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Missouri University of Science and Technology

Doctoral Dissertations

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Full-Text Articles in Engineering

Advanced Manufacturing Of Nanomaterials For Energy Storage And Biomedical Applications, Hiep Pham Jan 2024

Advanced Manufacturing Of Nanomaterials For Energy Storage And Biomedical Applications, Hiep Pham

Doctoral Dissertations

"Nanomaterials have emerged as an important component to the advancement of many fields, ranging from advanced energy materials in the energy field to highly sophisticated treatment vehicles in the biomedical field. Understanding the physical behavior of nanomaterials is critical to design materials with excellent properties and performance for the many disciplines in which they are utilized and is necessary to master the various manufacturing processes that influence nanomaterial properties and behavior. This research focused on a fundamental study into the behaviors of newly developed nanomaterials under both conventional and new manufacturing processes for high performance lithium-ion batteries and for advanced …


Novel Uses Of Distributed Optical Fiber Sensing For Geo-Mechanical Monitoring, Samuel Vincent Nowak Jan 2024

Novel Uses Of Distributed Optical Fiber Sensing For Geo-Mechanical Monitoring, Samuel Vincent Nowak

Doctoral Dissertations

"Rock mass monitoring in underground excavations is crucial for ensuring workplace safety and efficiency. As mines become deeper and more complex, the need to monitor larger volumes of rock during mining becomes impractical with existing instruments due to high costs. Distributed Optical Fiber Sensing (DOFS) is a powerful technology with advantages like long sensor length, real-time measurement capabilities, ease of installation, low cost, and distributed measurement. However, its application in rock mass monitoring is limited, especially in the mining industry. This study addresses a major gap in DOFS technology, specifically the inability of long-range distributed optical fiber strain sensors to …


Low-Shrinkage Fiber-Reinforced Concrete For Infrastructure Construction And Rehabilitation, Jingjie Wei Jan 2024

Low-Shrinkage Fiber-Reinforced Concrete For Infrastructure Construction And Rehabilitation, Jingjie Wei

Doctoral Dissertations

"The aim of this study is to develop two classes of low-shrinkage high-performance concrete (HPC): fiber-reinforced super workable concrete (FR-SWC) for infrastructure construction and fiber-reinforced self-consolidating concrete (FR-SCC) for repair applications. HPC with excess content of shrinkage mitigation materials (SMMs), including shrinkage-reducing admixture (SRA), superabsorbent polymer (SAP), and expansive agent (EA) has a detrimental effect on mechanical performance. These classes of HPC were optimized to reduce shrinkage, enhance mechanical properties, and improve durability. The effect of fiber type (macro synthetic fiber, MSF; 5D steel fiber, 5D; 80% 3D + 20% short steel fibers; STST), SMMs, and plastic viscosity on bond …


Novel Supercritical Biodiesel Plant Design & Process Scale-Up, Ghana Shyam Paudel Jan 2024

Novel Supercritical Biodiesel Plant Design & Process Scale-Up, Ghana Shyam Paudel

Doctoral Dissertations

"Current energy prices, national energy security, and global climate change fuel our momentum to find efficient advanced fuels choices. In this study, biodiesel processing, and a novel design for next generation biodiesel plants are explored. During a National Science Foundation (NSF) I-Corps project we identified three creative and profitable improvements to the process: 1. Incorporating Energy intensive separations and reactions 2. Utilizing Low commodity glycerol and 3. Applying process intensification principles.

Current biodiesel processes are catalyzed processes using continuous stir reactors with distillation systems to separate material constituents. We tested a lab-scale nocatalyst supercritical biodiesel process using waste cooking oil …


The Comprehensive Study Of High Viscosity Friction Reducers In High-Tds And High-Temperature Environments, Xiaojing Ge Jan 2024

The Comprehensive Study Of High Viscosity Friction Reducers In High-Tds And High-Temperature Environments, Xiaojing Ge

Doctoral Dissertations

"High viscosity friction reducers (HVFRs) have been recently gaining more attention and increasing in use, not only as friction-reducing agents but also as proppant carriers. Reusing of produced water has also been driven by both environmental and economic benefits. Currently, most friction reducers on the market are anionic friction reducers, which are fully compatible with most produced water with low to medium level of Total Dissolved Solids (TDS) but show a significant drop at high TDS conditions in term of their friction reduction performance in most cases. On the contrary, cationic friction reducers are believed to have better TDS tolerance …


