Mechanical Engineering Commons^™

Evolution Of Glassy Carbon Derived From Pyrolysis Of Furan Resin, Josh Kemppainen, Ivan Gallegos, Aaron Krieg, Jacob R. Gissinger, Kristopher E. Wise, Margaret Kowalik, Julia A. King, S. Gowtham, Adri Van Duin, Gregory Odegard

Michigan Tech Publications, Part 2

Glassy carbon (GC) material derived from pyrolyzed furan resin was modeled by using reactive molecular dynamics (MD) simulations. The MD polymerization simulation protocols to cure the furan resin precursor material are validated via comparison of the predicted density and Young's modulus with experimental values. The MD pyrolysis simulations protocols to pyrolyze the furan resin precursor is validated by comparison of calculated density, Young's modulus, carbon content, sp carbon content, the in-plane crystallite size, out-of-plane crystallite stacking height, and interplanar crystallite spacing with experimental results from the literature for furan resin derived GC. The modeling methodology established in this work can …

Conductive 3d Nano-Biohybrid Systems Based On Densified Carbon Nanotube Forests And Living Cells, Roya Bagheri, Alicia K. Ball, Masoud Kasraie, Aparna Chandra, Xinqian Chen, Ibrahim Miskioglu, Zhiying Shan, Parisa Pour Shahid Saeed Abadi

Michigan Tech Publications, Part 2

Conductive biohybrid cell-material systems have applications in bioelectronics and biorobotics. To date, conductive scaffolds are limited to those with low electrical conductivity or 2D sheets. Here, 3D biohybrid conductive systems are developed using fibroblasts or cardiomyocytes integrated with carbon nanotube (CNT) forests that are densified due to interactions with a gelatin coating. CNT forest scaffolds with a height range of 120–240 µm and an average electrical conductivity of 0.6 S/cm are developed and shown to be cytocompatible as evidenced from greater than 89% viability measured by live-dead assay on both cells on day 1. The cells spread on top and …

Comparative Analysis Of Injection Of Pyrolysis Oil From Plastics And Gasoline Into The Engine Cylinder And Atomization By A Direct High-Pressure Injector, Magdalena Szwaja, Jeffrey Naber, David Shonnard, Daniel G. Kulas, Ali Zolghadr, Stanislaw Szwaja

Michigan Tech Publications

The article discusses the results of experimental studies on the course of pyrolysis oil injection through the high-pressure injector of a direct-injection engine. The pyrolysis oil used for the tests was derived from waste plastics (mainly high-density polyethylene—HDPE). This oil was then distilled. The article also describes the production technology of this pyrolysis oil on a laboratory scale. It presents the results of the chemical composition of the raw pyrolysis oil and the oil after the distillation process using GC-MS analysis. Fuel injection tests were carried out for the distilled pyrolysis oil and a 91 RON gasoline in order to …

Accurate Predictions Of Thermoset Resin Glass Transition Temperatures From All-Atom Molecular Dynamics Simulation, Gregory Odegard, Sagar Patil, Prashik Gaikwad, Prathamesh Deshpande, Aaron Krieg, Sagar P. Shah, Aspen Reyes, Tarik Dickens, Julia A. King, Marianna Maiaru

Michigan Tech Publications

To enable the design and development of the next generation of high-performance composite materials, there is a need to establish improved computational simulation protocols for accurate and efficient prediction of physical, mechanical, and thermal properties of thermoset resins. This is especially true for the prediction of glass transition temperature (Tg), as there are many discrepancies in the literature regarding simulation protocols and the use of cooling rate correction factors for predicting values using molecular dynamics (MD) simulation. The objectives of this study are to demonstrate accurate prediction the Tg with MD without the use of cooling rate correction factors and …

Molecular Modeling Of High-Performance Thermoset Polymer Matrix Composites For Aerospace Applications, Prathamesh P. Deshpande

Dissertations, Master's Theses and Master's Reports

The global efforts from major space agencies to transport humans to Mars will require a novel lightweight and ultra-high strength material for the spacecraft structure. Three decades of research with the carbon nanotubes (CNTs) have proved that the material can be an ideal candidate for the composite reinforcement if certain shortcomings are overcome. Also, the rapid development of the polymer resin industry has introduced a wide range of high-performance resins that show high compatibility with the graphitic surface of the CNTs. This research explores the computational design of these materials and evaluates their efficacy as the next generation of aerospace …

Development Of Advanced Models For Pre-Ignition Prediction In Gas Engines And Analytical Model For Wallfilm Evaporation, Ankith Ullal

Dissertations, Master's Theses and Master's Reports

Ever-changing regulations aimed at improving efficiency and reducing harmful emissions have resulted in many power-generation device (engine) manufacturers to adopt new strategies. Computer simulation of these new strategies of power generation requires more accurate and higher fidelity modelling tools. In the present study, two such models are developed. The first model deals with pre-ignition phenomena driven by lubricant (lube) oil in natural gas engines and the second model is relevant to prediction of wallfilm evaporation by employing analytical solutions to transport governing equations for boundary layers.

