Engineering Commons^™

Study Of Interaction Between Indium Species And Dna In The Formation Of Dna -Templated Nanowires, Shivashankar Suryanarayanan

Doctoral Dissertations

A primary goal of semiconductor industry is to improve device performance and capability by downscaling feature size and upscaling packaging density. As optical-lithography, the mainstream technology for microfabrication, is being stretched to its limit, new unconventional fabrication techniques are being explored as alternatives. A "Bottom-up" approach for manufacturing is emerging as an answer to limitations posed by the traditional "Top-down" approach. Nanowires, bearing the potential of being the basic building blocks for such an approach, are gaining tremendous attention in nanoelectronics. Metal nanowires fabricated using DNA as templates have potential for precise control of length, diameter and positioning. However, wires …

Mechanistic Study Of Nano-Particle Fluidization, X. S. Wang, F. Rahman, Martin J Rhodes

The 12th International Conference on Fluidization - New Horizons in Fluidization Engineering

Degussa Aerosil R974 powder, with a primary particle size of 12 nm, was fluidized using nitrogen in a cylindrical vessel, 50-mm-id and 900 mm in height. Characteristics of incipient fluidization are analysed in relation to variations in the initial packing conditions. Bed collapse experiments were performed and the results are used for assessing fluidization characteristics of the particles. It was found that nanoparticles exhibit characteristics of both Group A and Group C powders. Various methods for estimating the cohesion forces between nanoparticle aggregates are discussed.

Improved Li-Ion Battery Performance By Coating Cathode Nano-Particles Using Atomic Layer Deposition, Renske Beetstra, John Nijenhuis, Erik M. Kelder, J. Ruud Van Ommen

The 12th International Conference on Fluidization - New Horizons in Fluidization Engineering

The use of nanoparticles as a cathode in Li-ion batteries is very promising. However, many of the cathode materials that could be economically attractive suffer from degradation. Therefore, an objective is to stabilise the surface, in order to reduce the degradation. A setup was build to coat the nanoparticles by atomic layer deposition in a fluidised bed reactor. The first fluidisation results for the nanoparticles are presented in this paper.

Role Of Sound Vibration During Aeration Of Nano-Sized Powders, Paola Ammendola, Riccardo Chirone

The 12th International Conference on Fluidization - New Horizons in Fluidization Engineering

The behaviour of two different nano-sized powders, Al2O3 (40 nm) and SiO2 (15 nm), during aeration has been investigated in a laboratory scale fluidized bed. The fluidization quality of both powders is very poor without application of acoustic fields even if some bed expansion has been found. The application of acoustic fields of intensities larger than 135 dB and frequencies close to 120 Hz is able to increase the fluidization quality of both powders. Sound is also able to promote an apparent self-fluidization of a relatively thin portion of the upper part of the bed. The possibility that there is …

Alumina Nanofluid For Spray Cooling Heat Transfer Enhancement, Aditya Bansal

USF Tampa Graduate Theses and Dissertations

Nanofluids have been demonstrated to be promising for heat transfer enhancement in forced convection and boiling applications. The addition of carbon, copper, and other high-thermal-conductivity material nanoparticles to water, oil, ethylene glycol, and other fluids has been determined to increase the thermal conductivities of these fluids. The increased effective thermal conductivities of these fluids enhance their abilities to dissipate heat in such applications. The use of nanofluids for spray cooling is an extension of the application of nanofluids for enhancement of heat dissipation.

In this investigation, experiments were performed to determine the level of heat transfer enhancement with the addition …

Enhancement Of Fluidization And Filtration Using Nanoparticle Agglomerates And Aerogels, Jose A. Quevedo

Dissertations

Previous works have classified the fluidization behavior of nanoparticles as Agglomerate Particulate Fluidization (APF) and Agglomerate Bubbling Fluidization (ABE). These fluidization behaviors are quite different in regard to the fluidized bed expansion, the presence of bubbles and the smoothness of the bed surface, with APF nanopowders showing a much more homogeneous fluidization and a much better dispersion than ABE nanopowders which are generally very difficult to fluidize and show vigorous bubbling. In the present work, the fluidization of APF as well as ABF nanopowders is studied in depth, both conventionally, and in the presence of extemal assistance; several related topics …

Synthesize A Nanoscale Ferrofluid, Rob Snyder

Nanotechnology Teacher Summer Institutes

The chemical synthesis of a ferrofluid is a nanoscale science activity that originally appears in the Journal of Chemical Education. Access to the following website requires a subscription to the journal. J. Chem. Educ., 76, 943-948 (1999). The article was authored by Jonathan Breitzer and George Lisensky.

Exafs Characterization Of Dendrimer‐Derived Pt/Γ‐Al2O3, A. Siani, Oleg S. Alexeev, Christopher T. Williams, Harry J. Ploehn, Michael D. Amiridis

Faculty Publications

The various steps involved in the preparation of a Pt/γ‐Al₂O₃ material using hydroxyl‐terminated generation four (G4OH) PAMAM dendrimers as templates were monitored by EXAFS. The results indicate that Cl ligands in the Pt precursors (H₂PtCl₆ and K₂PtCl₄) were partially replaced by aquo ligands upon hydrolysis to form [PtCl₃(H₂O)₃]⁺ and [PtCl₂(H₂O)₂] species. After interaction of such species with G4OH, Cl ligands from the first coordination shell of Pt were further replaced by nitrogen atoms from the dendrimer interior, …

Novel Pemfc Cathodes Prepared By Pulse Deposition, Subasri M. Ayyadurai, Yoon-Seok Choi, Prabhu Ganesan, Swaminatha P. Kumaraguru, Branko N. Popov

Faculty Publications

A pulse electrodeposition method of preparing thin platinum catalyst layers for polymer electrolyte membrane fuel cell (PEMFC) cathodes has been developed through surface activation of the gas diffusion layer (GDL) by a wetting agent. The performance of the catalyst layer was optimized by wetting agent type, immersion time in the wetting agent, and pulse deposition parameters such as total charge density, peak current density, and duty cycle ratio. The T_off time played a more important role than the T_on time in determining the electrode characteristics such as high concentration of Pt, smaller particle size, and loading. Pt cathodes …