Mechanics of Materials Commons^™

Functional Bio-Nano Hybrids Through A Precise Control Of Interfacial Interactions At The Nanoscale, Sirimuvva Tadepalli

McKelvey School of Engineering Theses & Dissertations

During the course of evolution, proteins have evolved to perform exquisite functions including structural support, signal transduction, actuation, sensing, catalysis, trafficking, gating, light-harvesting, charge transfer, molecular recognition, self-assembly, self-organization, or combinations of two or more of these functions. A precise control and manipulation of the structure and function of proteins is conceivable with the advent of nanotechnology, which has facilitated the integration of nanomaterials with functional biomolecules to realize bio-nano hybrids with synergistically enhanced functionalities.

At the genesis of bionanotechnology, a paucity in the fundamental understanding of the bio-nano interfaces is a grave impediment to the progress of the field. …

Characterization And Modeling Of Asphalt Concrete For Dynamic Properties And Performances, A S M A. Rahman

Civil Engineering ETDs

The recently developed mechanistic-empirical pavement design guide (MEPDG, also known as Pavement M-E design method) uses the nationally calibrated, binder viscosity-based dynamic modulus predictive model for the design and analysis of asphalt pavements. In this study, this model is assessed for its appropriateness for asphalt-aggregate mixtures typically used in New Mexico. In essence, this study investigates the predictability issue of complex modulus of New Mexico mixes. A total of 54 Superpave mixes with different aggregate gradations, air voids, and binder grades were collected from the mixing plants and from the pavement construction sites. The loose asphalt mixtures were then compacted, …

The Inter-Laminar Shearing Effect On Wrinkle Development In Composite Forming Processes, David Sundquist

McKelvey School of Engineering Theses & Dissertations

Composite materials are becoming prevalent in aerospace industries as the uniqueness of the composite structure allows the composite to be tailored specifically for individual applications. Many fabrication techniques produce defects in composite parts such as wrinkles, fiber waviness, fiber misalignment, and porosity. The driving mechanisms behind these defects occurring during forming processes are not fully understood and, thus, characterization formation of these defects in a uncured state is beneficial to optimize composite processing. This work primarily investigated the influence of how uncured pre-impregnated carbon ply properties affect the wrinkling behavior of a composite laminates. Several factors affecting composite ply forming …

Modeling Of Dislocation Channel Formation And Evolution In Irradiated Metals, Peter James Doyle

Masters Theses

Defect-free dislocation channel formation has been reported to promote plastic instability during tensile testing via localized plastic flow, leading to a distinct loss of ductility and strain hardening in many low-temperature irradiated materials. In order to study the underlying mechanisms governing dislocation channel width and formation, the channel formation process is modeled via a simple stochastic dislocation-jog process dependent upon grain size, defect cluster density, and defect size. Dislocations traverse a field of defect clusters and jog stochastically upon defect interaction, forming channels of low defect-density. Based upon prior molecular dynamics (MD) simulations and in-situ experimental transmission electron microscopy (TEM) …

A Comparison Study Of Composite Laminated Plates With Holes Under Tension, Joun S. Kim

Master's Theses

A Comparison Study of Composite Laminated Plates with Holes under Tension

A study was conducted to quantify the accuracy of numerical approximations to deem sufficiency in validating structural composite design, thus minimizing, or even eliminating the need for experimental test. Error values for stress and strain were compared between Finite Element Analysis (FEA) and analytical (Classical Laminated Plate Theory), and FEA and experimental tensile test for two composite plate designs under tension: a cross-ply composite plate design of [(0/90)4]s, and a quasi-isotropic layup design of [02/+45/-45/902]s, each with a single, centered hole of 1/8” diameter, and 1/4" diameter (four sets …

Synthesis Of Graphene And Graphene-Based Composite Membrane, Yuanjun Fan

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Vibration membrane equipped for earphone requires high performance in both mechanical properties and electronic properties. With extraordinary properties on both, graphene and graphene-based composite materials appear as a promising candidate for this application. Chemical vapor deposition (CVD) is believed to be the most convenient way to synthesize a large area (on scale of square centimeters) as well as a homogeneous thickness for the membrane. The thesis focuses on applying control variable experiment method to analyze different effects on mechanical property of the two CVD setting parameters: cooling rate, and hydrocarbon precursor. For isolating the specimens efficiently, a modified electrochemical method …

