Materials Science and Engineering Commons^™

The Study Of Corrosion On Additive-Manufactured Metals., Braydan Daniels

Electronic Theses and Dissertations

The purpose of this study was to investigate and compare the corrosion mechanisms between wrought and additive-manufactured (3D-printed) copper and stainless steel. The experimental procedure consisted of measuring the open circuit potential, electrochemical impedance spectroscopy, linear sweep voltammetry, Tafel analysis, surface topology, and scanning electron microscopy for each metal within salt water, tap water, sulfuric acid, and synthetic body fluid (excluding copper in synthetic body fluid).

Overall, printed stainless steel was more corrosion-resistant than wrought stainless steel in tap water and synthetic body fluid based on OCP, LSV, and surface topology results. Additionally, printed copper was more corrosion-resistant than wrought …

Use Of Electrochemical Techniques And Statistical Analysis To Investigate The Pitting Probability Of Copper, Sina Matin

Electronic Thesis and Dissertation Repository

The development of a safe permanent disposal plan is essential for the long-term disposal of used fuel bundles. Nuclear Waste Management Organization (NWMO) has been investigating the deep geologic disposal of nuclear waste which offers the optimum passive safety system with a negligible probability of release of radionuclides into the environment.

The proposed used fuel containers (UFC) for the permanent disposal of high-level nuclear waste in Canada is comprised of a carbon steel vessel coated with a 3 mm corrosion-resistant copper layer deposited using a combination of electrodeposition and cold spray deposition. Although copper is often considered to be thermodynamically …

Electrodeposited Epitaxial Cobalt Oxides And Copper Metal, Caleb M. Hull

Doctoral Dissertations

"Electrochemical deposition methods are presented for the deposition of Co(OH)₂ and Cu metal. Paper I shows the deposition of β-Co(OH)₂ on Ti through electrochemical reduction of [Co(en)₃]³⁺ to [Co(en)₃]²⁺ in 2M NaOH. The catalytic properties of the deposited Co(OH)₂ towards water oxidation is found comparable to Co₃O₄, with the surface of the Co(OH)₂ converting to CoOOH during the reaction. Paper II gives the conditions suitable for epitaxial growth of Co(OH)₂ on Au(100), Au(110), and Au(111) following the same reduction mechanism as described in Paper I. …

Homo- And Heterometallic Bis(Pentafluorobenzoyl)Methanide Complexes Of Copper(Ii) And Cobalt(Ii), Janell Crowder

Legacy Theses & Dissertations (2009 - 2024)

β-Diketones are well known to form metal complexes with practically every known metal and metalloid. Metal complexes of fluorinated β-diketones generally exhibit increased volatility and thermal stability compared to the non-fluorinated analogues, and thus are used extensively in various chemical vapor deposition (CVD) processes for the deposition of metal, simple or mixed metal oxides, and fluorine-doped metal oxide thin films. Furthermore, the electron-withdrawing nature of the fluorinated ligand enhances the Lewis acidity of a coordinatively unsaturated metal center which facilitates additional coordination reactions. The physical and structural properties of fluorinated β-diketonate complexes are discussed in Chapter 1 …

Doped Tio2 Nanowires For Applications In Dye Sensitized Solar Cells And Sacrifical Hydrogen Production, Qasem Alsharari

Electronic Thesis and Dissertation Repository

This thesis explores the synthesis of metal oxide 1-D nanowires using a sol-gel method in supercritical carbon dioxide (sc-CO₂), as an environmental friendly enabling solvent. Porous nanowires were synthesized and their performance was tested in dye sensitized solar cell and sacrifical hydrogen production. Titanium isopropoxide (TIP) was used as a precursor for titania synthesis while copper, bismuth and indium were examined as dopants, respectively. The sol-gel reactions were catalyzed by acetic acid in CO₂ at a temperature of 60 °C and pressure of 5000 psi. It was observed that acetic acid/monomer ratio > 4 produced nanowires while a …

Ruco To Extend The Scalability Of Ultra-Thin Direct Plate Liners, Daniel Verne Greenslit

Legacy Theses & Dissertations (2009 - 2024)

In traditional semiconductor technology a sputtered copper seed layer is used to improve the adhesion, microstucture, and electromigration characteristics of electrochemically deposited (ECD) copper. The seed layer is deposited on top of a Ta/TaN stack. The Ta layer acts as an adhesion and nucleation layer for the copper seed and the TaN serves as a diffusion barrier for the Cu. As the line widths continue to shrink, scaling each of these layers becomes more difficult. It would be advantageous for the interconnect to be composed of as much copper as possible, transitioning from the traditional liner seed stack to a …

Nucleation, Wetting And Agglomeration Of Copper And Copper-Alloy Thin Films On Metal Liner Surfaces, Stephanie Florence Labarbera

Legacy Theses & Dissertations (2009 - 2024)

