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Articles 31 - 60 of 84
Full-Text Articles in Chemical Engineering
Project-Based Introduction To Engineering -- Course Assessment, Samuel Bogan Daniels, Michael Collura, Bouzid Aliane, Jean Nocito-Gobel
Project-Based Introduction To Engineering -- Course Assessment, Samuel Bogan Daniels, Michael Collura, Bouzid Aliane, Jean Nocito-Gobel
Engineering and Applied Science Education Faculty Publications
The School of Engineering and Applied Science at the University of New Haven has a newly developed project-based Introduction to Engineering course. This new course plays a central role in the new Multi-Disciplinary Engineering Foundation Spiral curriculum as the first semester course for all engineering freshmen. An assessment process was developed to determine the effectiveness of this project-based course, specifically with attention towards assessing attitudes, impact on retention, problem-solving and engineering foundation topics. This paper addresses the particular portion of the assessment process for the individual course projects and their contribution to the last two assessment categories.
Project Planning & Development For Engineering Freshmen, Bouzid Aliane, Michael Collura, Samuel Bogan Daniels, Jean Nocito-Gobel
Project Planning & Development For Engineering Freshmen, Bouzid Aliane, Michael Collura, Samuel Bogan Daniels, Jean Nocito-Gobel
Engineering and Applied Science Education Faculty Publications
The nature and background of students seeking an engineering education has changed drastically in the last decade, as has the expectations of industrial employers. Many students lack the organizational skills needed for academic success. Similar organizational skills, although more advanced, are required for managing engineering projects. A new course was developed by the faculty at the School of Engineering and Applied Science at the University of New Haven. Through this course, a key component of the Multidisciplinary Engineering Foundation Spiral, seeks to promote higher retention rates, increase student motivation and begin a confidence-building transition to professional practice. Project management concepts …
Optimization Of Cell Density And Dilution Rate In Pichia Pastoris Continuous Fermentations For Production Of Recombinant Proteins, Mehmet Inan, Michael M. Meagher, Wenhui Zhang, Chih Ping Liu
Optimization Of Cell Density And Dilution Rate In Pichia Pastoris Continuous Fermentations For Production Of Recombinant Proteins, Mehmet Inan, Michael M. Meagher, Wenhui Zhang, Chih Ping Liu
Papers in Biomolecular Engineering
This paper provides an approach for optimizing the cell density (Xc) and dilution rate (D) in a chemostat for a Pichia pastoris continuous fermentation for the extracellular production of a recombinant protein, interferon τ (INF-τ). The objective was to maximize the volumetric productivity (Q, mg INF-τ I-1 h-1), which was accomplished using response surface methodology (RSM) to model the response of Q as a function of Xc and D within the ranges 150 ≤ Xc ≤ 450 g cells (wet weight) l-1 and 0.1 μm ≤D ≤ 0.9 μm (μm =0.0678 h-1, the maximum specific growth rate obtained from a …
Hydrazine/Nitrogen Dioxide Fiber Optic Sensor, Alfred S. Andrawis, Josephine B. Santiago, Rebecca Young, Clayton J. Baum
Hydrazine/Nitrogen Dioxide Fiber Optic Sensor, Alfred S. Andrawis, Josephine B. Santiago, Rebecca Young, Clayton J. Baum
Chemistry and Chemical Engineering Faculty Publications
This paper outlines the development of a dual hydrazine/nitrogen dioxide (HZ/NO2) prototype fiber optic sensor utilizing an acid-base indicator that undergoes color changes depending on which gas is present. Bromothymol blue bromocresol green mixture (1/1) in hydrogel (1/1), produces a blue-green indicator for HZ and/or NO2. The sensor was tested several times over a period of eight weeks and the response was consistent and proved the feasibility of dual HZ/NO2 leak detection. Prototype sensor construction, the hardware, and the software of the electronic interrogator circuitry are briefly explained. The paper presents a summary of sensor response when exposed to 52 …
Pictures From My Life With Polymer Science: Album 6, Otto Vogl
Pictures From My Life With Polymer Science: Album 6, Otto Vogl
Emeritus Faculty Author Gallery
No abstract provided.
