Engineering Commons^™

Post-Fire Damage Inspection Of Concrete Tunnel Structures, James Viglas

Masters Theses

In general, tunnels are designed with an abundance of safety regarding structural integrity, however, there can be uncertainty related to structural performance after a fire event. The residual condition of a tunnel after a fire is dependent on fire intensity and duration. The goal of this study is to correlate visual and material characteristics of structural and non-structural components of tunnels with fire temperature and exposure time. This can be further related to the residual capacity of structural members in a tunnel, providing insight into safety and overall functionality. Experimental results show that the visual response of materials with heat …

Learning To Rig Characters, Zhan Xu

Doctoral Dissertations

With the emergence of 3D virtual worlds, 3D social media, and massive online games, the need for diverse, high-quality, animation-ready characters and avatars is greater than ever. To animate characters, artists hand-craft articulation structures, such as animation skeletons and part deformers, which require significant amount of manual and laborious interaction with 2D/3D modeling interfaces. This thesis presents deep learning methods that are able to significantly automate the process of character rigging. First, the thesis introduces RigNet, a method capable of predicting an animation skeleton for an input static 3D shape in the form of a polygon mesh. The predicted skeletons …

Design And Analysis Of Content Caching Systems, Anirudh Sabnis

Doctoral Dissertations

Caching is a simple yet powerful technique that has had a significant impact on improving the performance of various computer systems. From internet content delivery to CPUs, domain name systems, and database systems, caching has played a pivotal role in making these systems faster and more efficient. The basic idea behind caching is to store frequently accessed data locally, so that future requests for that data can be served more quickly. For example, a Content Delivery Network (CDN) like Akamai deploys thousands of edge caches across the globe, so that end-user requests can be served from a nearby cache, rather …

Additive Manufacturing Of High-Performance Nanolamellar Eutectic High-Entropy Alloys, Jie Ren

Doctoral Dissertations

Additive manufacturing, also called three-dimensional (3D) printing, is an emerging technology for printing net-shaped components layer by layer for applications in automotive, aerospace, biomedical and other industries. In addition to the vast design freedom offered by this approach, metal 3D printing via laser powder-bed fusion (L-PBF) involves large temperature gradients and rapid cooling and provides exciting opportunities for producing microstructures and mechanical properties beyond those achievable by conventional processing routes. Although these extreme printing conditions enable microstructural refinement to the nanoscale for achieving high strength. However, high-strength nanostructured alloys by laser additive manufacturing often suffer from limited ductility. Eutectic high-entropy …

Capacity Planning For Heterogeneous Patient Populations In Primary Care And Specialty Networks, Prashant Meckoni

Doctoral Dissertations

Access to primary care has a direct impact on morbidity and mortality, and is strongly influenced by indirect waiting time: the delay between the requested and allotted appointment day. Our models describe the heterogeneous appointment seeking patterns of a primary care patient panel using stochastic processes parameterized to reflect the diversity of primary care visit rates in the US. For capacity planning, we estimate the distribution of daily appointments, and show that the distribution variability can be reduced by heuristics that use patient flexibility regarding the day of the appointment. For delays, we demonstrate that in a first-come, first-served system, …

A Digital Twin Framework For Production Planning Optimization: Applications For Make-To-Order Manufacturers, Ron Mallach

Doctoral Dissertations

In this dissertation, we develop a Digital Twin framework for manufacturing systems and apply it to various production planning and scheduling problems faced by Make-To-Order (MTO) firms. While this framework can be used to digitally represent a particular manufacturing environment with high fidelity, our focus is in using it to generate realistic settings to test production planning and scheduling algorithms in practice. These algorithms have traditionally been tested by either translating a practical situation into the necessary modeling constructs, without discussion of the assumptions and inaccuracies underlying this translation, or by generating random instances of the modeling constructs, without assessing …

Singular Integration By Interpolation For Integral Equations, Ioannis Kyriakou

Doctoral Dissertations

Maxwell’s equations and the laws of Electromagnetics (EM) govern a plethora of electrical, optical phenomena with applications on wireless, cellular, communications, medical and computer hardware technologies to name a few. A major contributor to the technological progress in these areas has been due to the development of simulation and design tools that enable engineers and scientists to model, analyze and predict the EM interactions in their systems of interest. At the core of such tools is the field of Computational Electromagnetics (CEM), which studies the solution of Maxwell’s equations with the aid of computers. The advances in these applications technologies, …