Effect Of Ultrasonic Treatment On The Microstructure And Mechanical Properties Of Al6061 And Composite, Ana S. Exime

FIU Electronic Theses and Dissertations

In this study, the effect of ultrasonic treatment (UST) parameters such as amplitude, sonication time, and melt temperature on microstructure and microhardness of Al 6061 alloy is evaluated. The effect of UST on the dispersion of tungsten disulfide (WS₂) and carbon nanotubes (CNT) as reinforcement particles in Al 6061 during casting is also studied. The cast Al 6061 with UST demonstrated 32% grain size reduction and 8% increase in the microhardness for optimum processing conditions. The cavitation process induced by UST is responsible for the refinement in microstructure and increase of hardness by enhancing the degassing and nucleation …

Photodynamic Therapy: Agents And Mechanisms, Rebecca Claire Gilson

McKelvey School of Engineering Theses & Dissertations

Despite enormous efforts, cancer remains a leading cause of morbidity and mortality world-wide. The main challenges currently facing cancer therapy include lack of adequate tumor targeting, failure to treat hypoxic tumor cells, and induction therapy resistant tumors. A solution to these limitations can be found in photodynamic therapy (PDT) which combines light and light activatable compounds, photosensitizers (PSs), to produce cytotoxic reactive oxygen species (ROS) to damage tumor tissue. This creates a spatiotemporal therapeutic effect, where cell damage only occurs at the intersection of the PS and light. PDT can treat tumors through unique mechanisms which reduce induction of tumor …

Hollow And Porous Plasmonic Nanostructures For Highly Efficient Chemical And Biological Sensing, Keng-Ku Liu

McKelvey School of Engineering Theses & Dissertations

Localized surface plasmon resonance (LSPR) involves the collective and coherent oscillation of dielectrically confined conduction electrons. The LSPR wavelength of noble metal nanoparticles (such as gold, silver and copper), which falls into the visible and near infrared range of the electromagnetic spectrum, is sensitive to the composition, size, shape, dielectric properties of the surrounding medium, and proximity to other nanostructures (plasmon coupling). Based on the sensitivity of the surface plasmon resonance to the changes in the dielectric properties of the surrounding medium and the enhancement of the electromagnetic (EM) field in proximity of metal nanostructures, two important classes of plasmonic …

Simulating Dynamic Failure Of Polymer-Bonded Explosives Under Periodic Excitation, Rachel Kohler, Camilo Duarte Cordon, Marisol Koslowski

The Summer Undergraduate Research Fellowship (SURF) Symposium

Accidental mishandling of explosive materials leads to thousands of injuries in the US every year. Understanding the mechanisms behind the detonation process is crucial to prevent such accidents. In polymer-bonded explosives (PBX), high-frequency mechanical excitation generates thermal energy and can lead to an increase in temperature and vapor pressure, and potentially the initiation of the detonation process. However, the mechanisms behind this energy release, such as the effects of dynamic fracture and friction, are not well understood. Experimental data is difficult to collect due to the different time scales of reactions and vibrations, so research is aided by running simulations …

Dynamic Range Limitations Of Low-Noise Microwave Transistors At Cryogenic Temperatures, Ahmet Hakan Coskun

Doctoral Dissertations

Dynamic range is an important metric that specifies the limits of input signal amplitude for the ideal operation of a given receiver. The low end of dynamic range is defined by the noise floor whereas the upper limit is determined by large-signal distortion. While dynamic range can be predicted in the temperature range where compact transistor models are valid, the lack of large-signal models at temperatures below -55 C prevents the prediction and optimization of dynamic range for applications that require cryogenic cooling. For decades, the main goal concerning the performance of these applications was lowering the noise floor of …

Inkjet Printing Of Nano-Silver Conductive Ink On Pet Substrate, Skyler Jiang

Materials Engineering

Printing of conductive ink traditionally uses copper-based ink and was used on high temperature metal substrates due to the high curing and sintering temperature of copper. In this experiment, however, Metalon JS-B25P nano-silver conductive ink was printed using an Epson Stylus C88+ inkjet printer on polyethylene terephthalate (PET) based Novele printing media made for low temperature applications. With silver’s lower sintering temperature, the nano-silver particles in this ink are desired to be able to sinter at a low enough temperature to be used on the PET substrate. The printed ink traces were cured with a temperature-controlled hotplate at 100℃, 120℃, …

