Engineering Commons^™

Determination Of Critical Experiment Correlations Via The Monte Carlo Sampling Technique, William Jay Marshall

Doctoral Dissertations

Critical benchmark experiments are the foundation of validation of the computational codes used in criticality safety analyses because they provide a basis for comparison between the calculated results and the physical world. These experiments are often performed in series varying a limited number of parameters to isolate the effect of the independent parameter. The use of common materials, geometries, machines, procedures, detectors, or other shared features can create correlations among the resulting experiments. Most validation techniques used in criticality safety practice do not treat these correlations explicitly, and the effect of this is unclear as the correlations themselves are not …

Double Differential Neutron Yields Produced By Proton, Helium, And Iron Interactions In Thick Aluminum Targets, Natalie Ann Mcgirl

Doctoral Dissertations

Recent calculations of galactic cosmic ray (GCR) transport in enclosed, shielded space environments indicate that a minimum dose equivalent is achieved with aluminum shielding thicknesses near 20 g/cm² [grams per centimeter squared]. Increases in the absorbed dose and dose equivalent with shielding thicknesses above 20 g/cm² are believed to be caused by the production of light ions and neutrons in the thick shielding. However, uncertainties surround these calculations due to limited cross section and yield data for high-energy projectiles incident on thick targets. Thick-target neutron yields are particularly valuable measurements since they are produced over a wide range …

A Wide Area Hierarchical Voltage Control For Systems With High Wind Penetration And An Hvdc Overlay, Yidan Lu

Doctoral Dissertations

The modern power grid is undergoing a dramatic revolution. On the generation side, renewable resources are replacing fossil fuel in powering the system. On the transmission side, an AC-DC hybrid network has become increasingly popular to help reduce the transportation cost of electricity. Wind power, as one of the environmental friendly renewable resources, has taken a larger and larger share of the generation market. Due to the remote locations of wind plants, an HVDC overlay turns out to be attractive for transporting wind energy due to its superiority in long distance transmission of electricity.

While reducing environmental concern, the increasing …

Novel Fission Track Detection For Identification And Characterization Of Special Nuclear Materials, Jonathan Allen Gill

Doctoral Dissertations

Fission track detection and analysis is used primarily in nuclear safeguards to identify special nuclear material. Identification of isotopic ratios is a crucial step in understanding the intended use of nuclear material and the nature of the materials production cycle. Unfortunately, this methodology uses etchable track detectors that require significant expertise and intensive labor to process.

This study developed a novel method using lithium fluoride (LiF) as a fluorescing nuclear track detector to conduct fission track analysis for isotopic prediction of uranium enrichment. Individual latent tracks produced by fission products were observed in LiF for the first time. These tracks …

Development Of High-Performing Polydimethylsiloxane-Based Membranes For Carbon Dioxide Separation, Tao Hong

Doctoral Dissertations

Membrane separation is highlighted as one of the most promising approaches to mitigate the excessive CO₂ [carbon dioxide] emission, due to its significant reduction of energy cost compared with many conventional separation techniques. Unfortunately, the separation performance of current membranes does not meet the practical CO₂/N₂ [nitrogen] separation requirements. And due to the huge volume of industrial flue gas, membranes with exceptionally high permeability are needed for practical reasons.

Currently, the separation mechanism of most polymeric membranes is based on size-sieving. However, this method is not sufficient for CO₂/N₂ separations due to the …

Electrochemical Hydrogen Separation Via The Solid Acid Electrolyte Cesium Dihydrogen Phosphate, David Leon Wilson

Doctoral Dissertations

Abundant, inexpensive, high purity molecular hydrogen as a medium for energy distribution is potentially enabling for adoption of alternative electricity generation schemes. Steam reforming of natural gas remains the dominant method of producing large amounts of hydrogen. However, this process also creates by-products, most notably, carbon monoxide and carbon dioxide. Separation to ultra-high purity hydrogen from these syngas reformate streams by traditional methods, such as pressure swing absorption, has its disadvantages including long cycle times, contamination and a large equipment footprint. Alternative methods of hydrogen separation, such as electrochemical pumping, are a viable alternative to this separation dilemma due to …

Low Energy Recoil Simulations In Mgo, Linbo3, And Litao3 Using Ab Initio Molecular Dynamics, Benjamin Aaron Petersen

