Engineering Commons^™

Engineering Polymers Through Impact Modification And Superheated Liquid Processing, Gregory Connor Evans

Doctoral Dissertations

A new approach to toughen anionically polymerized polyamide 6 (aPA6) was applied using reaction induced phase separation (RIPS). This method solved issues with particle dispersion, mixture viscosity, and additive concentration common with conventional rubber toughening thereby making it an ideal candidate for fiber reinforced aPA6 reaction injection molding (RIM). Octamethylcyclotetrasiloxane (D₄) was used as a functional additive that undergoes RIPS during aPA6 polymerization and polymerizes to polydimethylsiloxane (PDMS). Controlled phase separation, modulus retention, and increased crystallinity were achieved at low additive concentrations. Optimal properties were achieved with 2 wt% D₄. Fracture energy was measured at high …

Polymer And Small Molecule Designs For Anion Conducting Membranes: Connected Ion-Channel Morphologies And Highly Alkaline Stable Ammonium Cations, Sedef P. Ertem

Doctoral Dissertations

Fuel cells are one of the oldest sustainable energy generation devices, converting chemical energy into electrical energy via reverse-electrolysis reactions. With the rapid development of polymer science, solid polymer electrolyte (SPE) membranes replaced the conventional liquid ion transport media, rendering low-temperature fuel cells more accessible for applications in portable electronics and transportation. However, SPE fuel cells are still far from commercialization due to high operation cost, and insufficient lifetime and performance limitations. Anion exchange membrane fuel cells (AEMFCs) are inexpensive alternatives to current proton exchange membrane fuel cell (PEMFC) technology, which relies on utilizing expensive noble-metal catalysts and perfluorinated SPE …

Reduced Order Fluid-Structure Interaction Models For Thin Shells With Non-Zero Gaussian Curvatures To Understand The Response Of Aneurysms To Flow, Gary Han Chang

Doctoral Dissertations

In this thesis, a reduced-order model is constructed to study the physiological flow and wall shear stress conditions for aneurysms. The method of local proper orthogonal decomposition (POD) is used to construct the reduced-order modes using a series of CFD results, which are subsequently improved using a QR-factorization technique to satisfy the various boundary conditions in physiological flow problems. This method can effectively construct a computationally efficient physiological model, which allows us to examine the fluid velocities and wall shear stress distributions over a range of different physiological flow parameters. Aneurysms are the dilation, bulging, or ballooning-out of part of …

Automatic Development And Adaptation Of Concise Nonlinear Models For System Identification, William G. La Cava

Doctoral Dissertations

Mathematical descriptions of natural and man-made processes are the bedrock of science, used by humans to understand, estimate, predict and control the natural and built world around them. The goal of system identification is to enable the inference of mathematical descriptions of the true behavior and dynamics of processes from their measured observations. The crux of this task is the identification of the dynamic model form (topology) in addition to its parameters. Model structures must be concise to offer insight to the user about the process in question. To that end, this dissertation proposes three methods to improve the ability …

Extracellular Matrix Control Of Breast Cancer Metastasis And Dormancy, Lauren Barney

Doctoral Dissertations

To metastasize, a cell must travel through circulation to a secondary tissue, and this process causes 90% of all cancer deaths. Although inefficient, metastasis is not random, and only capable seeds in hospitable soils are capable of outgrowing into detectable metastases. The overall hypothesis in this work is that the secondary tissue microenvironment, particularly the extracellular matrix (ECM), mediates metastasis. We posit that the ability of metastatic cells to survive dormancy, exit quiescence, and colonize a tissue depends upon the ability of the soil to sustain survival, and subsequently trigger outgrowth. We created a simple biomaterial platform with systematic control …

Eulerian Cfd Modeling Of Multiphase Internal Injector Flow And External Sprays, Eli T. Baldwin

Doctoral Dissertations

The improvement of combustion systems which use sprays to atomize liquid fuel requires an understanding of that atomization process. Although the secondary break up mechanisms for the far-field of an atomizing spray have been thoroughly studied and well understood for some time, understanding the internal nozzle flow and primary atomization on which the far-field spray depends has proven to be more of a challenge. Flow through fuel injector nozzles can be highly complex and heavily influenced by factors such as turbulence, needle motion, nozzle imperfections, nozzle asymmetry, and phase change. All of this occurs within metallic injectors, making experimental characterization …

Dynamic Wetting And Drag Reduction On Superhydrophobic And Liquid-Infused Surfaces, Jeong-Hyun Kim

Doctoral Dissertations

Reducing drag in fluid flow has been one of the most widely studied topics in fluid dynamics due to the significant impact on improving operational efficiencies and cutting cost in applications from the aerospace, automotive and naval industries. Over the past two decades, superhydrophobic surfaces have been in the spotlight due to their ability to reduce frictional drag on the wall surface in both laminar and turbulent flows. Despite the extensive work on superhydrophobic surfaces, there are still a number of open questions remaining. In this dissertation, we investigate how a moving contact line interacts with a superhydrophobic surface by …