In Situ High Temperature Fiber-Optic Raman Sensor For Industrial Applications, Bohong Zhang Jan 2024

In Situ High Temperature Fiber-Optic Raman Sensor For Industrial Applications, Bohong Zhang

Doctoral Dissertations

"Continuous casting in steel production uses specially developed oxyfluoride glasses (mold fluxes) to lubricate a mold and control the solidification of the steel in the mold. The composition of the flux impacts properties, including basicity, viscosity, and crystallization rate, all of which affect the stability of the casting process and the quality of the solidified steel. However, mold fluxes interact with steel during the casting process, resulting in flux chemistry changes that must be considered in the flux design. Currently, the chemical composition of mold flux must be determined by extracting flux samples from the mold during casting and then …


Comprehensive Investigation Of Using Tire-Derived Aggregate In Chip Seal Subjected To Various Traffic And Environmental Conditions, Alireza Pourhassan Jan 2024

Comprehensive Investigation Of Using Tire-Derived Aggregate In Chip Seal Subjected To Various Traffic And Environmental Conditions, Alireza Pourhassan

Doctoral Dissertations

"Chip seal is one of the most cost- and performance-effective pavement preservation treatments commonly used in the United States. Using crumb rubber obtained from scrap tires as a partial or full replacement for mineral aggregate has been proposed as a sustainable solution to reduce the negative environmental impacts of scrap tire accumulation and excessive consumption of natural resources. However, there was no data available regarding the performance of rubberized chip seal under traffic loads and environmental conditions. An extensive study using laboratory specimens and conditioning as well as field implementation and assessments were conducted to bridge this gap. Different traffic …


Modeling And Analysis Methods For Esd And Emi Problems, Xin Yan Jan 2024

Modeling And Analysis Methods For Esd And Emi Problems, Xin Yan

Doctoral Dissertations

"Electrostatic discharge (ESD) failures and Electromagnetic interference (EMI) problems are becoming more critical in electronic devices and large systems. In this work, four studies are presented to model and analyze ESD and EMI problems.

First, a simplified physical-based model for deep-snapback transient voltage suppressors (TVS) is developed. While based on physics, the number of parameters and components is minimized. Results show that the proposed model captures the most important behaviors of the TVS response using a limited number of parameters, allowing the model to be tuned relatively easily using data obtained only from package-level transient and quasi-static measurements. Second, a …


Melt Pool Feature Extraction, A State-Space Model And Spatial Layer-To-Layer Control For Powder Bed Fusion, Xin Wang Jan 2024

Melt Pool Feature Extraction, A State-Space Model And Spatial Layer-To-Layer Control For Powder Bed Fusion, Xin Wang

Doctoral Dissertations

"Powder Bed Fusion (PBF) is an Additive Manufacturing (AM) technique which can reduce material waste and is a fast-prototyping technique for complex geometries. However, the lack of consistent quality is a major problem in industrial applications. An InfraRed (IR) camera is a common tool to monitor a surface temperature field and melt pool morphology in PBF. With melt pool features from camera videos, manufacturing researchers use spatial feature maps to visualize defect locations and control researchers use layer-to-layer control to achieve more uniform melt pools and less defects.

Paper I presents a simulation method to characterize the effect of down-sampling …


A Human-Centered Framework For Oncological Healthcare System Modeling Applied To Mobile Radiation Delivery, Alex Price Jan 2024

A Human-Centered Framework For Oncological Healthcare System Modeling Applied To Mobile Radiation Delivery, Alex Price

Doctoral Dissertations

"Healthcare systems engineering is challenging due to the complexity, geographic expansiveness, inertial properties, and the heterogeneous sub-systems, with varying vested interests. Additionally, humans comprise many of the forms and functions, and are independent, with resistance and uncertainty in their decision-making that adds complexity. Human-centered systems modeling approaches are therefore needed to capture this unique aspect of a healthcare system and to enhance understanding of emergent healthcare properties. This dissertation focuses on integrating systems modeling within healthcare and emphasizes the importance of incorporating human decision-making. Moreover, the incorporation of a human-centered approach yields particularly valuable insights into the decision-making processes that …