Doctoral Dissertations

Ab initio molecular dynamics (AIMD) was utilized to test a series of materials, MgO, LiNbO₃ , and LiTaO₃ , to determine defect structures produced due to low energy recoil events . The kinetic energy required to displace an atom from its lattice site, the threshold displacement energy, was calculated for an array of directions in each material, based on symmetry and complexity of the structure. MgO having a simple rock salt structure provided a model material for demonstrating computational techniques used later on LiTaO₃ and LiNbO₃ . The minimum values for displacing an atom were at …

An Exploration Of Basic Processes For Aqueous Electrochemical Production Of Hydrogen From Biomass Derived Molecules, Brian Fane

Doctoral Dissertations

Polymer electrolyte membrane fuel cells(PEMFCs) are energy conversion devices with significant potential. The factors preventing them from becoming widespread concern production and distribution of hydrogen. Developing an efficient hydrogen infrastructure with an approachable rollout plan is an essential step towards the future of fuel cells. Water electrolysis is limited by the thermodynamics of the process, which leads to high electrical consumption and significant materials challenges. Alternative methods for cleanly generating hydrogen while using a lower cell voltage are required. PEM based electrolyzers can operate with a "depolarized anode", whereby they become significantly less power hungry.

This thesis explores two techniques …

Design And Synthesis Of Analogs Of Myo-Inositol, Serine, And Cysteine To Enable Chemical Biology Studies, Tanei J. Ricks

Doctoral Dissertations

Phosphorylated myo-inositol compounds including inositol phosphates (InsPs) as well as the phosphatidylinositol polyphosphate lipids (PIP_ns) are critical biomolecules that regulate many of the most important biological processes and pathways. They are aberrant in many disease states due to their regulatory function. The same is true of the phospholipid phosphatidylserine (PS) which can serve as a marker to begin apoptosis. However, the full scope of activities of these structures is not clear, particularly since techniques that enable global detection and analysis of the production of these compounds spatially and temporally are lacking. With all of these obstacles in …

Nestle To Origami Coupling: A Nuclear Non-Proliferation Tool For Lwr Fuel Assembly Isotope Analysis, Margaret Alva Kurtts

Doctoral Dissertations

NESTLE to ORIGAMI coupling is a versatile nuclear modeling tool that allows researchers to directly observe the impact of operator induced changes on LWR assembly isotope production. The paper presents an experimental method by which to test the ability of an operator to manipulate the core neutron spectrum in order to produce higher quality plutonium for weapons use. The paper presents two plutonium production scenarios and evaluates their feasibility based on potential for detection and production capacity. Reactor modeling of a VVER-1000 uses NESTLE core simulation software. NESTLE outputs burnup and relative power information for all nodes in the core. …

Multiscale Modeling Approach To Understand Active Sites In Non-Conventional Catalyst Layers For Fuel Cell Applications, Diana Constanza Orozco Gallo

Doctoral Dissertations

Fuel cells development required stable, active and more abundant catalytic materials. Oxygen reduction reaction (ORR) is the key process to enhance better activity and reduce the fabrication costs. Pt-based has proven to be the best catalyst for ORR and greater efforts has been made in terms of reducing the Pt content in the electrodes, reduce electrode thickness and enhance better catalytic activities. To overcome many of the challenges present, the catalyst layer studies are the great importance in the fuel cell community. Understanding catalyst layer with new catalytic materials, and configurations requires the development of methodological approach to relate structure, …

Mechanical Behavior Of Pipeline Steels And An Al0.1cocrfeni High-Entropy Alloy, Bilin Chen

Doctoral Dissertations

This dissertation is composed of two parts. The first part focuses on the mechanical behavior study on pipelines steels. More specifically, the effect of hydrogen on the deformation behavior of the crack tip of an X52 pipeline steel specimen, and the overload effects on the fatigue crack growth of an x70 pipeline weld metal are discussed. For the second part of the dissertation, fatigue behavior of an Al0.1CoCrFeNi high-entropy alloy (HEA) is studied, and the influence of heat treatment is discussed.