Polyesters Derived From Biobased 1,5-Pentanediol For Coatings, Adhesives, And Biodegradable Plastics, Lei Zheng

Doctoral Dissertations

Biomass-derived polymers are drawing increased attention from researchers due to unique performance attributes, potential for biodegradability, new low-cost feedstocks, and improved sustainability. Biobased feedstocks are employed in both major applications of polymers thermosets and thermoplastics. For thermoset coatings and adhesives, biobased resins such as biobased alkyds, epoxy resins, benzoxazine resins, starch derivatives, and proteins from plants and animals, are promising candidates to replace petroleum-derived counterparts. Thermoplastics such as polyethylene are mainly produced from fossil resources, generally have poor degradability and are difficult to effectively recycle. Currently, in the United States, less than 10% plastics are recycled, and more than 70% …

Polymer Based Energy Storage And Thermal Management On Textile Devices, Wesley A. Viola

Doctoral Dissertations

Humans developed textiles to manage thermal energy transfer with the environment and support homeostasis in a wide range of climates. With the anticipation of wearable technologies to transform healthcare via early, pre-symptomatic detection of illness, there is now a demand for electrical energy storage to support such on-body devices. Finding energy materials to merge seamlessly with textiles is basic requirement to ensure widespread adoption of wearable health monitors. Here we use a vapor deposition process to conformally coat ordinary fabrics with the doped conjugated polymer poly(3,4 ethylenedioxythiophene) (PEDOT-Cl), a soft material which possesses electronic and redox capabilities. We demonstrate PEDOT-Cl …

Assembly Of Polymer Colloids At Fluid Interfaces Through External Fields And Nanoscale Surface Topography, Samuel Trevenen

Doctoral Dissertations

The superposition of dipolar repulsion and capillary attraction energies between colloidal particles pinned at fluid interfaces dictates their microstructural organization and therefore the macroscopic interfacial material properties of particle-stabilized emulsions and 2D monolayer materials. While isotropic, spherical, particles have been extensively utilized, expanding the possible applications and material property tunability via anisotropic particles has been a challenge due to the propensity of particles to form disordered aggregates at the interface. My thesis presents the synthesis of anisotropic polymer ellipsoids and the development and use of experimental tools to study their interfacial behavior to reveal how dipolar and capillary interactions can …

Heat Transfer Characteristics Of Latent Heat Thermal Energy Storage, Kedar Prashant Shete

Doctoral Dissertations

Latent heat thermal energy storage (LHTES) systems can be used to reduce electric demand when used in conjunction with Combined Heat and Power Plants or HVAC(Heating, Ventilation, Refrigeration and Air-Conditioning), as they can regulate the demand and supply of thermal energy. They can also be used to integrate renewable energy sources with the grid. A design procedure and performance modeling is required for designing and using thermal energy storage systems effectively. We propose hypotheses about the performance of an LHTES device with different operating conditions and material properties, for devices that are governed by different modes of heat transfer. We …

Controlling Mechanical Properties Of Well-Defined Polymer Networks, Ipek Sacligil

Doctoral Dissertations

Polymer networks are one of the most versatile and highly studied material class that revolutionized many aspects of life. Connecting the final network properties to the molecular parameters of its building blocks remains a major research thrust. Recent advances in network synthesis techniques allowed for accurate predictions of elastic modulus in model networks. Tew Group has developed highly efficient, thiol-norbornene networks with controllable mechanical properties. Chapter 2 focuses on modifying the gel fracture energy predicted by Lake-Thomas theory by accounting for loop defects. This study allowed for a priori estimates of gel fracture energy by combining theory, experiments, and simulations. …

Stimulating Electricity Demand To Enhance Sustainable Human Development In Sub-Saharan Africa, June M. Lukuyu