Design And Development Of Biocompatible Mofs And Silica-Based Nanocarriers With Controlled Pharmacokinetics For Drug Delivery Applications, Neila Pederneira Jan 2024

Design And Development Of Biocompatible Mofs And Silica-Based Nanocarriers With Controlled Pharmacokinetics For Drug Delivery Applications, Neila Pederneira

Doctoral Dissertations

"In the past decade, a big interest has drawn into nanoporous metal-organic frameworks (MOFs) and silica-based materials as nanocarriers for drug delivery applications, owing to their exceptionally high surface area and highly structured porous network. The overall goal of this research was to optimize the pharmacokinetic behavior of several highly porous biocompatible drug carriers that have the potential to carry Ibuprofen, 5-Fluorouracil, and Curcumin to the desired tissue without creating a burst effect and minimizing the amount of dosage and size that conventional capsules require. The specific objectives of this study are to (i) assess the effect of drug solubility …


Sustainable Cementitious Materials For Building And Sorption Applications, Sukanta Kumar Mondal Jan 2024

Sustainable Cementitious Materials For Building And Sorption Applications, Sukanta Kumar Mondal

Doctoral Dissertations

"Ordinary Portland Cement (OPC) is the most widely used cement material, but it contributes over 8% of the global CO2 emission and the process is energy intensive. Moreover, OPC faces durability challenges, particularly in aggressive environments. Hence, there is rapidly increasing interest in sustainable alternative cements with lower carbon footprint, lower energy consumption, and those that offer superior properties that are beneficial for specific applications. Two sustainable cementitious materials that are frequently researched as an alternative to OPC are calcium sulfoaluminate (CSA) cement and alkali-activated materials (AAMs). CSA cement lowers CO2 emission by over 40% compared to OPC, …


A Structure From Motion Photogrammetric Method For Continuously Measuring And Tracking The Deformations Of Soils During Triaxial Testing, Xiaolong Xia Jan 2024

A Structure From Motion Photogrammetric Method For Continuously Measuring And Tracking The Deformations Of Soils During Triaxial Testing, Xiaolong Xia

Doctoral Dissertations

"Measuring soil deformation characteristics during triaxial testing is an important part of characterizing the stress-strain behavior of both saturated and unsaturated soils. The total and local deformations and volume changes of a soil specimen are indispensable parameters that need to be measured and are of great significance for understanding volume change and shear strength characteristics of the soil. Over the past several decades, numerous efforts have been made to measure the soil deformations during triaxial testing. However, it remains a great challenge for researchers to measure the volume-changes of unsaturated soils due to the existence of the air phase.

This …


Advancing A Systems Perspective On Innovative Behavior, Stephen Demski Jan 2024

Advancing A Systems Perspective On Innovative Behavior, Stephen Demski

Doctoral Dissertations

"Engineering organizations pursue innovation in strategy, structure, processes, and the services and products offered to remain relevant and competitive. Identifying factors supporting or constraining innovative work behavior and recognizing the complexity of their interactions are vital to sustaining an innovative workforce, yet how factors interact has not been comprehensively studied.

Recognizing innovative work behavior as the output of a complex system of factors guided this study’s literature search that identified over one hundred individual, team, and organizational factors influencing innovative behavior, interviews of engineers to learn what factors are essential in their work environment, and Delphi survey to rank factors, …


Investigation Of Asphaltene Instability Under Gas Injection In Unconventional Reservoirs And Its Impact On Oil Recovery Performance, Mukhtar Elturki Jan 2024

Investigation Of Asphaltene Instability Under Gas Injection In Unconventional Reservoirs And Its Impact On Oil Recovery Performance, Mukhtar Elturki

Doctoral Dissertations

"Unconventional reservoirs, such as shale gas and tight oil formations, have become an important source of energy in recent years. However, these reservoirs often contain high levels of asphaltenes, which can lead to deposition and blockages in production wells and reduce the flow of hydrocarbons during gas enhanced oil recovery (GEOR) techniques. This study aims to experimentally evaluate the impact of miscible and immiscible carbon dioxide (CO₂) and nitrogen (N₂) on asphaltene deposition and its impact on oil recovery performance in unconventional shale reservoirs.