One of the key challenges in fabricating narrower and higher aspect ratio interconnects using damascene technology has been achieving an ultra-thin (~2 nm) and continuous Cu seed coverage on trench sidewalls. The thin seed is prone to agglomeration because of poor Cu wetting on the Ta liner. Using in-situ conductance measurements, the effect of lowering the substrate temperature during Cu seed deposition has been studied on tantalum (Ta) and ruthenium (Ru) liner surfaces. On a Ta surface, it was found that lowering the deposition temperature to -65°C increases the nucleation rate of the Cu thin film, and reduces the minimum …

Compensation And Characterization Of Gallium Arsenide, Randy A. Roush

Electrical & Computer Engineering Theses & Dissertations

The properties of transition metals in gallium arsenide have been previously investigated extensively with respect to activation energies, but little effort has been made to correlate processing parameters with electronic characteristics. Diffusion of copper in gallium arsenide is of technological importance due to the development of GaAs:Cu bistable photoconductive devices. Several techniques are demonstrated in this work to develop and characterize compensated gallium arsenide wafers. The material is created by the thermal diffusion of copper into silicon-doped GaAs. Transition metals generally form deep and shallow acceptors in GaAs, and therefore compensation is possible by material processing such that the shallow …

Effect Of Recovery On The Recrystallized Grain-Size Of High Purity Aluminum, Rodney L. Helterline

Bachelors Theses and Reports, 1928 - 1970

When a cold-worked metal is annealed, it’s physical properties hange as a result of a new grain structure. The annealing treatment is divided into three stages according to the changes that occur in the distorted metal: (1) recovery, (2) recrystallization, and (3) grain growth.

The Application Of Electric Energy To The Metallurgy Plants In Montana, Edwin J. Duncan

Bachelors Theses and Reports, 1928 - 1970

Since the year 1800, metallurgy has been affiliated with electricity. In fact, the two industries have grown side by side, being naturally dependent upon each other and having a parallel growth.

The Construction And Operation Of A Universal Specimen Mount With Protective Lead Shield For The Purpose Of Determining Pole Figures Using The Schulz-Decker Transmission Technique, Richard L. Fausner

Bachelors Theses and Reports, 1928 - 1970

It was the purpose of this study to construct a universal mount, to construct a protective lead shield, to operate the instrument, and to provide a pole figure using the transmission method of Schulz and Decker. There are at present several lengthy x-ray methods of determining the grain orientation of metals. These methods are mainly photographic. In order to provide a rapid means of obtaining the necessary information concerning the grain orientation of a metal, a universal mount was constructed.

Host Rocks And Gangue Minerals Associated With Copper Deposits In Plutonic Igneous Rocks, Richard D. Montgomery

Bachelors Theses and Reports, 1928 - 1970

All of the information on the various districts has come directly from published reports. The investigation was suggested by Mr. Forbes Robertson. The geographical extent of the deposits was confined to the western United States. Many of these deposits are of the disseminated porphyry type. A few of the de­posits, such as at Butte, Montana, were of the fissure vein type.

The Effect Of Manganese On The Age Hardening Of Aluminum-Copper Alloys, Keith P. Burgess

Bachelors Theses and Reports, 1928 - 1970

It is known that age-hardening occurs in alloys of the solid solution type containing a hardening constituent, of a metal or metallic compound which is more soluble in the solvent phase at higher tempertures than at lower temperatures.

The Benefication Of A Low-Grade, Montana Scheelite Ore, Walter G. Parker

Bachelors Theses and Reports, 1928 - 1970

The increasing importance of tungsten as an industrial metal and the recent discoveries of extensive deposits of low-grade tungsten ores in Montana led to the investigation which is reported in this paper. The purpose of this investigation was to determine if a saleable concentrate could be obtained from one of these low-grade, Montana scheelite ores.

The Effect Of Ferric Iron Upon The Current Efficiency And The Deposition Of Copper In The Electrowinning Of Copper From Copper Sulphate Solutions, James L. Owings

Bachelors Theses and Reports, 1928 - 1970

In the hydrometallurgy of copper, probably the most widely used method for the precipitation of copper is by electrolysis using insoluble anodes. The process is similar in many respects to the electrolytic refining of copper; one of the main differences is the use of insoluble anodes in electrowinning as compared to the use of impure copper anodes in electrorefining. Impurities, however, are common to both processes. The nature of these impurities differ and the problem of purifying the electrolyte is also different.

Variation Of Induction And Hysteresis Curves For The Heusler Alloy, Cu2mna1, Ford W. Knight

Bachelors Theses and Reports, 1928 - 1970

The purpose of this investigation is to determine the fundamental magnetic characteristics of induction and hysteresis, for the alloy Cu₂MnAl. This is a ternary, ferromagnetic Heusler alloy. The problem is not only to determine these characteristics for the alloy as-cast but to heat treat it and observe the manner in which different heat treat­ments affect these two fundamental magnetic characteristics.

An Investigation Of The Hardening Properties Of Some Alpha Copper Indium Alloys, Charles W. Mcpherson

Bachelors Theses and Reports, 1928 - 1970

Precipitation hardening alloys has assumed a major role in modern da^y development of alloys. In his search for stronger, harder materials, the metallurgist has often been limited by the cost of metals which posses the needed properties.

