Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 2 of 2
Full-Text Articles in Mechanical Engineering
Order-Disorder Transition Of Aragonite Nanoparticles In Nacre, Zaiwang Huang, Xiaodong Li
Order-Disorder Transition Of Aragonite Nanoparticles In Nacre, Zaiwang Huang, Xiaodong Li
Faculty Publications
Understanding nacre’s bottom-up biomineralization mechanism, particularly, how individual aragonite platelets are formed, has long remained elusive due to its crystallographic peculiarity and structural complexity. Here we report that crystallographic order-disorder transition can be triggered within individual aragonite platelets in pristine nacre by means of heat treatment and/or inelastic deformation, offering a unique opportunity to discriminate mysterious aragonite nanoparticles in transmission electron microscopy. Our findings unambiguously uncover why aragonite nanoparticles in pristine nacre have long been inaccessible under TEM observation, which is attributed to the monocrystal-polycrystal duality of the aragonite platelet. The underlying physical mechanism for why an individual aragonite platelet …
Investigation Of Carbon Corrosion Resistance Of Cnt Containing Electrode, Diana Larrabee, William A. Rigdon, Eli Mcpherson, Joshua Sightler, Xinyu Huang
Investigation Of Carbon Corrosion Resistance Of Cnt Containing Electrode, Diana Larrabee, William A. Rigdon, Eli Mcpherson, Joshua Sightler, Xinyu Huang
Faculty Publications
Carbon support corrosion is one of the major degradation mechanisms of polymer electrolyte membrane (PEM) fuel cell. Carbon oxidation occurs in PEM electrode and is accelerated at high potential created by adverse operating conditions and improper distribution of reactants and products [1, 2, 3]. Carbon corrosion can lead to the thinning of the electrode layer and severe performance degradation. The detailed mechanisms of carbon support corrosion induced performance loss are still not fully understood; it is believed that the following events contribute to the decay: (1) structural collapse of the porous electrode due to the loss of carbon; (2) carbon …