This research began with a comprehensive literature review and data analysis of GEOR methods in unconventional …


Characterization Of The Acquisition Parameters Of A Submersible Gamma-Ray Computed Tomography System, Zhongmin Jin Jan 2024

Characterization Of The Acquisition Parameters Of A Submersible Gamma-Ray Computed Tomography System, Zhongmin Jin

Doctoral Dissertations

"The purpose of this work is to study a component of a submersible gamma-ray computed tomography (CT) system used in the non-destructive testing of irradiated nuclear fuels. The first section of this study proposes two acceleration approaches for rapidly modeling a transmission-type gamma-ray tomography system. The first relies on Monte Carlo simulations with a monodirectionally biased source sampled from a sub-volume of the whole source volume. This method estimates the real count rate using analytical correction factors. The second way of acceleration is based on deterministic calculations that use the Beer-Lambert law and detector response characteristics. It shows that both …


Contextualizing Renewable Energy Adoption: An Examination Of The Role Of Community Choice Aggregation, Ankit Agarwal Jan 2024

Contextualizing Renewable Energy Adoption: An Examination Of The Role Of Community Choice Aggregation, Ankit Agarwal

Doctoral Dissertations

"The rapid expansion of renewable energy generation in the U.S., both through distributed and utility-scale facilities, is largely driven by top-down policy measures and the growing engagement of residential consumers on both individual and community levels. Previous studies on motives behind residential renewable energy adoption have examined procurement options in isolation and within a static context, primarily focused on intrinsic attributes like economic incentives, emission reductions, and peer popularity. This research introduces a novel context, assessing renewable procurement options in the presence of Community Choice Aggregation (CCA), a more prevalent and accessible alternative. This dissertation makes four pivotal contributions, offering …


Monitoring And Control Of Coal Dust Exposure Using Low-Cost Pm Sensors And Computational Fluid Dynamics, Nana Kobina Amoako Amoah Jan 2024

Monitoring And Control Of Coal Dust Exposure Using Low-Cost Pm Sensors And Computational Fluid Dynamics, Nana Kobina Amoako Amoah

Doctoral Dissertations

"Overexposure to respirable coal mine dust has been linked to causing serious health problems including coal workers pneumoconiosis (CWP) and chronic massive fibrosis. The prevalence of these health problems has been on the increase since the 2000s due to increased exposure levels with roof bolter operators having the highest exposure levels. The currently used PDM3700 is too expensive, heavy and bulky which limits their use only for regulatory monitoring failing to measure miners’ personal exposure levels. Also, since roof bolter operators are more prone to elevated coal dust levels, the canopy air curtain (CAC) was developed to protect then high …


Control And Optimization Of Energy Storage System In Power Distribution System, Waqas Ur Rehman Jan 2024

Control And Optimization Of Energy Storage System In Power Distribution System, Waqas Ur Rehman

Doctoral Dissertations

"The widespread adoption of electric vehicles (EVs) and transportation electrification is encumbered by two chief barriers: i) the limited driving range of EVs in the market today and ii) inadequate fast-charging infrastructure for long-distance trips. Extreme fast charging (XFC) technology can recharge EVs in less than 10 minutes for 200 miles range. Firstly, a novel robust optimization-based mixed integer linear programming model is proposed to size a battery energy storage system (BESS) and PV system in an XFCS. In this part, it is assumed that the sizing and location of the XFCS are known. Secondly, the aforesaid assumption is relaxed, …


Geometry-Aware Methodology For Coupling Mechanism Analysis And Radiation Mechanism Analysis, Xu Wang Jan 2023

Geometry-Aware Methodology For Coupling Mechanism Analysis And Radiation Mechanism Analysis, Xu Wang

Doctoral Dissertations

"Due to the wide-band spectrum of digital signals, a variety of noise generators, including microprocessors, liquid crystal displays, digital microphones, high-speed traces, and double-data-rate memory modules, are found in consumer electronics products. Noise generated by digital circuits can couple to the antennas and degrade their sensitivity. Additionally, it also couples to metallic housings or heatsinks and produces a significant amount of emission. In this research, methodologies are presented to analyze the coupling and radiation mechanism in electronic devices.