Role Of Curvature Elasticity In Sectorization And Ripple Formation During Melt Crystallization Of Polymer Single Crystals, Rujul Mehta, Wirunya Keawwattana, Andrew L. Guenthner, Thein Kyu
Role Of Curvature Elasticity In Sectorization And Ripple Formation During Melt Crystallization Of Polymer Single Crystals, Rujul Mehta, Wirunya Keawwattana, Andrew L. Guenthner, Thein Kyu
College of Polymer Science and Polymer Engineering
The present article focuses on theoretical elucidation of possible effect of mechanical deformation on spatio-temporal emergence of unusual polymer morphology subjected to quiescent isothermal crystallization conditions. The present theory developed is based on a phase field model consisted of non-conserved time dependent Ginzburg-Landau equation having an asymmetric double well potential in the crystal order parameter signifying metastability for crystallization, coupled with the chain tilt angle involving curvature elasticity and strain recovery potentials. Under quiescent crystallization conditions, the curvature elasticity term is needed to discern the emergence of sectorized single crystals. Upon coupling with the strain recovery potential, the numerical calculation …
Modification Of Statistical Threading In Two-Component Pseudorotaxane Melts Using The Amphiphilic Approach And Variations In The Confinement Geometry, Sagar S. Rane, Wayne L. Mattice, Coleen Pugh
Modification Of Statistical Threading In Two-Component Pseudorotaxane Melts Using The Amphiphilic Approach And Variations In The Confinement Geometry, Sagar S. Rane, Wayne L. Mattice, Coleen Pugh
College of Polymer Science and Polymer Engineering
Recently we described a coarse-grained model of poly(ethylene oxide) and then employed that model to study the amount of spontaneous threading of cyclic molecules by linear chains in the melt [C. A. Helfer, G. Xu, W. L. Mattice, and C. Pugh, Macromolecules 36, 10071 (2003)]. Since the amount of statistical threading at equilibrium is small, there is interest in identifying physical changes in the system that will increase the threading. We now use that coarse-grained model to investigate the effect on threading of various hypothetical (but feasible) modifications to the two-component system of macrocycles and linear chains in the melt, …
The Influence Of Strontium Substitution In Fluorapatite Glasses And Glass-Ceramics, R. G. Hill, A. Stamboulis, R. V. Law, A. Clifford, Mark R. Towler, C. Crowley
The Influence Of Strontium Substitution In Fluorapatite Glasses And Glass-Ceramics, R. G. Hill, A. Stamboulis, R. V. Law, A. Clifford, Mark R. Towler, C. Crowley
Chemical and Biochemical Engineering Faculty Research & Creative Works
Strontium is often substituted for calcium in order to confer radio-opacity in glasses used for dental cements, Biocomposites and bio glass-ceramics. The present paper investigates the influence of substituting strontium for calcium in a glass of the following composition: 4.5SiO23Al2O 31.5P2O53CaO2CaF2, having a Ca:P ratio of 1.67 corresponding to calcium fluorapatite (Ca5(PO 4)3F). The glasses were characterized by magic angle spinning nuclear magnetic resonance (MAS-NMR), by differential scanning calorimetry (DSC) and X-ray powder diffraction (XRD). The 29Si, 27Al and 31P NMR spectra for the glasses with …
Fundamental Chemistry Of U And Pu In The Tbp-Dodecane-Nitric Acid System, Kenneth Czerwinski, Byron Bennett
Fundamental Chemistry Of U And Pu In The Tbp-Dodecane-Nitric Acid System, Kenneth Czerwinski, Byron Bennett
Separations Campaign (TRP)
The speciation of hexavalent U and tetravalent Pu will be examined in the TBP-dodecane-nitric acid systems. This topic is chosen based on data needs for separation modeling identified by the AFCI. Emphasis will be placed on studying the influence of nitrate and acetohydroxamic acid on U and Pu speciation as well as conditions where a third phase forms in the organic phase. The organic phase will be 30% TBP in dodecane. Equal volumes of aqueous and organic phase will be used. The speciation of the actinides in the aqueous and organic phase will be determined by a number of different …