Characterizing Structure, Properties, And Deformation In Metallic Glasses And Olivine Using Instrumented Nanoindentation, Kelly Kranjc

McKelvey School of Engineering Theses & Dissertations

Micro- and nanomechanical testing can provide significant insight about the structure, properties, and behavior of materials. These techniques are nondestructive, require only limited amounts of material, and have been known to detect a brittle-to-ductile transition in mechanical behavior due to a size effect. This work utilizes this type of testing to explore fundamental questions about the structure, properties, and behavior of two disparate material systems: metallic glasses and olivine.

Metallic glasses are metallic alloys devoid of any long-range order. Their unique atomic structure imbues them with properties such as a high elastic strain limit, near-theoretical strengths, and the ability to …

Negahban Group Report: Saw-Tooth Shear Response Of Aged Poly(Methyl Methacrylate) (Pmma), Mehrdad Negahban

Department of Mechanical and Materials Engineering: Faculty Publications

Results for isothermal saw-tooth shear loading experiments conducted on annealed and oven-cooled poly(methyl methacrylate) (PMMA) at temperatures between 50^oC and 140^oC. The experiments were conducted 1996.

Formation Of Mound-Like Multiscale Surface Structures On Titanium By Femtosecond Laser Processing, Edwin Peng, Alfred Tsubaki, Craig A. Zuhlke, Ryan Bell, Meiyu Wang, Dennis R. Alexander, George Gogos, Jeffrey E. Shield

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Surface Functionalization Technique • Femtosecond Laser Surface Processing (FLSP) • Utilize high power, femtosecond (10-15 s) laser pulses • Produce self-organized, multiscale surface micro/nanostructures • Diverse range of applicable substrates: semiconductors, metals, polymers, & composites

Why? • What are the different types of FLSP structures on Ti? • Physical evidence needed for FLSP formation models • Optimize FLSP of Ti for biomedical & other applications

How? • Obtain evidence of mound growth processes by examining underlying microstructure • Utilize dual beam Scanning Electron Microscope-Focused Ion Beam instrument to cross section surface structures & fabricate transmission electron microscopy samples

Tensile Specimen Punch, John Allen

All Undergraduate Projects

This project comes from a need to have tensile specimens made for the MET 351, Metallurgy/Materials and Processes, and 426, Applied Strengths of Materials, labs. This punch is designed to be used with an arbor press to create the desired tensile specimen shape out of plastic blanks. The initial concept was suggested by Dr. Craig Johnson. The designs went through many changes, for example getting rid of the sides originally proposed to hold the specimen in place, and modifications to other parts to make them more efficient. Additional parts were also added to the design with the help and advice …

Detecting Laminate Damage Using Embedded Electrically Active Plies – An Analytical Approach, Amany Micheal, Yehia Bahei-El-Din

Centre for Advanced Materials

Assessment of damage initiation and progression in composite laminates with embedded electrically active plies is modeled. Utilizing electrically active layers embedded in composite laminates as damage sensors is proposed by several researchers and is mainly assessed experimentally. Sensing damage using embedded electrically active plies is generally preferred over the use of surface mounted PZT wafers since the range of the latter is limited to a very narrow area underneath the surface, while multiple damage mechanisms can generally be found in several plies of the laminate. The solution presented invokes two levels of analysis. Firstly, on the laminate level, applied membrane …

Characterization & Extraction Of Extracellular Matrix From Porcine Adipose Tissue, Rahulkumar Kantibhia Bhoi

Open Access Theses & Dissertations

Tissue in particular extracellular matrix(ECM) plays a vital role in the growth and the function of each cell types and promote tissue regeneration and repair an impair organs. Many techniques have been developed so far to decellularized porcine tissue for the purpose to use as regenerative medicine and in tissue engineering. We aimed to optimized a method to decellularized porcine tissue while effectively eliminating xenogeneic epitopes, lipids and to retain necessary component of it intact without disrupting ECM. We have developed 2-week protocol to optimize well preserved ECM component that may keep xenogeneic biomaterial for tissue engineering and regenerative medicine. …

