Engineering Commons^™

Customized Boron And Magnesium-Based Reactive Materials Prepared By High Energy Mechanical Milling, Xinhang Liu

Dissertations

New reactive materials need to be developed having biocidal combustion products. When ignited, such material can add chemical biocidal effects to the common effects of high temperature and pressure. Biocidal combustion products are capable of deactivating harmful spores or bacteria, which can be released by targets containing biological weapons of mass destruction. Research showed that halogens, especially iodine, are effective as biocidal components of reactive material formulations. Recently, magnesium combustion product MgO is also found to have a biocidal effect. Thus, advanced formulations containing both magnesium and iodine are of interest; such formulations are prepared and investigated here.

Reactive materials …

Heat Transfer In Silicon - Experiments And Simulation, Chihlin Huang

Theses

The purpose of this thesis is to study the heat transfer in silicon. Silicon is the key semiconductor material, and thermal processing is the traditional method that is used in semiconductor processing. In this research, we can predict the temperature of the silicon wafer during heating. This ability to predict wafer temperature during semiconductor processing will facilitate in the following: (a) Process temperature uniformity, (b) Film thickness uniformity, (c) Diffusion, (d) Process yield, (e) Thermally induced stresses, and (f) Device yield - spatially and temporally across the wafer. For low temperature applications, IC chips can be modeled to simulate the …

Modeling Of Non-Uniform Hydrodynamics And Catalytic Reaction In A Solids-Laden Riser, Rajeshkumar Patel

Dissertations

The riser reactors are widely used in a variety of industrial applications such as polymerization, coal combustion and petroleum refinery because of the strong mixing of gas and solids that yields high heat and mass transfer rates, and reaction rates. In a Fluid Catalytic Cracking (FCC) process, the performance of riser reactor is strongly dependent on the interaction between the fluid and catalysts, since the reaction takes place on the active surface of the catalysts. This is why, the local coupling between hydrodynamics and reaction kinetics is critical to the development of riser reaction models. The local gas-solids flow structure …

Phase Transfer In A Collision Between A Droplet And Solid Spheres, Zheng Shen

Theses

The hydrodynamics of a liquid droplet impinging on a particle is of direct relevance to many engineering applications. The mechanism of heat and mass transfer during the droplet solid collision is essential to the design and operation of many industrial systems. However, very limited systemic research is available to describe the droplet impact on hot solid spheres.

This paper aims to establish a systematic investigation of phase transfer due to the droplet-solid impact, by both experimental and modeling approaches. The targeted phase transfer includes the surface attachment, mass of vaporization, heat transfer to droplet and its partition between vaporization and …

3-D Numerical Simulation Of Reactive Extrusion And Its Application To Polymerization Of Ε-Caprolactone In Co-Rotating Twin-Screw Extruders, Linjie Zhu

Dissertations

A 3-D numerical simulation model was proposed to predict the polymerization of ε-caprolactone in fully-filled conveying elements and kneading blocks of co-rotating twin-screw extruders, in which the kinetics equation for polymerization is coupled with continuity equation, momentum equation, and energy equation. With the 3-D model, parametric studies have been carried out to investigate the effects of screw configurations, screw diameter, operational conditions, values of heat from reaction, initiator concentration, and heat transfer conditions at barrel surface upon the polymerization progress. Two simulation models for the polymerization in the partially-filled channels were developed based on the conveying mechanisms of the reaction …