Civil and Environmental Engineering Commons^™

The Reactivity Of Dissolved Organic Matter For Disinfection By-Product Formation, Mehmet Kitis, Tanju Karanfil, James E. Kilduff

Tanju Karanfil

Dissolved organic matter (DOM) in 6 water samples collected from 4 surface waters were fractionated using some or all of 5 physicochemical separation processes (activated carbon and XAD-8 batch adsorption, alum coagulation, ultrafiltration (UF), and XAD-8 column fractionation). Activated carbon, XAD-8 batch adsorption and alum coagulation processes fractionated DOM by preferentially removing high-SUVA components from solution. The XAD-8 column method fractionated DOM into hydrophobic and hydrophilic components while UF separated DOM into different size fractions. Over 40 DOM fractions, characterized using carbon-normalized (specific) ultraviolet absorbance (SUVA), were obtained for each water. Trihalomethane (THM) and haloacetic acid (HAA_9) formation after chlorination …