Chemical Engineering Commons^™

Liquid-Liquid Dispersion In Agitated Vessels Provided With Multiple Impellers, Yu-Tsang Huang

Theses

Baffled vessels with multiple impellers are widely used in industry to generate liquid-liquid dispersions. In this work, a new method to determine the minimum agitation speed for complete dispersion in two immiscible liquids was developed. This method was conceived to replace the traditional visual observation method that has been extensively used in the past for this purpose. The minimum agitation speeds for liquid-liquid dispersion with single and multiple impellers in baffled vessel were also measured. The effect of a number of variables such as size and type of impellers, size of tank, impeller location, spacing between impellers, and dispersed phase …

Polymer Research In Austria. I: Introduction And The Facilities, Otto Vogl, Josef Schurz, Bernd Thrattnigg, Klaus Hummel, Wolfgang Daimler, Klaus Lederer

Otto Vogl

No abstract provided.

Japan-U.S. Seminar On Polymer Synthesis, Otto Vogl, Hiroyuki Nishide

Otto Vogl

No abstract provided.

Structural, Depositional, And Diagenetic Controls On Reservoir Development: St. Peter Sandstone, Newaygo County, Michigan, Mark S. Caldwell

Masters Theses

Enhanced reservoir quality in the Middle Ordovician St. Peter Sandstone is observed in gas bearing zones in wells located on domal structures. Geometry and degree of this enhanced porosity development is the result of the interplay of structural, depositional, and diagenetic controls. An integrated subsurface study of the Woodville/Goodwell field area was performed in order to document controls on hydrocarbon accumulation.

Recurrent structural growth of domal features throughout the Paleozoic is well documented by isopach mapping. Burial and thermal history studies indicate that hydrocarbons were generated in Ordovician aged source rocks during late Devonian to early Mississippian time, and accumulated …

Solder/Polymer Composite Paste And Method, Ravi F. Saraf

Department of Chemical and Biomolecular Engineering: Patents

An improved solder/polymer fluxless composite paste interconnection material having a low reflow temperature to form electrical contacts having good bonding strength and low contact resistance. The present pastes comprise a major proportion of a meltable metal alloy powder filler, free of noble metals and preferably free of lead, a minor proportion of a solution of a temperature-stable thermoplastic polymer having a softening temperature above the melting temperature of the metal powder filler in a volatile solvent which evaporates during reflow, and a minor proportion of a fluxing agent having a boiling point lower than the reflow temperature of the composition …

Modeling Electroplating Rinse Systems Using Equation-Solving Software, Andrew C. Hillier, Clifford W. Walton

Andrew C. Hillier

Microcomputers are finding application in a vast array of academic and industrial settings, but are under-utilized in the electroplating industries. An often overlooked tool for computer simulation, for example, is equationsolving software. Such programs can predict the performance of a process system from basic mathematical relations without requiring the operator to have extensive knowledge of sophisticated programming and numerical solution techniques. A model of a multi-tank counter-current rinse system is described, then simulated with this software, and the results compared to actual plating facility rinse data, showing the excellent predictive qualities of this approach.

Integrated Anaerobic-Aerobic System For The Biodegradation Of Highly Chlorinated Aromatic Compounds, Cheng-Ming Kung

Dissertations

A two-step process was developed for the complete mineralization of hazardous chlorinated aromatic compounds. The system consisted of an anaerobic reactor, in which reductive dehalogenation took place, coupled with an aerobic reactor in which the complete mineralization of the products of the anaerobic dehalogenation occurred.

A mixed anaerobic culture from a municipal sewage treatment plant was enriched and then immobilized on silica-based porous beads to treat 2,4,6-trichlorophenol (TCP), which is the model target compound in this work. In the anaerobic reactor, TCP was degraded to 2,4-dichlorophenol which was, in turn, reduced to 4-chlorophenol (4-CP). Stoichiometric amounts of 4-CP were recovered …

Biodegradation Of Phenol And 4-Chlorophenol Using A Single Species In A Sequencing Batch Reactor, Kung-Wei Wang

Theses

Biodegradation of phenol and 4-chlorophenol (4CP) using Pseudomonas putida (ATCC 17514) was studied in batch and sequencing batch reactors. Batch experiments were first performed in order to reveal the kinetics of biodegradation for each substrate. 4-Chlorophenol was degradable only in the presence of phenol, or immediately after exposure of the organism to phenol. It was postulated that an enzyme induced by the presence of phenol was necessary to initiate degradation of 4-chlorophenol.

