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Full-Text Articles in Civil Engineering

Influence Of Water Chemistry Parameters On The Dissolution Rate Of The Lead (Ii) Carbonate Hydrocerussite, Caitlin Se Kushnir Dec 2014

Influence Of Water Chemistry Parameters On The Dissolution Rate Of The Lead (Ii) Carbonate Hydrocerussite, Caitlin Se Kushnir

Electronic Thesis and Dissertation Repository

This work has focused on the kinetic dissolution of the lead (II) carbonate hydrocerussite (Pb3(CO3)2(OH)2) under four pH conditions (7.5, 8, 9, 10), three dissolved inorganic concentrations (DIC; 10, 20, 50 mg C/L), and three initial hydrocerussite concentrations (10, 20, 50 mg/L) in batch experiments. Experiments were performed in at least duplicate to determine total dissolved lead dissolution curves at short time scales (hr.). All equilibrium dissolved lead concentrations were achieved in 40 minutes or less, and matched trends from previous studies; pH 7.5 and pH 10 corresponding to the highest and …


Chemical And Hydrodynamic Mechanisms For Long-Term Geological Carbon Storage, Susan J. Altman, Wen Deng, For Full List Of Authors, See Publisher's Website. May 2014

Chemical And Hydrodynamic Mechanisms For Long-Term Geological Carbon Storage, Susan J. Altman, Wen Deng, For Full List Of Authors, See Publisher's Website.

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Geological storage of CO₂ (GCS), also referred to as carbon sequestration, is a critical component for decreasing anthropogenic CO₂ atmospheric emissions. Stored CO₂ will exist as a supercritical phase, most likely in deep, saline, sedimentary reservoirs. Research at the Center for Frontiers of Subsurface Energy Security (CFSES), a Department of Energy, Energy Frontier Research Center, provides insights into the storage process. The integration of pore-scale experiments, molecular dynamics simulations, and study of natural analogue sites has enabled understanding of the efficacy of capillary, solubility, and dissolution trapping of CO₂ for GCS. Molecular dynamics simulations provide insight on relative wetting of …


Effect Of Crumb Rubber Dissolution On Low-Temperature Performance And Aging Of Asphalt-Rubber Binder, Amir Ghavibazoo, Magdy Abdelrahman Jan 2014

Effect Of Crumb Rubber Dissolution On Low-Temperature Performance And Aging Of Asphalt-Rubber Binder, Amir Ghavibazoo, Magdy Abdelrahman

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Asphalt binder plays a critical role in defining the low-temperature performance of asphalt pavement, and, therefore, enhancing its mechanical behavior at low service temperatures through modification always has been of great interest. Crumb rubber modification of asphalt is one of the common practices in the industry. However, the effect of a crumb rubber modifier (CRM) on low-temperature performance of the binder is not well understood. A CRM swells by absorbing the aromat-ics and light molecular components of asphalt at low interaction temperatures (i.e., 160°C) and dissolves at higher interaction temperatures (i.e., 190°C, 220°C). Each of those activities affects the performance …


Effects Of Interaction Conditions On Internal Network Structure Of Crumb Rubber-Modified Asphalts, Mohyeldin Ragab, Magdy Abdelrahman Jan 2014

Effects Of Interaction Conditions On Internal Network Structure Of Crumb Rubber-Modified Asphalts, Mohyeldin Ragab, Magdy Abdelrahman

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Investigation of the effect of interaction conditions on the development of the internal network structure of crumb rubber-modified asphalt (CRMA) was carried out. Enhancements in the CRMA physical properties, such as stiffness, expressed in the complex modulus (G*), and elasticity, expressed in the phase angle (δ), as a result of the development of three-dimensional (3-D) entangled network structure were achieved. These results came from controlling the interaction conditions of CRMA synthesis to regulate the crumb rubber-modified (CRM) components that were responsible for the formation of the 3-1) entangled network structure. Dissolution tests and thermogravimetric analysis (TGA) were performed on the …