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Analyses Of Densely Crosslinked Phenolic Systems Using Low Field Nmr, Jigneshkumar Patel Nov 2017

Analyses Of Densely Crosslinked Phenolic Systems Using Low Field Nmr, Jigneshkumar Patel

Doctoral Dissertations

A uniform dispersion of reactants is necessary to achieve a complete reaction involving multi-components, especially for the crosslinking of rigid high-performance materials. In these reactions, miscibility is crucial for curing efficiency. This miscibility is typically enhanced by adding a third component, a plasticizer. For the reaction of the highly crystalline crosslinking agent hexamethylenetetramine (HMTA) with a strongly hydrogen-bonded phenol formaldehyde resin, furfural has been traditionally used as the plasticizer. However, the reason for its effectiveness is not clear. In this doctoral thesis work, miscibility and crosslinking efficiency of plasticizers in phenolic curing reactions are studied by thermal analysis and spectroscopic …


Structural Behavior Of Inflatable, Reinforced, Braided, Tubular Members, Joshua Clapp Aug 2017

Structural Behavior Of Inflatable, Reinforced, Braided, Tubular Members, Joshua Clapp

Electronic Theses and Dissertations

The Hypersonic Inflatable Aerodynamic Decelerator (HIAD) system being developed by the National Aeronautics and Space Administration (NASA) is an inflatable structure composed of multiple, concentric, pressurized tori, load straps, and a thermal protection system. The HIAD overcomes limitations inherent with the use of rigid decelerators since the deployed diameter is much larger than the packed size, which makes it an enabling technology for new opportunities in space exploration. The HIAD is designed to decelerate and protect spacecraft during atmospheric re-entry. The objective of this research was to improve understanding of structural behavior of HIAD components through material testing, structural testing …