Growth And Transport Properties Of Complementary Germanium Nanowire Field Effect Transistors, Andrew B. Greytak, Lincoln J. Lauhon, Mark S. Gudiksen, Charles M. Lieber
Growth And Transport Properties Of Complementary Germanium Nanowire Field Effect Transistors, Andrew B. Greytak, Lincoln J. Lauhon, Mark S. Gudiksen, Charles M. Lieber
Faculty Publications
n- and p-type Ge nanowires were synthesized by a multistep process in which axial elongation, via vapor–liquid–solid (VLS) growth, and doping were accomplished in separate chemical vapor deposition steps. Intrinsic, single-crystal, Ge nanowires prepared by Au nanocluster-mediated VLS growth were surface-doped in situ using diborane or phosphine, and then radial growth of an epitaxial Ge shell was used to cap the dopant layer. Field-effect transistors prepared from these Ge nanowires exhibited on currents and transconductances up to 850 µA/µm and 4.9 µA/V, respectively, with device yields of >85%.
Pictures From My Life With Polymer Science: Album 7, Otto Vogl
Pictures From My Life With Polymer Science: Album 7, Otto Vogl
Emeritus Faculty Author Gallery
No abstract provided.
Characterisation Of The Glass Fraction Of A Selection Of European Coal Fly Ashes, J. Henry, Mark R. Towler, K. T. Stanton, X. Querol, N. Moreno
Characterisation Of The Glass Fraction Of A Selection Of European Coal Fly Ashes, J. Henry, Mark R. Towler, K. T. Stanton, X. Querol, N. Moreno
Chemical and Biochemical Engineering Faculty Research & Creative Works
Fly ash largely consists of the inorganic content of coal that remains after combustion. The crystalline phases present in fly ash may form upon cooling of a molten alumino-silicate glass. This view is supported by the spherical shape of many fly ash particles, inferring that they have gone through a viscous fluid state. The amorphous content in fly ash is believed to dominate reactivity behaviour, under both alkaline and acid conditions, because glasses have a higher potential energy than the equivalent crystal structure and the variation of bond angles and distances in a glass makes the bond breakage easier. It …
Heat Transfer In A Thin Liquid Film In The Presence Of An Electric Field, Rama Subba Reddy Gorla, Jorge E. Gatica, Bahman Ghorashi, Pijarn Ineure, Larry W. Byrd
Heat Transfer In A Thin Liquid Film In The Presence Of An Electric Field, Rama Subba Reddy Gorla, Jorge E. Gatica, Bahman Ghorashi, Pijarn Ineure, Larry W. Byrd
Chemical & Biomedical Engineering Faculty Publications
Heat transfer enhancement in an evaporating thin liquid film utilizing a electric field under isothermal interfacial condition is presented. A new mathematical model subjected to van der Waals attractive forces, capillary pressure, and an electric field is developed to describe the heat transfer enhancement in the evaporating thin liquid film. The effect of the electrostatic field on the curvature of the thin film, evaporative flux, pressure gradient distribution, heat flux, and heat transfer coefficient in the thin film is presented. The results show that applying an electric field can enhance heat transfer in a thin liquid film significantly. in addition, …
A Sequential Approach To Modeling Catalytic Reactions In Packed-Bed Reactors, Jing Guo, Muthanna H. Al-Dahhan
A Sequential Approach To Modeling Catalytic Reactions In Packed-Bed Reactors, Jing Guo, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