To investigate the coupling between the distributive geometries in the radio frequency interference (RFI) problem, a mesh-dependent partition-based coupling mechanism analysis method …


Intragranular Tungsten-Titanium Carbide Composite Ceramics Via Gas-Solid Displacement Reactions, Ryan Daniel Dempsey Jan 2023

Intragranular Tungsten-Titanium Carbide Composite Ceramics Via Gas-Solid Displacement Reactions, Ryan Daniel Dempsey

Doctoral Dissertations

"Research presented herein details the synthesis and characterization of nanocomposite ceramics featuring novel heterogeneous microstructures of potential interest in a variety of electrical and structural applications. Specifically, W-TiCy composite ceramics featuring tungsten nanoprecipitates located primarily within TiCy grains have been produced via sintering of intragranular nanocomposite powders produced via reaction processing-based techniques. This dissertation details the thermodynamic basis and applied kinetics of a processing scheme for fabricating nanocomposite ceramics whose morphological heterogeneity reflects that originally developed in the powder state. The first study in this series overviews the motivation for applying metallothermic displacement reactions, conducted through gaseous intermediates, to solid …


Investigation Of Recrosslinkable Preformed Particle Gels For Natural Gas Conformance Control, Ali Abdulmohsen Al Brahim Jan 2023

Investigation Of Recrosslinkable Preformed Particle Gels For Natural Gas Conformance Control, Ali Abdulmohsen Al Brahim

Doctoral Dissertations

"Recross linkable Preformed Particle Gel (RPPG) is a novel type of preformed particle gel in which particles can bond together to form a strong bulk gel system after being placed in the target formation. In this research, I systematically evaluated the feasibility of using this product to improve gas flooding conformance for mature reservoirs with conduits or fractures. Two RPPG systems were used for the experiment: a CO2- resistant RPPG (CR-RPPG) synthesized using acrylamide (AM) and 2-acrylamide-2- methylpropane sulfonate acid (AMPS), designed for CO2 flooding; and an acrylamide-co-acrylic acid-based RPPG (LT-RPPG), designed for water flooding. Different experimental apparatuses …


Identification, Mapping, Analysis, And Dating Of Composite Mega Landslides In The Colorado Plateau, Conor Maris Watkins Jan 2023

Identification, Mapping, Analysis, And Dating Of Composite Mega Landslides In The Colorado Plateau, Conor Maris Watkins

Doctoral Dissertations

"This research consists of three articles focusing on landslide complexes within the Grand Canyon region of the Colorado Plateau. This is a vast and remote region of rugged topography. The landslide complexes in this study are greater than 10 million cubic meters in volume. The slides are located within different areas of the region and consist of differing geology but share multiple commonalities. Stratigraphic and structural controls tend to dictate where the slides occur. All of the landslides occur where carbonates and/or sandstones overlie over consolidated shales. The shales are susceptible to creep and strain softening where lateral confinement has …


Sustainable Development: A Data Analysis Investigation For A New Conceptual Model, Case Study Comparison And Validation Techniques, Tiffanie Marie Toles Jan 2023

Sustainable Development: A Data Analysis Investigation For A New Conceptual Model, Case Study Comparison And Validation Techniques, Tiffanie Marie Toles

Doctoral Dissertations

"The three pillars model for sustainability, often represented with three intersecting circles described as economic, environmental, and social factors with sustainability being at the center is a complex and philosophically open model [1]. As society promotes efforts to reduce carbon impacts, there becomes a need to critically review the models employed for understanding. This research presents a validated methodology, an updated conceptual configuration of sustainability for overall use, as well as a sustainable development performance measurement system. Using the 2020 Sustainable Development Goals Index Data, 232 indicators from 193 countries were used to evaluate the efficacy of using more than …


Promoting Enhanced Decision-Making And Proactive Management For Modularization In The Construction Industry Using Risk-Based Approach, Analytical Hierarchy Process, And Graph Theory, Mohamad Abdul Nabi Jan 2023

Promoting Enhanced Decision-Making And Proactive Management For Modularization In The Construction Industry Using Risk-Based Approach, Analytical Hierarchy Process, And Graph Theory, Mohamad Abdul Nabi

Doctoral Dissertations

"Modularization is an approach that can potentially mitigate many of the current construction industry’s challenges. Despite the documented advantages of modularization, the industry is still not able to capitalize on its full potential and benefits. The latter is due to the outdated decision-making models that may not reflect the multiple factors involved in modular construction, the unique source of risks associated with modular construction methods, need for continuous improvement, and complex contractual requirements and disputes. As such, the goal is to promote the use of modularization in the construction industry by enhancing decision-making and proactive risk management. The associated objectives …


