Bioresource and Agricultural Engineering Commons^™

Characterizing And Predicting The Antimicrobial Properties Of Lignin Derivatives, Ryan Kalinoski

Theses and Dissertations--Biosystems and Agricultural Engineering

Due to the overuse of antibiotics in our society, there has been a steady rise in highly antimicrobial-resistant bacteria in the last decade. This has created a renewed interest in natural phenolic compounds for antimicrobial discovery amongst the scientific community. To this end, lignin is the most abundant naturally occurring phenolic polymer on earth and has already been known to have antimicrobial properties due to its polyphenolic structure. In addition, lignin is considered a major waste product for lignocellulosic biorefineries, and its valorization into value-added products will generate extra profit for a biorefinery, making biofuels less expensive, increasing their marketability …

Purification Of Biomass Hydrolyzates For The Promotion Of Xylose Diester Formation, Laura Fernandez

Electronic Theses and Dissertations

The application of a novel xylose isolation procedure using phenyl boronic acid esterification has been limited to the hydrolyzates of low extractive biomasses like hardwoods and agricultural resides. Hydrolyzates with lower sugar and higher extractive concentrations, like softwoods, have not yielded xylose, or even xylose diester (XDE), the first intermediate product in the new process, under the same conditions. This research applied evaporation concentration, adsorbent separation and membrane filtration to these lower performing biomass hydrolyzates to maximize the yield of the XDE formation step of the new xylose extraction process. Lab-scale tests of these techniques were applied to pine hydrolyzate …

Lignin-Derived Carbon And Nanocomposite Materials For Energy Storage Applications, Wenqi Li

Theses and Dissertations--Biosystems and Agricultural Engineering

With a growing demand for electrical energy storage materials, lignin-derived carbon materials have received increasing attention in recent years. As a highly abundant renewable carbon source, lignin can be converted to a variety of advanced carbon materials with tailorable chemical, structural, mechanical and electrochemical properties through thermochemical conversion (e.g. pyrolysis). However, the non-uniformity in lignin structure, composition, inter-unit linkages and reactivity of diverse lignin sources greatly influence lignin fractionation from plant biomass, the pyrolysis chemistry, and property of the resulting carbon materials.

To introduce a better use of lignocellulosic biomass to biofuels and co-products, it is necessary to find novel …

Fractionation And Characterization Of Lignin Streams From Unique High-Lignin Content Endocarp Feedstocks, Wenqi Li, Kirtley Amos, Mi Li, Yunqiao Pu, Seth Debolt, Arthur J. Ragauskas, Jian Shi

Biosystems and Agricultural Engineering Faculty Publications

Background: Lignin is a promising source of building blocks for upgrading to valuable aromatic chemicals and materials. Endocarp biomass represents a non-edible crop residue in an existing agricultural setting which cannot be used as animal feed nor soil amendment. With significantly higher lignin content and bulk energy density, endo-carps have significant advantages to be converted into both biofuel and bioproducts as compared to other biomass resources. Deep eutectic solvent (DES) is highly effective in fractionating lignin from a variety of biomass feedstocks with high yield and purity while at lower cost comparing to certain ionic liquids.

Results: In the present …

So2-Alcohol-Water Fractionation Of Sugarcane Straw, Asif Sharazi

Electronic Theses and Dissertations

Climate change resulting from fossil fuels combustion is motivating researchers to explore feasible routes to convert renewable biomass into biofuels and biochemicals for a sustainable society. Typically, biofuel is produced from corn or sugarcane but both feedstocks compete with human food supply. Thus, lignocellulosics as renewable feedstock represent a more ethical and ecofriendly approach. Sugarcane straw (SCS) is a cheap and abundantly available feedstock which potentially can be used for biofuels/biochemicals production. It can also help to mitigate environmental and health problems resulting from conventional practice of SCS burning in the fields.

There are different biomass conversion technologies for production …

Towards A Cost-Effective Biorefinery : Production Of Activated Carbons From Residual Biomass For Energy Storage Devices., Zachary Dean Herde

Electronic Theses and Dissertations

Biomass processing for industrial products and biofuels has gained an increasing presence as society looks to using sustainable resources for manufacturing and renewable fuels for energy. However, these sustainably produced materials and products cannot gain a competitive edge because of the manufacturing expenses that are a result of high process temperatures and pressures. In order to lower these costs, theoretical modeling has described a value-added co-product strategy as one of the best ways to combat high bioprocessing prices. Biomass has been shown to make effective carbons for energy storage devices such as supercapacitors and batteries. These carbons, with the right …