Engineering Science and Materials Commons^™

Multi-Axial Failure Of High-Performance Fiber During Transverse Impact, Matthew C. Hudspeth

Open Access Dissertations

The effect of projectile nose geometry on ensuing wave development in high-performance yarns is explored during single yarn transverse impact. Special attention has been placed on visualizing the immediate region around the projectile-yarn contact site for 0.30-cal round, 0.30-cal fragment simulation projectiles (FSP), and razor blades using high-speed imaging. Kevlar® KM2, Dyneema®SK76 and AuTx have been impacted at velocities ranging from ∼100 m/s to ∼1200 m/s depending on projectile nose shape, with an emphasis set on determining the critical velocity wherein below said velocity significant development of wave propagation occurs and above said velocity the yarn fails immediately upon impact. …

Analytical Investigation Of Fretting Wear With Special Emphasis On Stress Based Models, Arnab Jyoti Ghosh

Open Access Dissertations

Fretting refers to the minute oscillatory motion between two surfaces in contact under an applied normal load. It can cause either surface or subsurface initiated failure resulting in either fatigue or wear or both. Two distinct regimes – partial slip and gross slip are typically observed in fretting contacts. Due to the nature of contact, various factors such as wear debris, oxidation, surface roughness, humidity etc. effect failures caused due to fretting. A number of different techniques have been developed to quantify fretting damage and several numerical models are proposed to predict damage due to fretting. Fretting wear also depends …

Preparation Of Mesoporous Silica Supported Ruthenium Oxides And The Application And Kinetic Study In The Catalysis Of Water Oxidation, Yang Zhang

Open Access Dissertations

Photo-induced water splitting of water into H2 and O2 has been a major focus in the development of clean and renewable energy. The development of viable and efficient catalysts that facilitates O2 production remains the major challenge in the study of the corresponding half-reaction of water oxidation. There are plenty of metal oxides reported active in the catalysis of water oxidation. However, several important performance bench marks of those materials, such as the non-stoichiometric production of O2, slow reaction rate and/or low quantum efficiency, remain to be improved.

Ruthenium oxide (RuO2) has long been known as one of the most …

Orientation Controllable Epitaxial Vapor-Liquid-Solid Semiconductor Nanowire Synthesis On Silicon Substrate, Sung Hwan Chung

Open Access Dissertations

Semiconductor nanowires synthesized via the vapor-liquid-solid (VLS) mechanism have attracted extensive research interest in recent years owing to their unique structure as a promising candidate for the future electronic devices. Germanium and silicon nanowires, in particular, are compatible with the current silicon-based technology via direct assembly. However, one of the main challenges for the successful nanowire application in large-scale is the lack of the method for obtaining nanowires in desired positions and directions. Therefore, the comprehensive, systematic understanding of epitaxial nanowire growth and the more suitable method to align nanowires on novel structure are required. In this work, the synthesis …