A Primal Treatise Of Constant-Force Compliant Segment And Mechanism Design With Applications, Vamsi Lodagala Jan 2023

A Primal Treatise Of Constant-Force Compliant Segment And Mechanism Design With Applications, Vamsi Lodagala

Doctoral Dissertations

"The evolution of compliant mechanisms propelled the development of constant-force mechanisms (CFMs) for various applications because of their unique characteristics. Many research endeavors have presented different techniques that often involve some optimization to design the CFMs. However, the mechanics of the generation of constant force at the elemental level is not well understood. This research effort theorizes and validates that simple, compliant segment with different boundary conditions, subjected to axial loading, produce near-constant force without the need for design optimization. Analytical models are developed based on the pseudo-rigid-body model (PRBM) concept to predict their force-displacement behavior, and to establish that …


Fiber Optic Sensors For Liquid Identifications, Wassana Naku Jan 2023

Fiber Optic Sensors For Liquid Identifications, Wassana Naku

Doctoral Dissertations

"The fiber optic Fabry-Perot interferometer (FPI) is a widely utilized sensing configuration, offering numerous advantages over conventional electronic sensors, including high accuracy, distributed sensing capabilities, immunity to electromagnetic interference, and compact size. In this study, we propose a remarkably simple fiber optic-tip sensor system combined with machine learning techniques for the identification of pure and volatile organic liquids (VOLs).

A liquid droplet forms an extrinsic FPI (EFPI), with its effective reflectance being a function of the droplet's length. As the droplet evaporates, its length decreases. We conducted immersion tests using optical fiber tip sensors and monitored the time-transient responses of …


Introduction Of A Variable Inductance Transformer For The Design Of Resonant Power Converters, Angshuman Sharma Jan 2023

Introduction Of A Variable Inductance Transformer For The Design Of Resonant Power Converters, Angshuman Sharma

Doctoral Dissertations

"Magnetic integration is a hot topic in power electronics that concerns the use of a transformer's leakage and magnetizing inductances purposefully in isolated power electronic converters, thereby giving the opportunity to save the cost and footprint of any additional inductor. This is of prime interest, especially in CLLLC resonant converters which require up to three inductors. For a complete integration of these inductances, the concept of a variable inductance transformer (VIT) is introduced in this thesis. A VIT is an adaptive magnetic structure that facilitates an easy adjustment of both magnetizing and leakage inductances to meet their desired values. However, …


Effects Of Downwash When Measuring Gas Concentration With Uav-Mounted Gas Sensors, Jacob Lane Brinkman Jan 2023

Effects Of Downwash When Measuring Gas Concentration With Uav-Mounted Gas Sensors, Jacob Lane Brinkman

Doctoral Dissertations

"This research concludes that the downwash region of a rotary-wing unmanned aerial vehicle (UAV) does not produce pressure variations substantial enough to cause significant changes in density-based gas concentration measurements. US regulations evaluate gas concentration as a function of gas density, and accurate concentration measurements are critical for protecting health and safety, which means evaluation of actual downwash effects on measured gas concentration is essential.

During experimentation, the UAV was fixed to a stand in a sealed chamber filled with NOx (NO and NO2) of constant concentration. The UAV rotors ran at hovering speeds, and gas concentrations were …


Co2-Assisted Ethylene Production And Subsequent Purification: A Materials Development, Kinetic Assessment, And Process Performance Investigation, Khaled Baamran Jan 2023

Co2-Assisted Ethylene Production And Subsequent Purification: A Materials Development, Kinetic Assessment, And Process Performance Investigation, Khaled Baamran

Doctoral Dissertations

"This research focuses on the In-Situ CO2 capture and utilization in the oxidative dehydrogenation of ethane (ODHE) for ethylene production, and a subsequent ethylene purification through adsorptive separation process. In particular, several dual-function materials (DFMs) were developed, formulated into 3D-structure, and investigated for ODHE reaction to ethylene under various process conditions using CO2 as a mild oxidant. The DFMs materials were consisted of CaO and metal oxides (e.g., Cr2O3 and V2O5) supporting H-ZSM-5. The results indicated that higher cell densities lead to better performance due to kinetic enhancement, and the optimum …