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Polymer and Organic Materials Commons™
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Full-Text Articles in Polymer and Organic Materials
Thienoisatin Oligomers As N-Type Molecular Semiconductors, Natalie M. Kadlubowski, Xuyi Luo, Jianguo Mei
Thienoisatin Oligomers As N-Type Molecular Semiconductors, Natalie M. Kadlubowski, Xuyi Luo, Jianguo Mei
The Summer Undergraduate Research Fellowship (SURF) Symposium
Organic field effect transistors (OFETs) offer many advantages compared to traditional inorganic transistors, such as flexibility and solution processability. In this study we design and synthesize two thienoisatin-based organic semiconducting small molecules, then investigate their electronic properties in n-type OFETs. To introduce n-type charge transport, electron-withdrawing dicarbonitrile moieties were installed on thienoisoindigo and bis-thienoisatin molecules, which led to a quinoidal conjugation on thienoisoindigo, while maintaining an aromatic conjugation on the bis-thienoisatin. Following the syntheses, the molecules were characterized to determine highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) levels via cyclic voltammetry, as well as any potential …
Validation Of Wrinkling-To-Delamination Adhesion Measurement Technique, Allison Chau, Hyeyoung Son, Chelsea S. Davis
Validation Of Wrinkling-To-Delamination Adhesion Measurement Technique, Allison Chau, Hyeyoung Son, Chelsea S. Davis
The Summer Undergraduate Research Fellowship (SURF) Symposium
Polymer thin films have a wide range of applications that span several different industries. Their optical clarity as well as their mechanical rigidness result in their versatile use in applications such as contact lenses, wearable sensors, and flexible electronics. These applications require precise adhesion, so the need for a simple, quantitative adhesion measurement technique is critical. Several methods have already been developed that quantify the adhesion of flexible thin films attached to rigid substrates. However, when the thin films are rigid and the substrates compliant, these methods are insufficient. In the authors’ previous work, an adhesion measurement technique was developed …
Developing Strategies To Toughen Bio-Inspired Adhesives, Narelli P. Narciso, Samuel Lee Huntington, Jonathan J. Wilker
Developing Strategies To Toughen Bio-Inspired Adhesives, Narelli P. Narciso, Samuel Lee Huntington, Jonathan J. Wilker
The Summer Undergraduate Research Fellowship (SURF) Symposium
Mussels and other marine creatures adhere very well in underwater environments, having the ability to withstand the force of the sea. These animals have inspired synthetic biomimetic adhesives for wet systems, presenting potential for biomedical applications. However, most current commercial adhesives tend to be brittle, not resisting repetitive movements. This study assesses toughening strategies to improve the mussel-inspired adhesives’ ductility while maintaining its strength. The strategies included altering the polymer’s chemical structure by changing the percentage of polyethylene glycol (PEG) in the molecule and by adding fillers, such as calcium carbonate, silica and nacre - a calcium carbonate compound found …