Polymer and Organic Materials Commons^™

High-Stress Shear-Induced Crystallization In Isotactic Polypropylene And Propylene/Ethylene Random Copolymers, Zhe Ma, Lucia Fernandez-Ballester, Dario Cavallo, Tim Gough, Gerrit W. M. Peters

Department of Mechanical and Materials Engineering: Faculty Publications

Crystallization of an isotactic polypropylene (iPP) homopolymer and two propylene/ethylene random copolymers (RACO), induced by high-stress shear, was studied using in situ synchrotron wide-angle X-ray diffraction (WAXD) at 137 °C. The “depth sectioning” method (Fernandez-Ballester, Journal of Rheology 53:5 (2009), pp. 1229−1254) was applied in order to isolate the contributions of different layers in the stress gradient direction and to relate specific structural evolution to the corresponding local stress. This approach gives quantitative results in terms of the specific length of fibrillar nuclei as a function of the applied stress. As expected, crystallization becomes faster with increasing stress—from the inner …