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Articles 1 - 15 of 15
Full-Text Articles in Engineering
Error Reduction For The Determination Of Transverse Moduli Of Single-Strand Carbon Fibers Via Atomic Force Microscopy, Joshua D. Frey
Error Reduction For The Determination Of Transverse Moduli Of Single-Strand Carbon Fibers Via Atomic Force Microscopy, Joshua D. Frey
Theses and Dissertations
The transverse modulus of single strand carbon fibers is measured using PeakForce Atomic Force Microscopy - Quantitative Nanomechanical Measurement to less than 5 percent error for 11 types of carbon fiber with longitudinal moduli between 924-231 GPA, including export-controlled fibers. Statistical methods are employed to improve the quality of data to exclude outliers within an measurement and within the sample set. A positive linear correlation between the longitudinal and transverse modulus with an R2=0.76 is found. Pitch-based fibers exhibit lower measurement error than PAN-based fibers, while PAN fibers exhibited no apparent modulus correlation when the Pitch fibers are …
Laser Induced Thermal Degradation Of Carbon Fiber-Carbon Nanotube Hybrid Laminates, Joshua A. Key
Laser Induced Thermal Degradation Of Carbon Fiber-Carbon Nanotube Hybrid Laminates, Joshua A. Key
Theses and Dissertations
Recent advancements in fiber laser technology have increased interest in target material interactions and the development of thermal protection layers for tactical laser defense. A significant material of interest is carbon fiber reinforced polymers due to their increased use in aircraft construction. In this work, the thermal response of carbon fiber-carbon nanotube (CNT) hybrid composites exposed to average irradiances of 0.87-6.8 W/cm2 were observed using a FLIR sc6900 thermal camera. The camera had a pixel resolution of 640x512 which resulted in a spatial resolution of 0.394x0.383 mm/pixel for the front and 0.463x0.491 mm/pixel for the back. The hybrid samples …
Electrochemical Modification Of Granular Activated Carbon And Carbon Nanofibers To Determine Effect On Adsorption, Jose E. Martinez Sanchez
Electrochemical Modification Of Granular Activated Carbon And Carbon Nanofibers To Determine Effect On Adsorption, Jose E. Martinez Sanchez
Theses and Dissertations
Granular activated carbon and carbon nanofiber samples were tested as is and electrochemically modified to determine the effect on adsorption. An electrochemical cell was used to modify the carbon samples. The samples were then used in bench bottle tests with 2,4-dinitrotoluene (DNT), brilliant blue (BB) dye, and methylene blue (MB) dye solutions and sampled over time intervals. An ultraviolet–visible spectrophotometer was used to analyze the results of the bottle bench tests. The results indicated that electrochemically modified coal-based carbons’ adsorption were improved 25% over the adsorption of the as is carbon samples prior to modification. The electrochemical modification increased adsorption …
Electrical And Physical Property Characterization Of Single Walled Carbon Nanotube Ink For Flexible Printed Electronics, Kristian E. Warner Jr.
Electrical And Physical Property Characterization Of Single Walled Carbon Nanotube Ink For Flexible Printed Electronics, Kristian E. Warner Jr.
