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Civil Engineering Faculty Publications

Mineralization

Publication Year

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Full-Text Articles in Civil Engineering

Degradation Of 3-Nitro-1, 2, 4-Trizole-5-One (Nto) In Wastewater With Uv/H2o2 Oxidation, Amalia Terracciano, Christos Christodoulatos, Agamemnon Koutsospyros, Zhaoyu Zheng, Tsan-Liang Su, Benjamin Smolinski, Per Arienti, Xiaoguang Meng Dec 2018

Degradation Of 3-Nitro-1, 2, 4-Trizole-5-One (Nto) In Wastewater With Uv/H2o2 Oxidation, Amalia Terracciano, Christos Christodoulatos, Agamemnon Koutsospyros, Zhaoyu Zheng, Tsan-Liang Su, Benjamin Smolinski, Per Arienti, Xiaoguang Meng

Civil Engineering Faculty Publications

Insensitive Munition (IM) formulations contain 3-nitro-1,2,4-trizole-5-one (NTO), an energetic compound with the highest aqueous solubility (16 g L−1) among all IM explosives, including 2,4-dinitroanisole (DNAN) and 1-nitroguanidine (NQ); as a result wastewater streams from IM processing facilities can be highly contaminated and potentially toxic. The removal of energetic compounds from wastewater streams prior to their discharge in the environment is imperative, and new technology must be developed to efficiently treat high levels of NTO and other IM compounds in these streams. In this study, the treatment of NTO wastewater by a UV/H2O2 oxidation process under …


Biodegradation Of The High Explosive Hexanitrohexaazaiso-Wurtzitane (Cl-20), Pelin Karakaya, Christos Christodoulatos, Agamemnon Koutsospyros, Wendy Balas, Steve Nicolich Nicolich, Mohammed Sidhoum Jan 2009

Biodegradation Of The High Explosive Hexanitrohexaazaiso-Wurtzitane (Cl-20), Pelin Karakaya, Christos Christodoulatos, Agamemnon Koutsospyros, Wendy Balas, Steve Nicolich Nicolich, Mohammed Sidhoum

Civil Engineering Faculty Publications

The aerobic biodegradability of the high explosive CL-20 by activated sludge and the white rot fungus Phanerochaete chrysosporium has been investigated. Although activated sludge is not effective in degrading CL-20 directly, it can mineralize the alkaline hydrolysis products. Phanerochaete chrysosporium degrades CL-20 in the presence of supplementary carbon and nitrogen sources. Biodegradation studies were conducted using various nutrient media under diverse conditions. Variables included the CL-20 concentration; levels of carbon (as glycerol) and ammonium sulfate and yeast extract as sources of nitrogen. Cultures that received CL-20 at the time of inoculation transformed CL-20 completely under all nutrient conditions studied. When …