Materials Science and Engineering Commons^™

Investigating The Rapid Curing Possibility Of Geopolymer Concrete, Ashlesh Banjara

Master's Theses

Recent studies of heat-cured fly ash based green geopolymer concrete have shown its suitability for fabrication of structural members. Fabrication of these structural members requires continuous moderate heating (145°F) for 24 hrs, and an oven essential, for a large member can quickly turn into an energy guzzler, potentially eliminating the green credentials of the product. The proposed research involves the development of a frontal polymerization (FP) method that achieves rapid curing of geopolymer at ambient condition after short-term heat application. Initial work shows thermal FP in geopolymer is a possibility and might be a solution to the problem. The process …

Polymer Foam /Fly Ash Composites: Evaluation Of Mechanical, Interfacial, Thermal, Viscoelastic And Microstructural Properties, Parisa Khoshnoud

Theses and Dissertations

Fly ash, a byproduct of coal combustion process in power plants, consists of fine, powdery particles that are predominantly spherical in shape, either solid or hollow, and mostly glassy (amorphous) in nature. It is capable of being recovered and used as a low-cost reinforcing filler. Adding fly ash particles to a thermoplastic foam poses many challenges to understanding the physical, mechanical, viscoelastic, thermal, and morphological changes to the composite. The effects of fly ash particles on the foaming process; e.g. nucleating and growth steps, cell types and size, and microstructure need to be evaluated in order to develop a commercial …

Synthesis And Characterization Of Microporous And Mesoporous Zeolites From Flyash For Heavy Metal Removal From Wastewater, Saeed Golbad

Theses and Dissertations

Class F fly ash was hydrothermally modified in one- and two-step processes to prepare zeolites with enhanced adsorption characteristics. Highly crystalline X type zeolite and hydroxy sodalite were targeted as microporous and mesoporous zeolite and were successfully synthesized using fly ash precursor by adjusting Si/Al molar ratio in reaction mixture. The heavy metal removal performance of the obtained fly ash-based zeolites was investigated in batch Pb2+ adsorption experiments.

Lead (Pb2+) is a positively charged toxic pollutant that can be present in surface water and industrial wastewater and may cause harmful physiological effects to human. As a result, standards for water …

The Effective Use Of Coal Combustion Products (Ccps) In Ashphalt Pavements, Clayton J. Cloutier

Theses and Dissertations

Hot-Mix Asphalt (HMA) is one of the most widely used construction materials. The National Asphalt Paving Association (NAPA) estimated that there are over 2.6 million miles of roadway surfaces paved in the United States and 94% of these roads are paved with asphalt. NAPA also estimates that approximately 550 million tons of asphalt worth over $30 billion a year is produced in the United States. At such a huge production rate, innovative solutions need to be developed so that asphalt pavements last longer and can also reduce the production and maintenance costs. Producing sustainable asphalt materials can provide for improved …

Experimental Evaluation Of The Effect Of Coal Combustion Products On Constructability, Damage And Aging Resistance Of Asphalt Mastics, Emil Garibaldy Bautista

Theses and Dissertations

Developing a cost-efficient and long-term road infrastructure requires innovative approaches that are both green and environmentally sustainable. Today, building a sustainable, long-lasting, and efficient road infrastructure with little or no repairs is a challenging task and highly innovative technological breakthroughs are urgently needed. For many years fly ash has been effectively used as a partial replacement of portland cement in the production of different types of concrete, as well as in embankments and soil stabilization. On the other hand, the use of Coal Combustion Products (CCPs), including fly ash, as a mineral filler in asphalt pavements has been very limited. …

Effects Of Alternate Cementitious Materials On Compressive Strength And Environmental Impacts Of Cement Mix Designs., Mitchell R. Bush

Materials Engineering

Specific proportions of Portland cement, fly ash, and blast furnace slag cement mixtures where chosen by a ternary phase diagram to be investigated. By experimental testing and company data history fly ash was limited to not exceed 30% and contribution of Portland cement must be over 50%. Ten chosen mix designs were batched by following ASTM C305-94 and cured for twenty-eight and forty-two days, the extended cure length allows the reaction of pozzolanic material with calcium hydroxide to complete. Compressive strength testing at forty-two days yielded low strength for mix designs with 20% or less Portland cement compared to our …

Investigating The Use Of Pozzolans In Portland Cement Concrete And Inorganic Polymer Mortar, Omar Abdelmalek Saleh

UNLV Theses, Dissertations, Professional Papers, and Capstones

The use of pozzolans offers promising signs for a change in the cement industry. Pozzolan in its natural and artificial forms can be used to improve cement properties or to synthesize new cement. This study investigates the use of pozzolans in portland cement concrete and inorganic polymer mortar (geopolymer mortar).

This thesis is divided into two phases. Phase 1 investigates the use of natural pozzolan as a partial replacement of portland cement in concrete. In this phase two types of class N pozzolan are used separately to develop concrete mixtures contain different percentages of class N pozzolan. Fresh concrete properties …

The Quantification Of The Fly Ash Adsorption Capacity For The Purpose Of Characterization And Use In Concrete, Zeyad Tareq Ahmed

Dissertations, Master's Theses and Master's Reports - Open

Fly ash has been shown to be an effective replacement for portland cement in concrete mixtures. However, many fly ash materials contain unburned carbon from the combustion process. Unburned carbon in fly ash adsorbs air entraining admixtures (AEAs) reducing their effectiveness in providing a specified air void system in concrete materials. Measurement tools and methods for characterization of the adsorption properties of fly ash materials are necessary for beneficial use of fly ash materials in concrete. In this research, two methods were developed to measure and quantify the adsorption capacity AEAs on fly ash materials. The first method is the …