The Effect Of Iron Upon The Electrowinning Of Copper With An Amalgam Electrode, John A. Alexander

Bachelors Theses and Reports, 1928 - 1970

Current commercial use of the mercury cathode cell is limited to two types of electrolytic sodium cells-­the Castner cell and the Sorenson cell. Mercury as a cathode medium has also found application in polarographic analysis, a method of a simultaneous quantitative and qualitative analysis of several metal components of solution.

Polarographic Analysis Applied To Metallurgical Solutions And Products, Donald W. Johnson

Bachelors Theses and Reports, 1928 - 1970

The polarograph has been applied to a large number of chemical and metallurgical analyses, and is especially applicable to solution control analysis and to the deter­mination of minute quantities of ions in the presence of large amounts of other ions.

Vacuum Distillation Of Zinc And Cadmium From Zinc Leach Purification Cake, Stiles R. Slosson

Bachelors Theses and Reports, 1928 - 1970

The term "vacuum distillation" is used to des­cribe the process employed when certain elements are separated either from their mother compounds or from one another by distilling them under reduced atmos­pheric pressure.

Ferromagnetic Alloys In The System Cu-Mn-Zn, W. Michael Yim

Bachelors Theses and Reports, 1928 - 1970

The purpose of this investigation is to determine whether ferromagnetic alloys exist in the ternary sys­tem Cu-Mn-Zn analogous to the other Heusler alloys. The work in this thesis is a preliminary investi­gation on these alloys using a common metallographic re­search technique and augmented with X-ray methods.

The Electrolytic Purification Of An Impure Cadmium Sulfate Solution With A Cell Utilizing A Mercury Cathode And A Lead Anode, W. D. Mcmaster

Bachelors Theses and Reports, 1928 - 1970

Cadmium is produced solely as a by-product and all cadmium of commerce is obtained from zinc ores. It is a rare occurrence when zinc deposits are found which do not contain some cadmium.

Mineralization Of The Bonanza Mine, H. M. Callaway

Bachelors Theses and Reports, 1928 - 1970

The Bonanza mine of the Emery mining district in Powell County is on the largest veins in the area, and is developed to a depth of 680 feet by an incline shaft following the dip of the structure. Sulfide ores carrying gold and silver values are mined throughout the area which is easily accessible by road from Deerlodge, Montana, ten miles west of the district.

An Investigation Into The Precipitation Of Copper From Mine Water By Cupric Copper Reduction, And The Subsequent Precipitation Of Copper As Cuprous Chloride, Jack T. Gentry

Bachelors Theses and Reports, 1928 - 1970

The objective of this thesis is to determine the possibility of applying a different method to the re­covery of the copper dissolved in the Butte mine waters, and thereby precipitate a purer cement copper with greater efficiency and less iron consumption.

A Study Of The Differential Seperation Of Galena And Sphalerite, Wilfred E. Nagel

Bachelors Theses and Reports, 1928 - 1970

The smelting of complex lead ores is a difficult operation, especially when they contain considerable amounts of iron and zinc. When these ores are smelted, all of the zinc, which is valuable and well worth recovering, goes into the slag. With the advent of the flotation processes, and the ability of these processes to concentrate the lead and zinc minerals into separate products, the smelting of complex lead ores was to a great extent simplified.

Separation Of Cadmium From Zinc In The Purification Step Of The Leaching Cycle, L. C. Powell

Bachelors Theses and Reports, 1928 - 1970

The purpose of this investigation is to determine the effect of the factors listed previously by conducting a series of tests that will indicate the ex­tent to which the purification is influenced by time, temperature, zinc oust size, zinc dust quantity, iron concentration, two stage precipitation, and aeration.

A Mineral Dressing And Economic Study Of A Complex Arsenical Ore, Luigi D. Piana

Bachelors Theses and Reports, 1928 - 1970

The factors that influence the choice of a method for treat­ment of an ore comprise the technical and economic limitations and advantages, derived in detail and balanced according to the exigencies of the particular situation.

An Investigation Of The Precipitation Of Cobalt With Zinc Dust, Lyle Hallberg

Bachelors Theses and Reports, 1928 - 1970

Cobalt, as well as copper, cadmium, and other impurities, is removed by selective precipitation with zinc during the zinc electrolyte purification cycle, and the purification residue may be treated by a Cadmium Plant for the recovery of cadmium.

Construction And Operation Of A Laboaratory Size Thum Cell, Raymond Dugdale

Bachelors Theses and Reports, 1928 - 1970

Electrolytic silver refining was not perfected until the end of the nineteenth century. During the process of development, two systems of silver refining have come into prominence: the Moebius and the Thum types.

A Study Of The Transformation Of A Twenty-Eight Per Cent Tin Bronze, Perry A. Boukind

Bachelors Theses and Reports, 1928 - 1970

In this investigation, attention is directed to the phases covered by a 28 per cent tin alloy. When the investigation was started, consideration was given to the possibility of making a Time - Temperature - Transformation curve for this parti­cular alloy. As the work progressed and further research was carried on, this phase of the work was abandoned.