch, Walten Owens

Graduate College Dissertations and Theses

Flexible thermal protection systems are of interest due to their necessity for the success of future atmospheric entry vehicles. Current non-ablative flexible designs incorporate a two-dimensional woven fabric on the leading surface of the vehicle. The focus of this research investigation was to characterize the aerothermal performance of silicon carbide fabric using the 30 kW Inductively Coupled Plasma Torch located at the University of Vermont. Experimental results have shown that SiC fabric test coupons achieving surface temperatures between 1000°C and 1500°C formed an amorphous silicon dioxide layer within seconds after insertion into air plasmas. The transient morphological changes that occurred …

An Atomic Force Microscopy Nanoindentation Study Of Size Effects In Face-Centered Cubic Metal And Bimetallic Nanowires, Erin Leigh Wood

Graduate College Dissertations and Theses

The enhancement of strength of nanoscale materials such as face-centered cubic metal nanowires is well known and arises largely from processes mediated by high energy surface atoms. This leads to strong size effects in nanoscale plasticity; ,smaller is stronger. Yet, other factors, such as crystalline defects also contribute greatly to the mechanical properties. In particular, twin boundaries, which are pervasive and energetically favorable defects in face-centered cubic metal nanowires, have been shown to greatly enhance the strength, furthermore this increase in strength has been shown to be directly influenced by the twin density. However, attempts to control the …