A mathematical model was then developed to describe the dynamic behavior of both substrates in a sequencing batch reactor (SBR). The model utilized rate parameters obtained from batch …

Thermal Characterization Of Carbon Monoxide Oxidation Catalysts Using Thermogravimetric Analysts And Differential Scanning Calorimetry, Rene A. Bartgis

Chemistry & Biochemistry Theses & Dissertations

Catalysts composed of platinum and/or palladium on tin (IV) oxide supports, with and without silica gel, as well as catalysts composed of gold on manganese oxide, have been developed for the recombination of carbon monoxide and oxygen to form carbon dioxide for use in carbon dioxide lasers. A thermogravimetric method and a differential scanning calorimetric method have been developed for the thermal characterization of these catalysts. The mass loss data and the enthalpy changes determined as the catalysts lost water were then related to existing activity data for these catalysts. No relationship was found between the thermal data and the …

Crystallization Kinetics And Polyblends Of Poly(Ethylene Terephthalate) Recycled From Post-Consumer Beverage Bottles, Peming Peter Hsu

Dissertations

In order to reduce waste generation, and comply with state and federal laws, plastic beverage bottles are usually undergoing recycling. Poly(ethylene terephthalate) [PET], which is the main component the bottles are made of, cannot be used for manufacturing new food containers, and has to be used for manufacturing other end consumer products. The recycled PET is a cheap material, but its use is problematic due to the low crystallization rates of PET. The present study investigates ways of accelerating PET crystallization by using inorganic carbonate salts as nucleating agents. This study also explores the possibility of forming polymer blends based …

An Experimental Investigation Of The Finite Time Efficiency Of A Peltier Refrigeration Device, Thomas Schneider

Dissertations and Theses

Since the need of energy conservation has become more and more urgent in the past decades, there has been an increased interest in the study and development of more efficient energy conversion systems. One of the fields that have arisen from that endeavor is a branch of physics called Finite Time Thermodynamics (FIT). It may be said that FIT was initiated through the famous paper by Curzon and Ahlborn (1975) that established new bounds on the efficiency of a finite time Carnot heat engine. Before, the traditional treatments gave a fundamental upper limit on the efficiency of any heat engine. …

Studies Of Mathematical Modelling And Experimental On-Line Measurement For The Tubular Film Blowing Process, Cheng-Chien Liu

Masters Theses

An experimental and analytical study of the process of blown film extrusion was carried out. On-line measuring techniques were used to follow the dynamics and temperature profiles occurring in the process. The applicability of a mathematical model which includes a non-isothermal crystallization rate equation was tested. Subsequently, a new simplified model derived from a modified force balance was proposed and examined.

Linear low density polyethylene, LLDPE, (melt flow index 1.0) provided by Dow Chemical Company was used in the experimental part of the study. On-line measurements for radius, thickness, velocity and temperature as a function of distance from the extrusion …

Solutal Partition Coefficients In Nickel-Based Superalloy Pwa-1480, Surendra N. Tewari, M. Vijayakumar, James E. Lee, P. A. Curreri

Chemical & Biomedical Engineering Faculty Publications

Solutal profiles in dendritic single-crystal specimens of PWA-1480 nickel-base superalloy, which were directionally solidified and quenched, were examined on several transverse cross-sections to obtain the partition coefficients. Similar to their nickel-base binaries, the partition coefficients of tantalum, titanium, and aluminum were found to be less than unity; those of tungsten and cobalt were greater than unity. The partition coefficients were temperature independent in the range 1584-1608 K. The contribution of solid-state diffusion to microsegregation was observed to be negligible.

