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Full-Text Articles in Complex Fluids

The Hydrodynamic Behavior Of An Inverse Liquid-Solid Circulating Fluidized Bed, Amin Jaberi Apr 2014

The Hydrodynamic Behavior Of An Inverse Liquid-Solid Circulating Fluidized Bed, Amin Jaberi

Electronic Thesis and Dissertation Repository

In this work the hydrodynamic behavior of an inverse liquid-solid circulating fluidized bed (ILSCFB) system was studied. In addition, the hydrodynamic characteristic of the inverse liquid-solid fluidization under the conventional fluidization regime was also studied. The system consists of a downer with an inner column diameter of 7.6 cm and a height of 5.4 meters, an upcomer (riser) with an inner column diameter of 20 cm, a separator, and feeding and returning pipes which connect the downer and the upcomer. Based on the axial hydrodynamic behavior of the ILSCFB, it was found that the axial solids holdup in the downer …


Effect Of Ionic Liquid Electrolytes In Dsscs With Titanium Dioxide (Tio2) Inverse Opal Structures, Naomi S. Ramesar Jan 2014

Effect Of Ionic Liquid Electrolytes In Dsscs With Titanium Dioxide (Tio2) Inverse Opal Structures, Naomi S. Ramesar

Dissertations and Theses

Dye-sensitized solar cells (DSSC) are low-cost alternatives to conventional solar cells that can work well in low-light conditions. Despite considerable study on improving the efficiency of DSSCs, the current liquid electrolyte cell has plateaued at a conversion efficiency of ~ 12%. A major problem with these cells regarding their applicability is the low viscosity and high volatility of the toxic electrolyte, i.e., acetonitrile, which cause leakage and volatilization. We propose that using ionic liquids (ILs), which are more viscous, less volatile, and conductive, may be more suitable electrolytes. However, one unwanted side effect of the higher viscosity of the ILs …