Doctoral Dissertations

Sub-Saharan Africa continues to aggressively pursue universal electricity access to drive economic development, improved health, literacy, food security, and gender equality. However, increasing electricity supply and household connections is only one important step towards achieving economic transformation. Countries in the region must also strive for increased use of energy services, not only by households but also for income-generating productive uses and community facilities. Unfortunately, unlike the other regions in the world, increasing electricity access rates in sub-Saharan Africa have not been met with complementary growth in electricity consumption density. Therefore, contrary to the energy efficiency zeitgeist in industrialized regions, countries …

Functionalizing Three-Dimensional Superhydrophobic Materials, Li He

Doctoral Dissertations

Traditional bulk superhydrophobic materials are usually characterized by high porosity, low fracture toughness, and extremely low strength due to the low surface energy on the internal surface. Therefore, it is very challenging to achieve a bulk superhydrophobic material with high strength and mechanical durability. This dissertation presents an experimental study of strengthening a superhydrophobic siloxane using carbon-based nanomaterials, emphasizes the effects of microscale dispersion and macroscale distribution of reinforcing graphene on the uniformity and strength of the composite, studies the impact factors on the water adsorption for hydrophilic and hydrophobic materials, and applies chemical modification modify the surface of clay …

Surface Engineering And Microfabrication Of Pdms-Based Devices For Women’S Health Applications, Jamar Hawkins

Doctoral Dissertations

Poly(dimethylsiloxane) (PDMS) is a widely used polymer in biomedical and microfluidics research due to its optical transparency, castability, gas permeability, and relative biocompatibility. However, while the favorable intrinsic properties of the polymer are typically suitable for preventing experimental artifacts, the true advantage of these devices often comes from their customized patterning and design, which can be tailored to specific applications. Critical parameters in biomedical applications such as chemical concentration profiles, fluid streamlines, substrate topography, and mechanical stiffness can all be fine-tuned simply by selecting the appropriate dimensions and arrangement of PDMS microstructures. To address challenges in expanding the application of …

Bottom-Up Morphological Control Of Biphasic Polymer Particles Via Heterogeneous Polymerization, Heather S.C. Hamilton

Doctoral Dissertations

Heterogeneous polymerization techniques are industrially relevant, scalable methods to synthesize polymer colloids and they have emerged in recent decades as viable methods to produce biphasic and morphologically complex polymer particles. The overarching goal of this thesis is to understand how heterogeneous polymerization techniques can be modified and optimized to control particle morphology through the systematic study of process parameters. Chapter 1 introduces relevant nomenclature and provides a brief historical perspective on the development of heterogeneous polymerization. This chapter also reviews the state-of-the-art techniques used to prepare morphologically complex polymer particles, with an emphasis on the heterogeneous polymerization processes studied in …

Phosphorus-Containing Zeolites For Biofuel Production, Jason Gulbinski

Doctoral Dissertations

Fossil fuel consumption increases 2% a year due to transportation fuels and specialty chemicals for plastics and synthetic fibers such as p-xylene, a monomer of polyethylene terephthalate. p-Xylene demand was over 50 million tons in 2021 and will increase by 5% a year through 2026. Therefore, sustainable p-xylene production is desired. p-Xylene is produced renewably through Diels-Alder cycloaddition of biomassderived 2,5-dimethylfuran (DMF) with ethylene from bio-ethanol and dehydration over an acid catalyst. Industrial aluminosilicate zeolite catalysts achieve a selectivity of 75%, with loss to side products and coking. A new class of catalysts, phosphoric acid-containing aluminum-free zeolites, P-zeosils, like dealuminated …

Effect Of Chemical Identity And Morphology On Amphiphilic-Zwitterionic Block Copolymer Membranes, Ria Ghosh

Doctoral Dissertations

Amphiphilic block copolymers have gained a broad research interest attributed to their self-assembly properties over a range of pH, temperature, and ionic strength. Polyzwitterions have attracted special attention due to their hydrophilicity, charge sensitivity and coulombic attraction of the opposite charges over a range of environments making them a popular material of study in the field of stimuli responsive systems, for example in self-healing hydrogels, and water transport membranes. Combining the stimuli responsiveness and higher hydrophilicity of zwitterionic polymers with self-assembly behavior of amphiphilic block copolymers created an interest to study the effect of composition and identity of the zwitterionic …

Structure-Function Relationships Of Bighorn Sheep Horncore Bone And Horn-Horncore Interface Materials For Energy Absorption Applications, Luca H. Fuller