Interaction Of Sodium, Sulfur, And Silica During Coal Combustion, Thomas A. Erickson, Douglas K. Ludlow, Steven A. Benson

Chemical and Biochemical Engineering Faculty Research & Creative Works

The Interaction of Sodium, Sulfur, and Silica at Conditions Typical in a Pulverized Coal Furnace Was Investigated by using Both Model Mixtures and a Synthetic Coal. the Model Mixtures Consisted of Selected Inorganic Constituents that Were Well Mixed in Proportions Typically Found in Low-Rank Coal. the Synthetic Coal Consisted of a Furfuryl Alcohol Polymer with Appropriate Amounts of Sodium, Sulfur, and Silica to Duplicate the Characteristics of Low-Rank Coal. the Model Mixtures and Synthetic Coal Were Burned in a Laminar Flow (Drop-Tube) Furnace at 900, 1100, 1300, and 1500 °C and Residence Times of 0.1,0.5,1.5, and 2.4 S. the Resulting …

Fabrication Of High-Conductivity, Transparent Electrodes With Trenched Metal Bus Lines, Otto J. Gregory, R. J. Zeto, E. Hryckowian, K. A. Burbank

Chemical Engineering Faculty Publications

A novel transparent electrode system has been developed for thin film electroluminescent displays in which the poor conductivity of the indium-tin-oxide (ITO) electrodes has been augmented by high-conductivity buses of thick aluminum or silver. The augmented electrode system consists of patterned ITO electrodes, 200 Fm wide, centered over narrow aluminum or silver lines 40 ~m wide and separated by an intermediate diffusion barrier film of titanium to promote adhesion to the ITO and prevent blackening of the main ITO electrode by interfacial reactions. The sheet resistances of the augmented ITO electrodes (A1-Ti-ITO and Ti-Ag-Ti-ITO) were lowered by two orders of …

A Comparative Analysis Of The Efficacy Of Zero-Order, First-Order And Monod Kinetic Models In Representing Raw Aerobic Biodegradation Data, Andrew I. Bakun

Theses

A total of 148 raw aerobic biodegradation data sets from batch and continuous stirred-tank reactors were extracted from the open literature and previous NJIT MS theses. Kinetic analysis of each of these data sets was performed with respect to the following commonly used empirical models: (1) zero-order, (2) first-order, and (3) Monod. Two constant-biomass versions of each model were evaluated; one in which So (i.e., the boundary condition for substrate concentration at time equal to zero) was assumed to be equal to the measured value of the initial substrate concentration and the other in which So was treated as a …

Network Model Investigation Of Gas Transport In Bidisperse Porous Adsorbents, John H. Petropoulos, John K. Petrou, Athanasios I. Liapis

Chemical and Biochemical Engineering Faculty Research & Creative Works

A capillary network model consisting of a micropore network permeated by one of macropores of randomly varying size has been constructed. Although simplified (to keep computer space and time requirements low) in relation to a real bidisperse porous adsorbent or catalyst, it embodies the salient pore structural features likely to determine the gas-transport behavior of such porous solids. Suitable model calculations of Knudsen gas-phase and surface diffusion enabled us to (i) validate useful approximate methods for the more economical evaluation of network permeability and (ii) demonstrate certain important characteristic effects of nonrandom bidisperse pore structure on transport behavior and their …

Reactivities Of Some Aromatic Compounds At Supercritical Water Conditions, Chun-Cheng Tsao

Masters Theses

The goals of this study are the removal of nitrogen from the extraction products of coal by Supercritical Water and the development of an understanding of the reactions leading to this removal. Six model compounds with structures similar to the intermediates of the coal liquefaction processes were studied. Benzylamine generated toluene through hydrogen abstraction after the C-N bond rupture. To a lesser extent, the oxidation of the benzylic carbon took place leading to benzene formation. Both reaction pathways occurred with equal probability for benzylidenebenzylamine, producing comparable yields of benzene and toluene. Benzaldehyde generated benzene through the oxidation/decarboxylation sequence. Benzyl alcohol …

Mathematical Modeling Of Mass Transfer In Microvascular Wall And Interstitial Space, Daekyung Kim