The objectives of the first part of this proposed work are to (1) detect the influence of hydrogen on …

Determining 235u Enrichment Using A Dual-Energy Approach For Delayed Neutron Measurements, Angela Lynn Lousteau

Doctoral Dissertations

Bulk uranium items are often measured using active neutron interrogation systems to take advantage of the relatively high penetrability of neutrons, providing the ability to quickly and accurately measure uranium masses in large, dense configurations. Active techniques employ an external neutron source to induce fission in the uranium and subsequently measure emitted prompt fission or delayed neutrons. Unfortunately, the emitted neutrons from ²³⁵U [uranium-235] and ²³⁸U [uranium-238] are, for all practical purposes, indistinguishable; therefore, commonly used systems such as the Active Well Coincidence Counter, the ²⁵²Cf [californium-252] Shuffler, and other systems based on measurement of prompt or …

Wide-Area Control Schemes To Improve Small Signal Stability In Power Systems, Meimanat Mahmoudi

Doctoral Dissertations

One of the main concerns for the secure and reliable operation of power systems is the small signal stability problem. In the complex and highly interconnected structure of future power systems, relying solely on operator responses and conventional controls cannot assure reliability. Therefore, there is a need for advanced Wide-Area Control Schemes (WACS) that can automatically respond to degradation of reliability in the system.

The main objective of this dissertation is to address two key challenges regarding the design and implementation of wide-area control schemes for damping inter-area oscillations. First is the high communication cost associated with optimal centralized control …

Transport Of Water And Ions Through Single-Walled Armchair Carbon Nanotubes: A Molecular Dynamics Study, Michelle Patricia Aranha

Doctoral Dissertations

The narrow hydrophobic interior of a carbon nanotube (CNT) poses a barrier to the transport of water and ions, and yet, unexpectedly, numerous experimental and simulation studies have confirmed fast water transport rates comparable to those seen in biological aquaporin channels. These outstanding features of high water permeability and high solute rejection of even dissolved ions that would typically require a lot of energy for separation in commercial processes makes carbon nanotubes an exciting candidate for desalination membranes. Extending ion exclusion beyond simple mechanical sieving by the inclusion of electrostatics via added functionality to the nanotube bears promise to not …

Dynamic In Vivo Skeletal Feature Tracking Via Fluoroscopy Using A Human Gait Model, William Patrick Anderson

Doctoral Dissertations

The Tracking Fluoroscope System II, a mobile robotic fluoroscopy platform, developed and built at the University of Tennessee, Knoxville, presently employs a pattern matching algorithm in order to identify and track a marker placed upon a subject’s knee joint of interest. The purpose of this research is to generate a new tracking algorithm based around the human gait cycle for prediction and improving the overall accuracy of joint tracking.

This research centers around processing the acquired x-ray images of the desired knee joint obtained during standard clinical operation in order to identify and track directly through the acquired image. Due …

Methodology For An Advanced Risk Assessment Of Crud Induced Power Shift Using Coupled Multi-Physics Simulations And A Monte Carlo Scenario Analysis Of The Potential Financial Benefits, Travis Louis Lange

Doctoral Dissertations

Beginning in the 1970's, power uprates in nuclear power plants began to cause an operational problem called Crud Induced Power Shift (CIPS). Over decades, a method has been developed and refined that has allowed industry to effectively avoid CIPS. However, increasingly challenging economic environments have caused power plants to utilize more aggressive core designs. The problem of CIPS still looms over many reactors as a potential hazard requiring conservative measures. CIPS is due to complex physical and chemical interactions. Current industry methods use multiple single-physics simulations in their analyses. However, improved 3D multi-physics models of CIPS can provide a better …

The Rheology And Roll-To-Roll Processing Of Shear-Thickening Particle Dispersions, Sunilkumar Khandavalli

Doctoral Dissertations

Particle dispersions are ubiquitous in our daily lives ranging from food and pharmaceutical products to inks. There has been great interest in the recent years in formulation of functional inks to fabricate myriad flexible electronic devices through high-throughput roll-to-roll technologies. The formulations often contain several functional additives or rheological modifiers that can affect the microstructure, rheology and processing. Understanding the rheology of formulations is important for tuning the formulation for optimal processing. This thesis presents investigations on the rheology of particle dispersions and their impact on roll-to-roll technologies. Shear-thickening behavior is common in particle dispersions, particularly, concentrated particulate inks. We …

Aliovalent Dopants In Zno Nanocrystals: Synthesis To Electronic Structure, Dongming Zhou