A Sequential Modeling Approach is Proposed to Simulate Catalytic Reactions in Packed-Bed Reactors. the Hydrogenation of Alpha-Methylstyrene and Wet Oxidation of Phenol Are Selected as Studied Cases. the Modeling Scheme Combines a Reactor Scale Axial Dispersion Model with a Pellet Scale Model. Without Involving Any Fitting Parameters, Such an Approach Accounts for the Non-Linear Reaction Kinetics Expression and Different Types of Pellet-Liquid Wetting Contact. to Validate the Developed Modeling Scheme and the Parallel Approach Reported in the Literature, the Experimental Observations for Hydrogenation of Alpha-Methylstyrene to Cumene Have Been Employed. the Predicted Results by Both Approaches Agree Reasonably with the …
Developing A Sensing System For The Measurement Of Oxygen Concentration In Liquid Pb-Bi Eutectic, Bingmei Fu, Yingtao Jiang, Jian Ma
Developing A Sensing System For The Measurement Of Oxygen Concentration In Liquid Pb-Bi Eutectic, Bingmei Fu, Yingtao Jiang, Jian Ma
Mechanical Engineering Faculty Research
Although liquid lead-bismuth eutectic (LBE) is a good candidate for the coolant in the subcritical transmutation blanket, it is known to be very corrosive to stainless steel, the material of the carrying tubes and the containers. Such a corrosion problem can be prevented by producing and maintaining a protective oxide layer on the exposed surface of stainless steel. The proper formation of this oxide layer critically depends on the accurate measurement and control of the oxygen concentration in the liquid LBE. YSZ (Yttria Stabilized Zirconia) oxygen sensors, using molten bismuth saturated with oxygen as the reference, have been utilized to …
Molecular-Dynamics Simulation Of The Effect Of Ions On A Liquid–Liquid Interface For A Partially Miscible Mixture, Richard L. Rowley, Kent E. Wardle, Eric Carlson, Douglas Henderson
Molecular-Dynamics Simulation Of The Effect Of Ions On A Liquid–Liquid Interface For A Partially Miscible Mixture, Richard L. Rowley, Kent E. Wardle, Eric Carlson, Douglas Henderson
Faculty Publications
Molecular-dynamics simulations were performed to model the effect of added salt ions on the liquid-liquid interface in a partially miscible system. Simulations of the interface between saturated phases of a model 1-hexanol + water system show a bilayer structure of 1-hexanol molecules at the interface with OH heads of the first layer directed into the water phase and the opposite orientation for the second layer. The alignment of the polar OH groups at the interface stabilizes a charge separation of sodium and chloride ions when salt is introduced into the aqueous phase, producing an electrical double layer. Chloride ions aggregate …
Pictures From My Life With Polymer Science: Album 8, Otto Vogl
Pictures From My Life With Polymer Science: Album 8, Otto Vogl
Emeritus Faculty Author Gallery
No abstract provided.
Dynamic Contact Angles Under Evaporation, Robert M. Ybarra, Partho Neogi
Dynamic Contact Angles Under Evaporation, Robert M. Ybarra, Partho Neogi
Chemical and Biochemical Engineering Faculty Research & Creative Works
Wetting kinetics in the presence of heat transfer, evaporation, and Marangoni effect has been explored using a method used by Joanny and de Gennes [C. R. Acad. Sci. Ser. II 299, 279 (1984)]. The method solves for the dynamic contact angle alpha by equating the rate of surface work to the rate of dissipation. The result in the form of dynamic contact angle alpha as a function of capillary number Ca agrees well with existing experimental data. Qualitative comparisons have been made in cases where quantitative data do not exist. Finally, a form of contact line instability is predicted, for …
Causes Of Proteolytic Degradation Of Secreted Recombinant Proteins Produced In Methylotrophic Yeast Pichia Pastoris: Case Study With Recombinant Ovine Interferon-T, Mehmet Inan, Michael M. Meagher, Bradley A. Plantz, Jayanta Sinha
Causes Of Proteolytic Degradation Of Secreted Recombinant Proteins Produced In Methylotrophic Yeast Pichia Pastoris: Case Study With Recombinant Ovine Interferon-T, Mehmet Inan, Michael M. Meagher, Bradley A. Plantz, Jayanta Sinha
Papers in Biochemical Engineering