Doctoral Dissertations

Bighorn sheep rams do not show overt signs of traumatic brain injury from head impacts experienced during intraspecific combat. Rams’ cranial appendages bear the brunt of ramming impacts and are composed of a keratin-rich horn anchored to a bony horncore via a soft connective tissue interface. The horncore is filled with velar bone which has a unique porous architecture with a comparable bone volume fraction, but larger strut thickness and separation than typical mammalian trabecular bone. Velar bone absorbs more energy than the horn and substantially reduces post-impact brain cavity accelerations in computational models of bighorn sheep ramming. These findings …

Thermal Transport Across 2d/3d Van Der Waals Interfaces, Cameron Foss

Doctoral Dissertations

Designing improved field-effect-transistors (FETs) that are mass-producible and meet the fabrication standards set by legacy silicon CMOS manufacturing is required for pushing the microelectronics industry into further enhanced technological generations. Historically, the downscaling of feature sizes in FETs has enabled improved performance, reduced power consumption, and increased packing density in microelectronics for several decades. However, many are claiming Moore's law no longer applies as the era of silicon CMOS scaling potentially nears its end with designs approaching fundamental atomic-scale limits -- that is, the few- to sub-nanometer range. Ultrathin two-dimensional (2D) materials present a new paradigm of materials science and …

Vapor Deposition Of Self-Wrinkling Polymer Films, Robert N. Enright

Doctoral Dissertations

Initiated chemical vapor deposition is used to grow polymer films on substrates of various three-dimensional shapes which exhibit wrinkling during film growth, termed self-wrinkling. Self-wrinkling avoids separate film growth and compression steps and more-closely mimics processes observed in nature. The self-wrinkling process is elucidated on flat elastic substrates, revealing control over the amount of compressive stress by changing deposition conditions. Next, a study of films grown on liquid substrates with interface profiles that either resemble cylinders or contain repeating concave cones, saddles, and bowls affirms the principle that the wrinkle roundness increases with interface curvature. The selection of high versus …

Correlation Between Laboratory Testing Results And In-Situ Sidewalk Scaling, Brian R. Shea

Masters Theses

Scaling tests aim to induce scaling behavior in concrete specimens similar to environmental conditions. The efficacy of laboratory tests’ ability to match environmental conditions is important to be able to evaluate the durability of concrete exposed to freeze-thaw cycles and de-icers. This study attempts to correlate results between two existing scaling test standards, ASTM C672 and the BNQ NQ 2621-900. The correlation is done via scaling evaluation including computer-based photogrammetric analysis, visual ratings, and cumulative mass loss measurements. Then a correlation between the laboratory testing and in-situ sidewalk panel specimens is made via visual ratings.

Comparison Of Scaling Performance Between Sidewalks Placed Using Hot And Cold Weather Concreting Procedures, Likhitha Rudraraju

Masters Theses

This study investigates the performance of concrete sidewalks placed using hot and cold weather concreting practices. The effect that curing methods, types of deicers, and supplementary cementitious material content have on the scaling resistance of concrete is examined in the laboratory and the field. After one winter, petrographic analysis was conducted on the cores from the sidewalk panels.

The results from field evaluation indicate that the concrete sidewalks placed using hot weather concreting showed better resistance against scaling than those placed using cold weather concreting. The results also suggest that the effect of curing method depends on the concreting procedure …

Wind-Wave Misalignment Effects On Multiline Anchor Systems For Floating Offshore Wind Turbines, Doron T. Rose

Masters Theses

Multiline anchors are a novel way to reduce the cost of arrays of floating offshore wind turbines (FOWTs), but their behavior is not yet fully understood. Through metocean characterization and dynamic simulations, this thesis investigates the effects of wind-wave misalignment on multiline anchor systems. Four coastal U.S. sites are characterized in order to develop IEC design load cases (DLCs) and analyze real-world misaligned conditions. Stonewall Bank, Oregon showed the highest 500-year extreme wave height, at 16.6 m, while Virginia Beach, Virginia showed the highest 500-year wind speed, at 56.8 m/s. Misalignment probability distributions, at all sites, are found to converge …

Electrothermal Properties Of 2d Materials In Device Applications, Samantha L. Klein