Doctoral Dissertations

Semiconductor nanocrystal doping has stimulated broad interest for many applications including solar energy conversion, nanospintronics, and phosphors or optical labels. The study of the chemistry and physics of doped colloidal semiconductor nanocrystals has been dominated in the literature by isovalent dopants such as Mn²⁺ and Co²⁺ ions in II-VI semiconductors, in which the dopant oxidation state is the same as the cation ions. Until recently, aliovalent dopants has received much attention due to the plasmonic properties. Aliovalent is when the oxidation states of the dopant in the lattice differs from the cation ions. In the plasmonic semiconductor nanocrystals, …

Formal Analysis Of Arithmetic Circuits Using Computer Algebra - Verification, Abstraction And Reverse Engineering, Cunxi Yu

Doctoral Dissertations

Despite a considerable progress in verification and abstraction of random and control logic, advances in formal verification of arithmetic designs have been lagging. This can be attributed mostly to the difficulty in an efficient modeling of arithmetic circuits and datapaths without resorting to computationally expensive Boolean methods, such as Binary Decision Diagrams (BDDs) and Boolean Satisfiability (SAT), that require “bit blasting”, i.e., flattening the design to a bit-level netlist. Approaches that rely on computer algebra and Satisfiability Modulo Theories (SMT) methods are either too abstract to handle the bit-level nature of arithmetic designs or require solving computationally expensive decision or …

The Role Of Chain Configuration In Governing The Rational Design Of Polymers For Adhesion, Onyenkachi Wamuo

Doctoral Dissertations

ABSTRACT THE ROLE OF CHAIN CONFIGURATION IN GOVERNING THE RATIONAL DESIGN OF POLYMERS FOR ADHESION SEPTEMBER 2017 ONYENKACHI C. WAMUO, B.Eng., FEDERAL UNIVERSITY OF TECHNOLOGY, OWERRI (FUTO), NIGERIA M.S., UNIVERSITY OF MASSACHUSETTS AMHERST Ph.D., UNIVERSITY OF MASSACHUSETTS AMHERST Directed by: Professor Shaw Ling Hsu The chain configurational control of polymers used in adhesion can be utilized as a means of tuning the cohesive properties of hot melt adhesives (HMAs). The cohesive properties control the solidification, strength, setting speed. Propylene-Ethylene copolymers (PP-co-PE) and thermoplastic polyurethanes (TPUs) were studied. In the first project, the effects of sequence distribution of the two types …

Microbial Competition In Bioelectrochemical Systems, Varun Srinivasan

Doctoral Dissertations

Bioelectrochemical systems(BESs)/ microbial fuel fells (MFCs) are a well-studied potential technology for bioremediation and decentralized wastewater treatment. However, progress has been somewhat stalled at the bench-scale. In well controlled experiments electron recovery is high. In natural environments, wastewaters are complex and anode-respiring bacteria can be outcompeted in the presence of competing microorganisms, leading to a loss in electron-recovery and power production. Furthermore, the cathode of the MFC plays a vital role in providing flexibility for treatment options but is an understudied part of MFCs. Modelling Intracellular Competition in a Denitrifying Biocathode: One potential MFC configuration uses an organic-oxidizing anode biofilm …

Computational Studies Of Structure–Function Relationships Of Supported And Unsupported Metal Nanoclusters, Hongbo Shi

Doctoral Dissertations

Fuel cells have been demonstrated to be promising power generation devices to address the current global energy and environmental challenges. One of the many barriers to commercialization is the cost of precious catalysts needed to achieve sufficient power output. Platinum-based materials play an important role as electrocatalysts in energy conversion technologies. In order to improve catalytic efficiency and facilitate rational design and development of new catalysts, structure–function relationships that underpin catalytic activity must be understood at a fundamental level. First, we present a systematic analysis of CO adsorption on Pt nanoclusters in the 0.2-1.5 nm size range with the aim …

Modeling Performance, Cost, Delivery, And Trip Distribution Of Demand Responsive Transit Systems With Zoning, Mahour Rahimi

Doctoral Dissertations

Demand responsive transit (DRT) services are expensive to operate, so it is crucial to understand the factors that drive the agency costs and be able to investigate and predict the effect of possible changes in specific operating parameters as well as demand and service coverage areas on total costs. In this research, we adopt the concept of the analytical model proposed by Daganzo (1978) to present continuum approximation (CA) models that can estimate important service related factors. As the first step, we propose three analytical models to approximate the operation related variables of DRT services; Fleet Size, Vehicle Hours Traveled …