It was observed that during fermentative production of recombinant ovine interferon-H (r-oIFN-H ) in Pichia pastoris, a secreted recombinant protein, the protein was degraded increasingly after 48 h of induction and the rate of degradation increased towards the end of fermentation at 72 h, when the fermentation was stopped. Proteases, whose primary source was the vacuoles, was found in increasing levels in the cytoplasm and in the fermentation broth after 48 h of induction and reached maximal values when the batch was completed at 72 h. Protease levels at various cell fractions as well as in the culture supernatant were …
Bio-Chip, Photoluminescent Methods For Identifying Biological Material, And Apparatuses For Use With Such Methods And Bio-Chips, Ravi F. Saraf
Bio-Chip, Photoluminescent Methods For Identifying Biological Material, And Apparatuses For Use With Such Methods And Bio-Chips, Ravi F. Saraf
Department of Chemical and Biomolecular Engineering: Patents
A method detects binding of molecules, advantageously without tagging molecules in the sample. A sensor is used in which is included a single stranded nucleic acid sequence and a photoluminescent material in respective layers. After the sensor is exposed to a biological sample for sufficient time for its single stranded nucleic acid sequence to bind to a material of interest, photoluminescence from the sensor can be measured. An apparatus for tagging-free detection of binding of molecules also is provided. Methods of making tagging-free sensors are provided. Also, tagging-free methods to detect binding of antigens and related devices are disclosed.
Pictures From My Life With Polymer Science: Album 9, Otto Vogl
Pictures From My Life With Polymer Science: Album 9, Otto Vogl
Emeritus Faculty Author Gallery
No abstract provided.
Growth Dynamics Of Isotactic Polypropylene Single Crystals During Isothermal Crystallization From A Miscible Polymeric Solvent, Rujul Mehta, Wirunya Keawwattana, Thein Kyu
Growth Dynamics Of Isotactic Polypropylene Single Crystals During Isothermal Crystallization From A Miscible Polymeric Solvent, Rujul Mehta, Wirunya Keawwattana, Thein Kyu
College of Polymer Science and Polymer Engineering
The present article presents a spatiotemporal growth of isotactic polypropylene (iPP) single crystals, melt crystallized from a polymeric solvent, i.e., poly (ethylene octene) copolymer that is known to be miscible with iPP. Optical and atomic force microscopic investigations reveal that the melt grown single crystals of iPP develop in the form of two parallel rows of crystal lamellae, but these crystals merge at the tips. To elucidate the mechanism of these emerging parallel rows of iPP crystals, a phase field model pertaining to solidification phenomena has been employed that involves a nonconserved crystal order parameter and a chain-tilting angle. This …
Analyzing And Modeling Of Photobioreactors By Combining First Principles Of Physiology And Hydrodynamics, Hu Ping Luo, Muthanna H. Al-Dahhan
Analyzing And Modeling Of Photobioreactors By Combining First Principles Of Physiology And Hydrodynamics, Hu Ping Luo, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Mixing in Photobioreactors is Known to Enhance Biomass Productivity Considerably, and Flow Dynamics Play a Significant Role in the Reactor's Performance, as They Determine the Mixing and the Cells' Movement. in This Work We Focus on Analyzing the Effects of Mixing and Flow Dynamics on the Photobioreactor Performance. based on Hydrodynamic Findings from the CARPT(Computer Automated Radioactive Particle Tracking) Technique, a Possible Mechanism for the Interaction between the Mixing and the Physiology of Photosynthesis is Presented, and the Effects of Flow Dynamics on Light Availability and Light Intensity Fluctuation Are Discussed and Quantitatively Characterized. Furthermore, a Dynamic Modeling Approach is …
Pictures From My Life With Polymer Science: Album 10, Otto Vogl
Pictures From My Life With Polymer Science: Album 10, Otto Vogl
Emeritus Faculty Author Gallery
No abstract provided.