Masters Theses

To keep downsizing transistors, new materials must be explored since traditional 3D materials begin to experience tunneling and other problematic physical phenomena at small sizes. 2D materials are appealing due to their thinness and bandgap. The relatively weak van der Waals forces between layers in 2D materials allow easy exfoliation and device fabrication but they also result in poor heat transfer to the substrate, which is the main path for heat removal. The impaired thermal coupling is exacerbated in few-layer devices where heat dissipated in the layers further from the substrate encounters additional interlayer thermal resistance before reaching the substrate, …

Security Of Hardware Accelerators In Multi-Tenant Fpga Environments, Shayan Moini

Doctoral Dissertations

Field-programmable gate arrays (FPGAs) play an important role in the acceleration of computationally expensive algorithms for machine learning, aerospace, and ASIC prototyping. The emergence of FPGAs in the cloud (cloud FPGAs) has accelerated FPGA adoption in various applications due to their low initial cost and the ability to quickly prototype a design. Multi-tenancy, in which multiple users execute circuitry in the same FPGAs simultaneously with logical isolation, reduces cloud FPGA usage cost and increases FPGA utilization. Multi-tenancy introduces new security challenges, such as remote side-channel and fault injection attacks, that cannot be addressed with traditional countermeasures against attacks. In this …

Synthesis Of Zeolites With Controlled Defects By Understanding The Role Of Charge Balance In Zeolite Crystallization, Song Luo

Doctoral Dissertations

Zeolites are well-defined and ordered microporous crystalline materials constructed by the continuous linkage of corner sharing TO4 tetrahedra (taking T atoms (e.g., Si or Al) as the tetrahedral center). Due to the structural and compositional diversities and superior hydrothermal stability, zeolites have been broadly utilized to many industrial fields, including gas separation and catalysis heterogeneous catalysis. However, understanding zeolite crystallization mechanisms remains a tantalizing challenge, which causes challenges in tailoring this material for advanced applications. Raman spectroscopy has emerged as a powerful tool for probing medium-range (0.35 - 1 nm) structures. Since this scale is consistent with the micropore size …

Water Resources Planning Under Deep Uncertainty For Physically, Socially, And Politically Complex Systems, Sarah St. George Freeman

Doctoral Dissertations

Water supply systems, particularly those of large cities, are complex systems linking supply, regulatory and distribution infrastructure, and points of use. Despite their physical complexities, it is infrequent that full supply, distribution, end use, and feedbacks therein are considered in an integrated manner. These complex systems-of-systems face large uncertainties related to physical aspects such as degradation of infrastructure, changing demand, and climate variability and change. Though great, such physical uncertainties often pale in comparison to the those related to the human systems in place to manage them and yet uncertainty in the decision-making landscape is often grossly simplified in our …

Heterogeneous Iot Network Architecture Design For Age Of Information Minimization, Xiaohao Xia

Masters Theses

Timely data collection and execution in heterogeneous Internet of Things (IoT) networks in which different protocols and spectrum bands coexist such as WiFi, RFID, Zigbee, and LoRa, requires further investigation. This thesis studies the problem of age-of-information minimization in heterogeneous IoT networks consisting of heterogeneous IoT devices, an intermediate layer of multi-protocol mobile gateways (M-MGs) that collects and relays data from IoT objects and performs computing tasks, and heterogeneous access points (APs). A federated matching framework is presented to model the collaboration between different service providers (SPs) to deploy and share M-MGs and minimize the average weighted sum of the …

Systematic Review Of Driver Distraction In The Context Of Advanced Driver Assistance Systems (Adas) & Automated Driving Systems (Ads), Apoorva Pramod Hungund

Masters Theses

Advanced Vehicle Systems promise improved safety and comfort for drivers. Steady advancements in technology are resulting in increasing levels of vehicle automation capabilities, furthering safety benefits. In fact, some of these vehicle automation systems are already deployed and available, but with promised benefits, such systems can potentially change driving behaviors. There is evidence that drivers have increased secondary task engagements while driving with automated vehicle systems, but there is a need for a clearer scientific understanding of any potential correlations between the use of automated vehicle systems and potentially negative driver behaviors.

Therefore, this thesis aims to understand the state …