Dissertations

The dynamics of macromolecular transport across the microvascular wall and into the adjoining interstitial space was studied in the hamster cheek pouch using intravital fluorescence microscopy in combination with digital image processing. Fluorescein isothiocyanate-labe led dextrans (FITC-Dx) of 70,000 and 150,000 daltons were used as tracers. In each experiment, the time-dependent extravasation of FITC-Dx from a leakage site in a blood vessel was videotaped for about 2 hours. The macromolecular transport from individual microvessels was quantified by digital video-image processing. Histograms of the light intensity distributions for selected fields at various times were obtained and then converted to the interstitial …

Mathematical Modeling Of Chemical Vapor Deposition Processes And Its Application To Thin Film Technology, Norman W. Loney

Dissertations

A number of workers in the field of Chemical vapor deposition (CVD) have presented mathematical models in the literature. Some workers were able to produce analytical expressions for the interwafer concentration profile. These analytical expressions were based entirely on zero or first order chemical reaction rates. Until now, it appears that a chemical reaction rate expression that is not zero or first order directly, must be handled by a numerical scheme.

Presented herein is a mathematical model with an analytical interwafer concentration profile. This concentration profile is neither zero nor first order but shifts from zero to first order as …

Kinetic Studies On Pyrolytic And Oxidative Decomposition Of Chlorocarbons In A Tubular Flow Reactor, Yang Soo Won

Dissertations

Chloroform decay and product distributions were distinctly different in the absence and presence of added O₂ and/or CH₄. Increases in O₂ concentration were observed to speed reagent loss, with a slower decay of chloroform observed for the CHCl₃/CH4/Ar pyrolysis system. In CHCl₃/CH₄/O₂, the major products were C₂Cl4, CH2CCl₂, C₂HCl₃, CO and CO₂ over a wide temperature range. Minor products included CH₂Cl₂, CH₃Cl, and C2H₃Cl. When CH₄ reactant was not present, …

Adiabatic Kinetic Studies Of The Cytidine/Acetic Anhydride Reaction By Utilizing Temperature Versus Time Data, Joseph John Shatynski

Theses

It is possible to predict the kinetics of a reaction by using temperature versus time data under adiabatic conditions. This method was used for the cytidine/acetic anhydride reaction using a RC1 Mettler Reaction Calorimeter.

The authenticity of the experimental adiabatic system was verified by determining the kinetic parameters of a known reaction (hydrolysis of acetic anhydride) and comparing them to literature values.

For example, the average experimental activation energy, heat of reaction, and ln k₀ values for the hydrolysis of acetic anhydride were 11.2 ±.5 kcal/gmole, -14.4 ± .2 kcal/gmole, and 12.74 ± .94 sec^-1, respectfully, while …

Charcoal Catalyzed Ozone Decomposition Of Organic Pollutants In Water, Kin Ho

Theses

A laboratory study has been performed on the wastewater treatment (destruction of organic species in water) using a novel process called Integrated Adsorption-Oxidation (IAO) where activated carbon is being utilized as a catalyst-adsorbent, and ozone as oxidant. The results of ozonation alone on the pollutants in water are also reported to provide a comparison with the adsorption-oxidation scheme in semi-batch reactions. All experiments were conducted at room temperature in a semi-batch reactor using five (water soluble) representative chemicals as pollutants: Aniline, Acetamide, Pyridine, N,N-dimethyl formamide and O-cresol. We also studied two volatile compounds: Trichloroethylene and Chloroform. Phenol was studied in …

Catalytic Oxidation Of Chlorinated Compounds Over Pdo/Al2o3 On A Monolith, Tai-Chiang Yu

Theses

The catalytic oxidation of trichloroethylene(TCE) and dichloromethane (DCM) was investigated over a catalyst containing 4% PdO on Al₂O₃ washcoat and on a cordierite monolith with 400 channels per in². Reactivity and selectivity of the catalyst for the destruction of 200 ppm C₂HCl₃ and 500 ppm CH₂Cl₂ in air was evaluated over the temperature range 250 to 550 °C. This research was conducted in a tubular reactor system at space velocities of 4,000 to 24,000 v/v/hr. It was found that complete oxidation occurs at 500°C for DCM and 550°C for …

Removal Of Chlorine From Chlorine-Nitrogen Mixture In A Film Of Liquid Water, Sarwan S. Sandhu

