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Influence Of Water Chemistry Parameters On The Dissolution Rate Of The Lead (Ii) Carbonate Hydrocerussite, Caitlin Se Kushnir Dec 2014

Influence Of Water Chemistry Parameters On The Dissolution Rate Of The Lead (Ii) Carbonate Hydrocerussite, Caitlin Se Kushnir

Electronic Thesis and Dissertation Repository

This work has focused on the kinetic dissolution of the lead (II) carbonate hydrocerussite (Pb3(CO3)2(OH)2) under four pH conditions (7.5, 8, 9, 10), three dissolved inorganic concentrations (DIC; 10, 20, 50 mg C/L), and three initial hydrocerussite concentrations (10, 20, 50 mg/L) in batch experiments. Experiments were performed in at least duplicate to determine total dissolved lead dissolution curves at short time scales (hr.). All equilibrium dissolved lead concentrations were achieved in 40 minutes or less, and matched trends from previous studies; pH 7.5 and pH 10 corresponding to the highest and …