The Stability Of Ferrate(Vi) In Water And Its Impacts On Disinfection Byproduct Precursors, Yanjun Jiang

Doctoral Dissertations

Ferrate has been proposed as an alternative pre-oxidant in drinking water treatment for many years. Despite extensive studies that examined ferrate oxidation of specific contaminants, little research has been done on the impacts of ferrate in raw waters that include natural organic matter (NOM) and bromide, and that are also treated with coagulants and chlorine. The future of ferrate as a potable water treatment chemical depends on its ability to achieve adequate disinfection while minimizing the formation of disinfection byproducts (DBPs) under these realistic scenarios. In this work, laboratory-scale treatment studies were conducted to (1) clarify the stability of ferrate …

Proactive Assessment Of Climate Change And Contaminant Spill Impacts On Source Water Quality, Lillian C. Jeznach

Doctoral Dissertations

Managing the water quality of surface drinking water sources has become an increasingly difficult task for water suppliers due to increased watershed urbanization and climate change. Changes in source water quality may affect public perceptions, treatment effectiveness, and ultimately costs to treat water to drinking standards. Although there are increased threats to current and future drinking water quality, current approaches to managing these threats are typically reactionary. Prior detailed modeling efforts of hypothetical events that may impair raw water quality allow for an understanding of constituent fate and transport, including potential maximum concentrations and travel times to the drinking water …

Design, Implementation, And Evaluation Of A User Training Program For Integrating Health Information Technology Into Clinical Processes, Ze He

Doctoral Dissertations

Health information technology (IT) implementation can be costly, and remains a challenging problem with mixed outcomes on patient safety and quality of care. Systems engineering and IT management experts have advocated the use of sociotechnical models to understand the impact of health IT on user and organizational factors. Sociotechnical models suggest the need for user-centered implementation approaches, such as user training and support, and focus on processes to mitigate the negative impact and facilitate optimal IT use during training. The training design and development should also follow systematic processes guided by instructional development models. It should take into account of …

Investigate The Interactions Between Silver Nanoparticles And Spinach Leaf By Surface Enhanced Raman Spectroscopic Mapping, Zhiyun Zhang

Masters Theses

Owing to their increasing application and potential toxicity, engineered nanoparticles (ENPs) have been considered as a potential agricultural contaminant that may pose unknown risk to human beings. However, many techniques require invasive and complicated sample preparation procedures to detect and characterize engineered nanomaterials in complex matrices. In the first part of this thesis, we present a non-destructive and label-free approach based on surface enhanced Raman spectroscopic (SERS) mapping technique to qualitatively detect and characterize gold nanoparticles (AuNPs), on and in spinach leaves in situ. We were able to detect the clearly enhanced signals from AuNPs at 15 to 125 nm …

Live Load Distribution Factors For Horizontally Curved Concrete Box Girder Bridges, Mohammed Zaki

Masters Theses

Live load distribution factors are used to determine the live-load moment for bridge girder design when a two dimensional analysis is conducted. A simple, analysis of bridge superstructures are considered to determine live-load factors that can be used to analyze different types of bridges. The distribution of the live load factors distributes the effect of loads transversely across the width of the bridge superstructure by proportioning the design lanes to individual girders through the distribution factors.

This research study consists of the determination of live load distribution factors (LLDFs) in both interior and exterior girders for horizontally curved concrete box …

Variation Aware Placement For Efficient Key Generation Using Physically Unclonable Functions In Reconfigurable Systems, Shrikant S. Vyas

Masters Theses

With the importance of data security at its peak today, many reconfigurable systems are used to provide security. This protection is often provided by FPGA-based encrypt/decrypt cores secured with secret keys. Physical unclonable functions (PUFs) use random manufacturing variations to generate outputs that can be used in keys. These outputs are specific to a chip and can be used to create device-tied secret keys. Due to reliability issues with PUFs, key generation with PUFs typically requires error correction techniques. This can result in substantial hardware costs. Thus, the total cost of a $n$-bit key far exceeds just the cost of …

Numerical Simulation Of High Velocity Impact Of A Single Polymer Particle During Cold Spray Deposition, Sagar P. Shah

Masters Theses

Abstract

The cold spray process is an additive manufacturing technology primarily suited for ductile metals, and mainly utilized in coating surfaces, manufacturing of freeform parts and repair of damaged components. The process involves acceleration of solid micro-particles in a supersonic gas flow and coating build-up by bonding upon high velocity impact onto a substrate. Coating deposition relies on the kinetic energy of the particles. The main objective of this study was to investigate the mechanics of polymer cold spray process and deformation behavior of polymers to improve technological implementation of the process.

