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Polymer and Organic Materials Commons

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Other Materials Science and Engineering

Iowa State University

2005

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Full-Text Articles in Polymer and Organic Materials

Rare-Earth Iodides In Ionic Liquids:  The Crystal Structure Of [Set3]3[Lni6] (Ln = Nd, Sm), Anja V. Mudring, Arash Babai Jan 2005

Rare-Earth Iodides In Ionic Liquids:  The Crystal Structure Of [Set3]3[Lni6] (Ln = Nd, Sm), Anja V. Mudring, Arash Babai

Anja V. Mudring

Crystals of [SEt3]3[LnI6] (Ln = Nd, Sm) were obtained by the reaction of LnI2 with the ionic liquid [SEt3][Tf2N] [Tf2N = bis(trifluoromethanesulfonyl)imide]. The compounds are characterized by octahedral [LnI6]3- units that are surrounded by a distorted cube of triethylsulfonium cations.