Theses and Dissertations
This research presents a method of characterizing single-walled carbon nanotube (SWCNT) ink. This research also examines the results of our characterization efforts. First, the process of ink jet printing SWCNT ink onto organic and inorganic substrates is discussed. Next, the tests for measuring sheet resistance, conductance, inductance, adherence, thickness, roll-off, and S-parameters of the ink are described. Results and findings of the research are presented. The SWCNT ink created by Brewer Science © is shown to be an effective material for additive manufacturing using an aerosol jet printer, but not an inkjet printer. The ink is shown to have a …
Carbon Allotrope Dependence On Temperature And Pressure During Thermal Decomposition Of Silicon Carbide, Munson J. Anderson
Carbon Allotrope Dependence On Temperature And Pressure During Thermal Decomposition Of Silicon Carbide, Munson J. Anderson
Theses and Dissertations
Bulk CNT and graphene films form on SiC using a metal-catalyst-free thermal decomposition approach. In this work, the background vacuum pressure and temperature used in the decomposition process are varied to investigate their impact on the type and quality of carbon allotrope formed on the SiC substrate. The carbon nanostructure growth is performed using two approaches, both of which involve intense heating (1400-1700°C) of SiC under moderate vacuum conditions (0.01 - 0.00001 Torr). The first growth method uses a conventional graphite resistance furnace capable of annealing waferscale samples over 1700°C under vacuum. Using this approach, post-growth characterization is performed using …
Field Emission Of Thermally Grown Carbon Nanostructures On Silicon Carbide, Jonathon M. Campbell
Field Emission Of Thermally Grown Carbon Nanostructures On Silicon Carbide, Jonathon M. Campbell
Theses and Dissertations
CNTs are known to be excellent field emitter due to their unique physical and electrical properties. Because of their semi-metallic nature, CNT do not suffer the thermal runaway found in metallic emitters, and their near one-dimension shape make them an ideal emission sources. CNTs growth by thermal decomposition of silicon carbide does not utilize a catalyst, therefore relatively defect free. One drawback to this method, however is that the CNT grow in a very dense carpet. This very dense CNT carpet comes under the affect of field emission screening effects which dampen the field emission. In this thesis, silicon carbide …
Providing A Theoretical Basis For Nanotoxicity Risk Analysis Departing From Traditional Physiologically-Based Pharmacokinetic (Pbpk) Modeling, Dirk P. Yamamoto
Providing A Theoretical Basis For Nanotoxicity Risk Analysis Departing From Traditional Physiologically-Based Pharmacokinetic (Pbpk) Modeling, Dirk P. Yamamoto
Theses and Dissertations
The same novel properties of engineered nanoparticles that make them attractive may also present unique exposure risks. But, the traditional physiologically-based pharmacokinetic (PBPK) modeling assumption of instantaneous equilibration likely does not apply to nanoparticles. This simulation-based research begins with development of a model that includes diffusion, active transport, and carrier mediated transport. An eigenvalue analysis methodology was developed to examine model behavior to focus future research. Simulations using the physicochemical properties of size, shape, surface coating, and surface charge were performed and an equation was determined which estimates area under the curve for arterial blood concentration, which is a surrogate …
Electrostatic Discharge Properties Of Irradiated Nanocomposites, Joshua D. Mcgary
Electrostatic Discharge Properties Of Irradiated Nanocomposites, Joshua D. Mcgary
Theses and Dissertations
Modernization in space systems requires employment of new light-weight, high performance composite materials that reduce bulk weight and increase structural integrity. This thesis explored the behavior of one such material prior to and following a 35-year simulated space radiation life-cycle. Select electrical properties of nickel nanostrandTM-carbon composites in seven configurations were characterized prior to electron irradiation via surface and bulk resistivity measurements and contact electrostatic discharge (ESD) measurements. Following irradiation at a fluence of 1016 e-/cm2 at an average energy of 500 keV, measurements were repeated and compared against pre-irradiation data. Configuration D is …
Patterning And Characterization Of Carbon Nanotubes Grown In A Microwave Plasma Enhanced Chemical Vapor Deposition Chamber, Mauricio Kossler
Patterning And Characterization Of Carbon Nanotubes Grown In A Microwave Plasma Enhanced Chemical Vapor Deposition Chamber, Mauricio Kossler
Theses and Dissertations
This research studies the growth of carbon nanotubes (CNT) from a nickel catalyst to be used on a field emission device. This thesis can be divided into three sections: the construction of a vacuum chamber for field emission testing, the design and fabrication of a triode structure to enable improved electron emission, and the pretreatment and growth of CNTs. To experimentally test the field emission of CNTs, a vacuum chamber must attain a vacuum of at least 10-5 torr. Our vacuum chamber designed and built achieved a maximum, final pressure of 10-8 torr. A triode structure was designed …
Fatigue Evaluation Of Nanocomposites As Lightweight Electronic Enclosures For Satellites' Applications, Javier Rodriguez