Theory And Practice Of Supply Chain Synchronization, Michael Prokle

Doctoral Dissertations

In this dissertation, we develop strategies to synchronize component procurement in assemble-to-order (ATO) production and overhaul operations. We focus on the high-tech and mass customization industries which are not only considered to be very important to create or keep U.S. manufacturing jobs, but also suffer most from component inventory burden. In the second chapter, we address the deterministic joint replenishment inventory problem with batch size constraints (JRPB). We characterize system regeneration points, derive a closed-form expression of the average product inventory, and formulate the problem of finding the optimal joint reorder interval to minimize inventory and ordering costs per unit …

Analyses Of Densely Crosslinked Phenolic Systems Using Low Field Nmr, Jigneshkumar Patel

Doctoral Dissertations

A uniform dispersion of reactants is necessary to achieve a complete reaction involving multi-components, especially for the crosslinking of rigid high-performance materials. In these reactions, miscibility is crucial for curing efficiency. This miscibility is typically enhanced by adding a third component, a plasticizer. For the reaction of the highly crystalline crosslinking agent hexamethylenetetramine (HMTA) with a strongly hydrogen-bonded phenol formaldehyde resin, furfural has been traditionally used as the plasticizer. However, the reason for its effectiveness is not clear. In this doctoral thesis work, miscibility and crosslinking efficiency of plasticizers in phenolic curing reactions are studied by thermal analysis and spectroscopic …

Protein-Nanoparticle Co-Engineering: Self-Assembly, Intracellular Protein Delivery, And Crispr/Cas9-Based Gene Editing, Rubul Mout

Doctoral Dissertations

Direct cytoplasmic delivery of gene editing nucleases such CRISPR/Cas9 systems and therapeutic proteins provides enormous opportunities in curing human genetic diseases, and assist research in basic cell biology. One approach to attain such a goal is through engineering nanotechnological tools to mimic naturally existing intra- and extracellular protein delivery/transport systems. Nature builds transport systems for proteins and other biomolecules through evolution-derived sophisticated molecular engineering. Inspired by such natural assemblies, I employed molecular engineering approaches to fabricate self-assembled nanostructures to use as intracellular protein delivery tools. Briefly, proteins and gold nanoparticles were co-engineered to carry complementary electrostatic recognition elements. When these …

Fabrication Of Functional Nano-Structured Materials And Devices Using Supercritical Fluids, Shengkai Li

Doctoral Dissertations

Nano-structured materials possess unconventional properties and enable miniaturization of devices. However, fabrications of such materials and devices are challenging and in many cases cumbersome, and development of nanofabrication techniques are essential to realizing novel designs and commercializing scientific ideas. Supercritical fluids possess a unique combination of gas-like diffusion properties and liquid-like dissolution power, and are suitable reaction media for fabricating materials at the nanometer scale. This dissertation focuses on developing supercritical fluids-related techniques for fast and large-scale fabrication of novel composite materials and devices. Using supercritical fluid deposition (SFD) technique, cobalt thin films were deposited on a variety of substrates, …

Bio-Based Wind Turbine Blades: Renewable Energy Meets Sustainable Materials For Clean, Green Power, Rachel Koh

Doctoral Dissertations

Wood, once the material of choice for wind turbine blades, was phased out in the late 20th century as the growing size of blades imposed stricter material requirements and glass- and carbon-fiber composites gained industry popularity. However, the last several years have seen great advances in bio-based composite materials technology, including flax, hemp, and wood composites and laminates. These materials are increasingly utilized in high-performance, structurally demanding applications, largely because they are a more sustainable choice than many other engineering materials. Today, as the first glass-fiber wind turbine blades are ready to retire, wind developers are presented with an enormous …

Tissue-Guided Engineering Of Polyethylene Glycol Hydrogels, Lauren Jansen

Doctoral Dissertations

Polyethylene glycol (PEG) hydrogels are tunable cell culture platforms that recapitulate tissue geometry, water content, and bulk modulus. Despite these benefits, PEG hydrogels elicit an acute immune response, limiting their use in regenerative medicine, and they critically underrepresent the cell-instructive proteins found in the extracellular matrix (ECM). Here, I developed a new class of tissue-specific PEG-based materials and provided biocompatible strategies to improve the user handling and cell viability post-encapsulation when using these hydrogels. I also demonstrated that decreasing the protein fouling to PEG does not decrease the foreign body response to implanted hydrogels, a common misconception in the field. …