Engineering Mechanics Commons^™

Characterization And Computational Modelling For The Garnet Oxide Solid State Electrolyte Ta-Llzo, Colin A. Versnick

Electronic Thesis and Dissertation Repository

The all-solid-state-battery (ASSB) serves as a promising candidate for next generation lithium ion batteries for significant improvements in battery safety, capacity, and longevity. Of the material candidates researched to replace the conventionally used liquid electrolyte, the garnet oxide Ta-LLZO (Li_6.4La₃Zr_1.4Ta_0.6O₁₂) has received much attention thanks to its high chemical and electrochemical stability, and ionic conductivity which rivals that of liquid electrolytes. While much investigation has taken place regarding the electrochemical performance of Ta-LLZO, much less is known about the micromechanics, including microstructural characterization, stress and strain development, and material failure …

Effect Of The Nonlinear Material Viscosity On The Performance Of Dielectric Elastomer Transducers, Yuanping Li

Electronic Thesis and Dissertation Repository

As a typical type of soft electroactive materials, dielectric elastomers (DEs) are capable of producing large voltage-induced deformation, which makes them desirable materials for a variety of applications in transduction technology, including tunable oscillators, resonators, biomimetics and energy harvesters. The dynamic and energy harvesting performance of such DE-based devices is strongly affected not only by multiple failure modes such as electrical breakdown, electromechanical instability, loss-of-tension and fatigue, but also by their material viscoelasticity. Moreover, as suggested by experiments and theoretical studies, DEs possess nonlinear relaxation processes, which makes modeling of the performance of DE-based devices more challenging.

In this thesis, …

Effect Of Material Viscoelasticity On Frequency Tuning Of Dielectric Elastomer Membrane Resonators, Liyang Tian

Electronic Thesis and Dissertation Repository

Dielectric elastomers (DEs) capable of large voltage-induced deformation show promise for applications such as resonators and oscillators. However, the dynamic performance of such vibrational devices is not only strongly affected by the nonlinear electromechanical coupling and material hyperelasticity, but also significantly by the material viscoelasticity. The material viscoelasticity of DEs originates from the highly mobile polymer chains that constitute the polymer networks of the DE. Moreover, due to the multiple viscous polymer subnetworks, DEs possess multiple relaxation processes. Therefore, in order to predict the dynamic performance of DE-based devices, a theoretical model that accounts for the multiple relaxation processes is …

Continuum Modeling On Size-Dependent Properties Of Piezoelectric Nanostructures, Zhi Yan

Electronic Thesis and Dissertation Repository

Piezoelectric beam- and plate-based nanostructures hold a promise for device applications in the nanoelectromechanical systems (NEMS) due to their superior mechanical and electromechanical coupling properties. “Small is different”, nanostructured piezoelectric materials exhibit size-dependent properties, which are different from their bulk counterparts. For predicting the unique physical and mechanical properties of these novel nanostructures, continuum mechanics modeling has been regarded as an efficient tool. However, the conventional continuum models fail to capture the size effects of nanostructures and thus are not directly applicable at the nanoscale. Therefore, it is necessary to develop modified continuum models for piezoelectric nanostructures by incorporating the …