Methods For Producing Graphene From Petroleum By-Products, Eva M. Deemer

Open Access Theses & Dissertations

N/A

Raman Microscopic Analysis Of Internal Stress In Boron-Doped Diamond Thin Films, Emma M.A. Sundin

Open Access Theses & Dissertations

The correlations between induced stress on undoped and boron-doped diamond (BDD) thin films, sample chemical composition, and fabrication substrate are investigated in this study via confocal Raman microspectroscopic analysis. Stability of BDD films is relevant to fast-scan cyclic voltammetry, as film delamination and dislocation of BDD-coated electrodes that can occur during neurosurgical electrode implantation can negatively impact the biosensing reliability of this technique. Electrodes were fabricated by coating cylindrical tungsten rods using a custom-built chemical vapor deposition reactor. The results of the analysis reveal a direct correlation between regions of pure diamond and enhanced material stress, as well as preferential …

Material Behavior Of Window 7 Carrier Panel Tiles And Thermal Pane Fragments Recovered From The Space Shuttle Columbia, Brenda Roseanne Arellano

Open Access Theses & Dissertations

Since the end of the space shuttle program, a new generation spacecraft has been developed to transport humans back into space. NASAâ??s Orion will carry a crew beyond low-earth orbit and the exploration of Mars may be possible in the future. Space safety becomes significant with human spaceflight and the risks are high. However, aerospace materials may provide opportunities to prevent future disasters. When the space shuttle Columbia disintegrated during re-entry in 2001, thousands of debris were collected for analysis. In contrast, when the Challenger space shuttle broke apart in 1986, all shuttle debris were buried. These tragic disasters are …

Ac Susceptibility And Epr Investigations Of Superspin Dynamics In Manganese Oxide Nanoparticles, Mahesh Koirala

Open Access Theses & Dissertations

We have investigated the superspin dynamics of 5 nm and 10 nm mixed state Mn3O4 nanoparticles utilizing ac-susceptibility and electron paramagnetic resonance measurements. The out of phase component of the ac-susceptibility measurements show a magnetic anomaly below (T

Comprehensive Finite Element Modeling Of Ti-6al-4v Cellular Solids Fabricated By Electron Beam Melting, Edel Arrieta

Open Access Theses & Dissertations

Additive manufacturing permits the fabrication of cellular metals which are materials that can be highly customizable and possess multiple and extraordinary properties such as damage tolerance, metamorphic and auxetic behaviors, and high specific stiffness. This makes them the subject of interest for innovative applications. With interest in these materials for energy absorption applications, this work presents the development of nonlinear finite element models in commercial software platforms (MSC Patran/Nastran) that permit the analysis of the deformation mechanisms of these materials under compressive loads. In the development of these models, a detailed multiscale study on the different factors affecting the response …

The Interplay Between Grain Size And Austenite Stability On Deformation Behavior Of High Strength-High Ductility Combination Nanostructured Stainless Steel, Venkata Sai Ananth Challa

Open Access Theses & Dissertations

The concept of phase reversion involving severe cold deformation of metastable austenite to generate strain-induced martensite, followed by temperature-time annealing sequence, was used to obtain varying grain size from nanograined/ultrafine-grained (NG/UFG) to coarse-grained (CG) regime. This concept was used to obtain â??high strength-high ductilityâ?? combination in nano/ultrafine-grained (NG/UFG) austenitic stainless steel. Using this concept, the objective of the study is to elucidate the dependence of grain size on deformation mechanisms and deformation-induced microstructural changes. The objective was accomplished by combining depth-sensing nanoindentation experiments conducted at various strain rates, and interrupted tensile testing at various strain and post-mortem analyses of deformed …

Anisotropy Evolution Due To Surface Treatment On 3d-Printed Fused Deposition Modeling (Fdm) Of Acrylonitrile Butadiene Styrene (Abs), Blake E. Lozinski

Honors Undergraduate Theses

Purpose: This paper will present insight to the methodology and results of the experimental characterization of Acrylonitrile Butadiene Styrene (ABS) using Fused Deposition Modeling (FDM). The work in this research explored the effects of print orientation, surface treatment, and ultraviolet (UV) light degradation with the utilization of Digital Image Correlation (DIC) on ABS tensile specimens.

