Engineering Science and Materials Commons^™

Nonlinear Impedance Spectroscopy To Characterize Hole Transport And Recombination Dynamics In Organic Semiconductor Devices, Robin Rice

Graduate College Dissertations and Theses

Impedance Spectroscopy (IS) is an increasingly common technique to characterize both solid state and electrochemical systems including solar cells and light emitting diodes (LEDs). However, IS relies on a system response being linear with its input such that a time invariant impedance can be defined. This is usually achieved by a small amplitude input. However, doing so suppresses responses of the nonlinear processes which are of considerable interest to those designing and optimizing these devices, such as charge carrier recombination and space charge effects. This investigation employs the recently developed nonlinear extension to IS (NLIS) based in Fourier analysis of …