Fatigue Evaluation Of Nanocomposites As Lightweight Electronic Enclosures For Satellites' Applications, Javier Rodriguez
Theses and Dissertations
Existing nanocomposite materials used for satellite applications don't offer the required conductivity and electromagnetic shielding protection, requiring metal shields in order to survive in space. The AFRL Materials and Manufacturing Directorate in conjunction with the private sector have developed a material that promises to blend the attributes of nanocomposites and metal materials. The M55J/RS3 material consists of carbon fibers combined with a polyisocyanate matrix, in which Nickel nanostrandsTM are added. The research effort investigated the changes in the EMI and ESD of the material after being subjected to cyclic loads. Four configurations of a symmetric layup with fibers oriented …
Evaluation Of Nanocomposites As Lightweight Electronic Enclosures For Satellites' Applications, Benjamin T. Harder
Evaluation Of Nanocomposites As Lightweight Electronic Enclosures For Satellites' Applications, Benjamin T. Harder
Theses and Dissertations
The United States military is exploring the use of nanocomposite materials for satellite structural applications. Current composite spacecraft structures are nonconductive and must have expensive shielding materials applied in order to protect the spacecraft from catastrophic damage that can be caused by electromagnetic interference (EMI) and/or electrostatic discharge (ESD) which are characteristics of the space environment. Conductive nanocomposites are being developed for spacecraft structures that will provide ESD and EMI shielding protection without the need for expensive secondary shielding materials. This thesis studied one such material consisting of M55J/RS-3 composite combined with nickel nanostrands™. Four different configurations were tested for …
Nano-Mechanical Properties Of Heat Inactivated Bacillus Anthracis And Bacillus Thuringiensis Spores, Jessica L. Poindexter
Nano-Mechanical Properties Of Heat Inactivated Bacillus Anthracis And Bacillus Thuringiensis Spores, Jessica L. Poindexter
Theses and Dissertations
B. thuringiensis spores must have similar properties to B. anthracis spores to be a good simulant in counter-proliferation studies. In particular, they must behave in a similar way when exposed to high temperatures for short periods of time as would be caused by an explosion. This research project compares surface elasticities for four different spore sample types, B. anthracis spores, heat inactivated B. anthracis spores, B. thuringiensis spores, and heat inactivated B. thuringiensis spores. Heat inactivated spores were exposed to a temperature just high enough that no spores were observed to germinate. Elasticity values for the spore surfaces were determined …
Characterization Of The Field Emission Properties Of Carbon Nanotubes Formed On Silicon Carbide Substrates By Surface Decomposition, Michael C. Pochet
Characterization Of The Field Emission Properties Of Carbon Nanotubes Formed On Silicon Carbide Substrates By Surface Decomposition, Michael C. Pochet
Theses and Dissertations
Dense arrays of vertically aligned carbon nanotubes (CNTs) form on the surface of silicon carbide wafers during high temperature anneals under moderate vacuum conditions. The novelty of this growth method is that the CNTs form without the aid of a metal catalyst, allowing for potentially impurity-free CNTs to form. In this study, CNT films were grown by the surface decomposition of silicon carbide substrates. The associated field emission characteristics were investigated to determine if films grown using this method possessed advantages over films grown using metal-catalyzed methods. The associated turn-on and threshold voltages, maximum current density, and emission current stability …
In Vitro Toxicity Of Aluminum Nanoparticles In Rat Alveolar Macrophages, Andrew J. Wagner
In Vitro Toxicity Of Aluminum Nanoparticles In Rat Alveolar Macrophages, Andrew J. Wagner
Theses and Dissertations
Nanomaterials, which are by definition in the 1 - 100 nanometer range, have numerous possible benefits to society, but currently there is a lack of data that characterizes these materials effects on human health and environment. In general nanomaterials are of interest to the Air Force because of their applications in electronics, sensors, munitions and energetic/reactive systems. Nanoparticles such as aluminum have been considered for enhancing propulsion in solid rocket fuel. To date, only a few studies have looked at the toxicological effects of direct exposure to nanoparticles, none with aluminum. It is important to increase the understanding of the …
Classification Characteristics Of Carbon Nanotube Polymer Composite Chemical Vapor Detectors, Huynh A. Hinshaw
Classification Characteristics Of Carbon Nanotube Polymer Composite Chemical Vapor Detectors, Huynh A. Hinshaw
Theses and Dissertations
The first step in combating a chemical weapons threat is contamination avoidance. This is accomplished by the detection and identification of chemical agents. The Air Force has several instruments to detect chemical vapors, but is always looking for lighter, faster, and more accurate technology for a better capability. This research is focused on using carbon nanotube polymer composite sensors for chemical detection. More specifically, models are developed to classify three sets of sensor data according to vapor using various multivariate techniques. Also, prediction models of a mixed sensor output are developed using neural networks and regression analysis. The classifiers developed …