Chemical and Materials Engineering Faculty Publications

In industry there are many examples of absorption of a gas with or without chemical reaction in the liquid phase. In physical absorption, a particular gaseous component is removed from a gas mixture due to its larger solubility in the liquid phase solvent. The removal of butane and pentane from a refinery gas mixture by a heavy oil in the liquid phase is an example of physical absorption. In absorption with chemical reaction, the gaseous component to be removed transfers across the gas-liquid interface due to a difference in the bulk chemical potentials or concentrations in the two phases. The …

Two-Phase Flow Measurement, Glenn Brenneke

Opportunities for Undergraduate Research Experience Program (OURE)

Liquid fuel engines have many applications in today's world. Diesel, spark-ignition, and gas turbine engines, and furnaces are just a few of the many applications of liquid fuel sprays. With the rising cost of fuel and need for energy conservation it is imperative that more efficient engines be developed. Analyzing liquid fuel spray characteristics non-intrusively could unlock the door to powerful highly efficient engines in the future.

The vaporization of fuel is mandatory in liquid fuel combustion. Vaporization and the fuel to air ratio are important characteristics of the spark-ignition engine. Compression ignition is controlled by the parameters of the …

Model Calculational Approach To The Conformation Of Adsorbed Polypeptide Fragments, Timothy J. Mckeon

Opportunities for Undergraduate Research Experience Program (OURE)

The focus of the paper is to examine possible conformational changes of peptides when placed in the presence of a poly-synthetic material. A major concern in the pharmaceutical industry is the loss of potency of polypeptide drug products during processing, packaging and storage. An example of this is polymer syringes being used in place of glass ones. The effect is that some protien-derived products experience structural changes due to contact with the polymer. This is otherwise known as surface denaturation. In order to understand the energetics of interfacial polypeptide systems, a calculational approach was used via the program Alchemy. The …

Establishment Of A Phase/Doppler Particle Analyzer For Two-Phase Flow Experiments, J. L. Burget

Opportunities for Undergraduate Research Experience Program (OURE)

The accurate measurement of liquid spray drop size and velocity is important in a variety of applications. These applications include agricultural sprays, furnaces, spark ignition and compression ignition engines, gas turbines, and a variety of industrial processes. Because of the need to improve combustion efficiency and minimize soot and other harmful emissions, one of the most active areas of research is fuel spray combustion. Quantitative measurements of the vapor phase in fuel sprays is vital to the understanding of spray dynamics and the operation of combustion devices.

There are various measurement techniques available to measure vapor phase characteristics in a …

Vapor-Liquid Equilibrium Data For The Nh3-H2o System And Its Description With A Modified Cubic Equation Of State, Thomas M. Smolen, David B. Manley, Bruce E. Poling

Chemical and Biochemical Engineering Faculty Research & Creative Works

New pressure-temperature-overall composition vapor-liquid equilibrium (VLE) data are reported for the ammonia-water system at five temperatures between 20 and 140 °C and up to 500 pela. These data have been converted to T-P-x data, and vapor-phase compositions have been calculated by means of a Rediich-Kwong equation of state modified to Include Peneloux's volume translation and a density-dependent mixing rule. In order to achieve agreement of calculated vapor-phase compositions with previous literature results, H was necessary to use different kij values In the vapor and liquid phases. © 1991, American Chemical Society. All rights reserved.

Sedimentology Of The Bedford-Berea Sequence (Early Mississippian), Williams Field, Michigan, David Alan Balthazor

Masters Theses

The Berea Sandstone has produced in excess of 1.6 million barrels of oil in the Williams field since discovery in 1980. Seven lithofacies are identified from conventional core in the Bedford-Berea sequence. These facies are interpreted as deltaic deposits comprising prodelta (Bedford Shale), delta front, destructive marine shale, abandoned distributary channel-fill, interdistributary bay-fill, transgressive marine sandstone, and marine shale (Sunbury Shale) facies. Passive channel-fill facies truncate reservoir sandstone bodies and compartmentalize the field NW-SE across the trend of the northwestplunging anticline.

The two reservoir facies in the Williams field are the delta front and transgressive marine sandstones. The sandstone framework …