Design/methodology: ABS specimens were printed at three build orientations (flat (0 degrees), 45 degrees, and up-right (90 degrees)). Each of these specimens were treated with three different surface treatments including a control (acrylic paint, Cyanoacrylate, and Diglycidyl Bisphenol A) followed by exposure to UV light …

Impact Of Clip Connection And Insulation Thickness On Bracing Of Purlins In Standing Seam Roof Systems, Michael W. Seek, Daniel Mclaughlin

Engineering Technology Faculty Publications

The flexural strength of purlins in standing seam roof systems is highly dependent upon the extent to which the sheathing provides lateral and torsional restraint. Typical models to predict the restraint provided by the sheathing assume that the plane of lateral resistance occurs at the top flange of the purlin. In reality, depending on the configuration of the clip and the amount of insulation located between the purlin and the clip, the plane of lateral resistance and corresponding center of rotation shifts above the top flange. This distance, referred to as the effective standoff, is important to evaluate the effectiveness …

Dft Study Of Adsorption Of Trimetallic Endohedral Fullerenes On Graphene, Nakul Nitin Karle

Open Access Theses & Dissertations

A density functional theory (DFT) study on the geometric and electronic structure of C60 and Sc3N@C80 along with their adsorption on pristine single layer graphene (SLG) is presented. C60 is found to adsorb in two nearly degenerate configurations: (i) with a pentagon facing the SLG, which is the most stable one, and (ii) with a hexagon facing the SLG in a face-to-face perfect alignment, rarely common in Ï?â??Ï? interactions, 0.06 eV higher in energy. The calculated binding energy of 0.76 eV, which includes dispersion effects, is in good agreement with previous theoretical and experimental reports. On the contrary, Sc3N@C80 adsorption …

Structural And Mechanical Characterization Of Nanocrystalline Tungsten And Tungsten-Based Alloy Thin Films For Extreme Environment Applications, Gustavo Martinez

Open Access Theses & Dissertations

Extreme environments associated with nuclear applications often results in degradation of the physical, mechanical and thermo-mechanical properties of the materials. Tungsten (W) exhibits unique physical and mechanical properties, which makes tungsten a good candidate for nuclear applications; however, intrinsic W exhibits low fracture toughness at all temperatures in addition to a high ductile to brittle transition. In the present work, nanocrystalline W, W-Y and W-Mo alloys were nanoengineered for nuclear applications. Nanocrystalline tungsten coatings with a thickness of ~1 µm were deposited onto Silicon (100) and Sapphire (C-plane) using RF and DC sputtering techniques under various growth conditions. Yttrium content …

Process-Structure-Property Relationship In Magnesium-Based Biodegradable Alloy For Biomedical Applications, Pramanshu Trivedi

Open Access Theses & Dissertations

Magnesium alloys are considered to be the next generation of biomaterials because of their ability to degrade in the physiological environment. We elucidate here the impact of multiaxial forging of Mg-2Zn-2Gd alloy on grain refinement to sub-micron regime and relate the structure to mechanical properties and biological functionality. As-cast and annealed samples were multiaxial forged (MAF) for a total number of two passes with a true strain of ~2/pass. Considering that the microstructure governs the biological response of materials, we studied the constituents of the microstructure in conjunction with the mechanical behavior. The antimicrobial behavior in a Mg-2Zn-2Gd alloy with …

Organic-Inorganic Graphite And Transition Metal Dichalcogenide Based Composites For 3d Printing, Jorge Alfredo Catalan Gonzalez

Open Access Theses & Dissertations

This project was multipronged to help fuse together topics of additive manufacturing and two-dimensional (2D) layered materials, and studying the mechanical and electrical properties of the composites produced. The composites are made from the thermoplastic polymer acting as a matrix and the graphite and 2D transition metal dichalcogenides (TMDs) serving as the filler or reinforcement. Different concentrations of TMD's were added to the matrix to study the effect of composition on the mechanical and electrical properties. To shed insights into the mechanical properties, test coupons were produced as "dog bone" structures for tensile testing using the ASTM D638 type 5 …