Pre-ignition in engines has been the subject of current research with the advent of …

Mechanical Properties And Characterization Of Epoxy Composites Containing Highly Entangled As-Received And Acid Treated Carbon Nanotubes, Aaron Krieg, Julia A. King, Gregory M. Odegard, Timothy Leftwich, Leif K. Odegard, Paul D. Fraley, Ibrahim Miskioglu, Claire Jolowsky, Matthew Lundblad, Jin Gyu Park, Richard Liang

Michigan Tech Publications

Huntsman–Merrimack MIRALON® carbon nanotubes (CNTs) are a novel, highly entan-gled, commercially available, and scalable format of nanotubes. As-received and acid-treated CNTs were added to aerospace grade epoxy (CYCOM® 977-3), and the composites were characterized. The epoxy resin is expected to infiltrate the network of the CNTs and could improve mechanical properties. Epoxy composites were tested for flexural and viscoelastic properties and the as-re-ceived and acid treated CNTs were characterized using Field-Emission Scanning and Transmission Electron Microscopy, X-Ray Photoelectron Spectroscopy, and Thermogravimetric Analysis. Composites containing 0.4 wt% as-received CNTs showed an increase in flexural strength, from 136.9 MPa for neat epoxy …

Radio Frequency Studies Of Soot Loading And Ammonia Storage On A Diesel Particulate Filter With A Scr Catalyst Coating, Shreyans Sethia

Dissertations, Master's Theses and Master's Reports

The radio frequency (RF) measurement technique has been shown to be a viable method for measurement of the amount of soot loaded onto DPF’s ^[1] and the amount of NH₃ stored on SCR catalysts ^[2]. In one of the configurations, a microwave resonant cavity is formed by the metal can encasing the enclosed catalyst. Two metal probes acting as antennas are placed on either side of the catalyst. Power transmitted between the antennas is monitored as the frequency of the signal is swept. At certain frequencies, resonance is achieved. Measurements of the resonance frequencies, amplitude at resonance, and …

Towards Sustainable Production Of Chemicals And Fuels From The Fast Pyrolysis Of Waste Polyolefin Plastics, Ulises Gracida Alvarez

Dissertations, Master's Theses and Master's Reports

The increasing amount of plastic waste (PW) generation has become an important concern due to the leveled-off recycling rates. Therefore, governmental agencies around the world, including state governments in the United States, have proposed initiatives to minimize the amount of PW that is landfilled and encourage recycling or energy recovery. Circular economy is a strategy that attempts on reusing PW to produce new polymers while avoiding its disposal and the use of virgin material. Chemical recycling raises an interesting technology prospect due to the potential reduction of pollutant emissions and the establishment of a circular economy through the production of …

Investigation On The Potential Of A Co2 Capture System, Downstream Of The Aftertreatment System For A Heavy-Duty Engine Application, Murchana Pathak

Dissertations, Master's Theses and Master's Reports

The transportation sector accounts for the second largest source of CO₂ emissions after power generation. New Corporate Average Fuel Economy (CAFE) regulations are focusing on improving energy through reduced fuel consumption and greenhouse gas emissions. This work investigates the potential of a CO₂ capture system downstream of an aftertreatment system for a heavy-duty engine application. Amine absorption has been described as one of the most effective ways to capture CO₂ from the exhaust for point sources. Therefore, using thermal-swing absorption process with potassium carbonate (K₂CO₃) as the absorbent liquid, a process was analyzed …

Heat Transfer Analysis In A Paddle Reactor For Biomass Fast Pyrolyis, Ankith Ullal

Dissertations, Master's Theses and Master's Reports

Heat transfer analysis was performed on a novel auger reactor for biomass fast pyrolysis. As part of this analysis, correlations for specific heat capacity and heat transfer coefficients for biomass (sawdust) and sand (used as heat transfer medium) were developed. For sand, the heat transfer coefficient followed a power law distribution with reactor fill level and temperature. For raw biomass, the heat transfer coefficient also showed similar dependence on fill level, but was independent of temperature up to 300°C. These correlations were used in a one dimensional heat transfer model developed to calculate the heating time and heating rate of …

Modeling Of Biomass Torrefaction And Pyrolysis And Its Applications, Jordan L. Klinger

Dissertations, Master's Theses and Master's Reports - Open

Utilizing biomass provides a possible near-term alternative solution for fossil energy dependence in both electricity generation and transportation. Though thermochemical conversion can produce solid/liquid fuels that are compatible in existing infrastructure, detailed scientific chemical and mechanistic understanding are still being developed. In contribution to these efforts, this work is focused on development of a semiempirical, lumped parameter, chemical kinetic model to describe the degradation of woody biomass.

The initial kinetic model was developed in the torrefaction region to describe the gas-phase evolution of products (water, organic acids, permanent gases, and furfural) through a three consecutive reaction model. In this model, …

Two-Phase Flow In Microchannels: Morphology And Interface Phenomena, Alexandru Herescu

Dissertations, Master's Theses and Master's Reports - Open

The existence and morphology, as well as the dynamics of micro-scale gas-liquid interfaces is investigated numerically and experimentally. These studies can be used to assess liquid management issues in microsystems such as PEMFC gas flow channels, and are meant to open new research perspectives in two-phase flow, particularly in film deposition on non-wetting surfaces. For example the critical plug volume data can be used to deliver desired length plugs, or to determine the plug formation frequency. The dynamics of gas-liquid interfaces, of interest for applications involving small passages (e.g. heat exchangers, phase separators and filtration systems), was investigated using high-speed …