Transcriptome-Based Determination Of Multiple Transcription Regulator Activities In Escherichia Coli By Using Network Component Analysis, Katy Kao, Young-Lyeol Yang, Riccardo Boscolo, Chiara Sabatti, Vwani Roychowdhury, James Liao
Transcriptome-Based Determination Of Multiple Transcription Regulator Activities In Escherichia Coli By Using Network Component Analysis, Katy Kao, Young-Lyeol Yang, Riccardo Boscolo, Chiara Sabatti, Vwani Roychowdhury, James Liao
Faculty Publications
Cells adjust gene expression profiles in response to environmental and physiological changes through a series of signal transduction pathways. Upon activation or deactivation, the terminal regulators bind to or dissociate from DNA, respectively, and modulate transcriptional activities on particular promoters. Traditionally, individual reporter genes have been used to detect the activity of the transcription factors. This approach works well for simple, non-overlapping transcription pathways. For complex transcriptional networks, more sophisticated tools are required to deconvolute the contribution of each regulator. Here, we demonstrate the utility of network component analysis in determining multiple transcription factor activities based on transcriptome profiles and …
Sger: Detection Of Bioterrorism-Linked Microbial Pathogens Using Surface Acoustic Wave Liquid Sensors, Maruicio Pereira Da Cunha, Paul J. Millard
Sger: Detection Of Bioterrorism-Linked Microbial Pathogens Using Surface Acoustic Wave Liquid Sensors, Maruicio Pereira Da Cunha, Paul J. Millard
University of Maine Office of Research Administration: Grant Reports
Bioterrorism threats and attacks in civilian environments require sensors that can rapidly and accurately detect minute quantities of pathological bioagents. Selective and inexpensive sensors are urgently needed to detect pathogens in liquid environments, including food and water supplies. Conventional laboratory analyses are time-consuming, labor-intensive and inconsistent with the expedient response required in the wake or possibility of a bioterrorist act.
The activities proposed in this Small Grant for Exploratory Research (SGER) are multidisciplinary and involve two faculty members from the University of Maine. Dr. Mauricio Pereira da Cunha, from the Department of Electrical and Computer Engineering, will provide expertise in …
8th Bratislava International Conference On Modified Polymers: Modpol2003, Otto Vogl, Maria Omastova
8th Bratislava International Conference On Modified Polymers: Modpol2003, Otto Vogl, Maria Omastova
Emeritus Faculty Author Gallery
No abstract provided.
A. Cover Page, Title Page, Table Of Contents, And Forward, Otto Vogl
A. Cover Page, Title Page, Table Of Contents, And Forward, Otto Vogl
Emeritus Faculty Author Gallery
The History of the Pacific Polymer Federation (PPF) describes the background and pursuit that was needed to create the PPF and bring it to a functioning organization. It includes a general description, as well as edited Pacific Polymer Newsletters and articles that have been written in Polymer News describing additional PPF activities and the Pacific Polymer Conferences.
B. The Signing Of The Constitution Of The Pacific Polymer Federation, Otto Vogl
B. The Signing Of The Constitution Of The Pacific Polymer Federation, Otto Vogl
Emeritus Faculty Author Gallery
The Constitution of the Pacific Polymer Federation was signed on October 19, 1987 in Tokyo, Japan at the Inter-national House in Roppongi, Tokyo by the Chairman of the ACS Division of Polymer Chemistry, S, R. Eby, and the Chair-man of the Foreign Affairs Committee, O. Vogl; by the President of the Society of Polymer Science Japan, M. Takayanagi; Chairman and Vice President for International Affairs, A. Abe. For the Polymer Division of the Royal Aus-tralian Institute of Chemistry, Chairman D.J.T. Hill and Chair-man of the International Committee, J.H. O'Donnell signed the Constitution.
C. Pacific Polymer Federation Presidents, Otto Vogl
C. Pacific Polymer Federation Presidents, Otto Vogl
Emeritus Faculty Author Gallery
Names and photographs of the presidents of the Pacific Polymer Federation.