A finite element model was created to simulate …

A Soft Multiple-Degree Of Freedom Load Cell Based On The Hall Effect, Qiandong Nie

Masters Theses

The goal of this thesis is to develop a soft multiple-degree-of-freedom (multi-DOF) load cell that is robust and light weight for use in robotics applications to sense three axes of force and a single axis of torque. The displacement of the magnet within the elastomer changes the magnetic flux density which is sensed by two 3-axis Hall effect sensors. Experimental measurements of magnetic flux density within the area of interest were used to formulate analytic expressions that relate magnet field strength to the position of the magnet. The displacement and orientation measurement and the material properties of the elastomer are …

Intent Recognition Of Rotation Versus Translation Movements In Human-Robot Collaborative Manipulation Tasks, Vinh Q. Nguyen

Masters Theses

The goal of this thesis is to enable a robot to actively collaborate with a person to move an object in an efficient, smooth and robust manner. For a robot to actively assist a person it is key that the robot recognizes the actions or phases of a collaborative tasks. This requires the robot to have the ability to estimate a person’s movement intent. A hurdle in collaboratively moving an object is determining whether the partner is trying to rotate or translate the object (the rotation versus translation problem). In this thesis, Hidden Markov Models (HMM) are used to recognize …

Extrinsic Effects On Heat And Electron Transport In Two-Dimensional Van-Der Waals Materials- A Boltzmann Transport Study, Arnab K. Majee

Masters Theses

Two-dimensional van der Waals materials have been a subject of intense research interest in recent years. High thermal conductivity of graphene can be utilized for many thermal management applications. In spite of possessing very high electron mobility, graphene can’t be used as transistors because of the absence of band gap; however transition metal dichalcogenides are another class of two-dimensional van der Waals materials with inherent band gap and show a great promise for future nanoelectronic applications. But in order to tailor these properties for commercial applications, we should develop a better understanding of the effect of extrinsic factors like size, …

Infrastructure-Free Secure Pairing Of Mobile Devices, Chunqiu Liu

Masters Theses

Mobile devices have advanced tremendously during the last ten years and have changed our daily life in various ways. Secure pairing of mobile devices has become a significant issue considering the huge quantity of active mobile device connections and mobile traffic. However, current commonly used file sharing mobile applications rely on servers completely that are always targeted by attackers. In this thesis work, an innovative mechanism is proposed to generate symmetric keys on both mobile devices independently from a shared movement in arbitrary pattern, which means no server needs to be involved and no data exchange needed. A secret wireless-communication …

Protecting Controllers Against Denial-Of-Service Attacks In Software-Defined Networks, Jingrui Li

Masters Theses

Connection setup in software-defined networks (SDN) requires considerable amounts of processing, communication, and memory resources. Attackers can target SDN controllers defense mechanism based on a proof-of-work protocol. This thesis proposes a new protocol to protect controllers against such attacks, shows implementation of the system and analyze the its performance. The key characteristics of this protocol, namely its one-way operation, its requirement for freshness in proofs of work, its adjustable difficulty, its ability to work withmultiple network providers, and its use of existing TCP/IP header fields, ensure that this approach can be used in practice.

Improving Efficiency Of Thermoelectric Devices Made Of Si-Ge, Si-Sn, Ge-Sn, And Si-Ge-Sn Binary And Ternary Alloys, Seyedeh Nazanin Khatami

Masters Theses

Thermoelectric devices with the ability to convert rejected heat into electricity are widely used in nowadays technology. Several studies have been done to improve the efficiency of these devices. However, because of the strong correlation between thermoelectric properties (electrical conductivity, Seebeck coefficient, and thermal conductivity including lattice and electron counterpart), improving ZT has always been a challenging task. In this study, thermal conductivity of group IV-based binary and ternary alloys such as SiGe, SiSn, GeSn, and SiGeSn has been studied. Phonon Boltzmann Transport Equation has been solved in the relaxation time approximation including intrinsic and extrinsic (in the presence of …

Cold Gas Dynamic Spray – Characterization Of Polymeric Deposition, Trenton Bush

Masters Theses

When a solid, ductile particle impacts a substrate at sufficient velocity, the resulting heat, pressure, and plastic deformation can produce bonding at the interface. The use of a supersonic gas flow to accelerate such particles is known as Cold Spray deposition. The Cold Spray process has been commercialized for some metallic materials, but further research is required to unlock the exciting material properties possible with polymeric compounds. In this work, a combined computational and experimental study a) simulated and optimized the nozzle flow conditions necessary to produce bonding in a polyethylene particle, b) developed and fabricated an experimental device, and …

Electromagnetic Scattering Models For Insar Correlation Measurements Of Vegetation And Snow, Yang Lei

Doctoral Dissertations

Interferometric Synthetic Aperture Radar (InSAR) has proved successful and efficient in measuring the vertical structure of the distributed targets such as vegetation and snow, which are dominated by volume scattering. In particular, the InSAR correlation measurement has been utilized to retrieve the target vertical structural information. One existing and well-known electromagnetic scattering model of the InSAR correlation was first brought forward focusing on the single-pass InSAR observation of a sparse random medium like vegetation. However, the lack of the adaption of this InSAR scattering model for repeat-pass InSAR observation of vegetation as well as for single-pass InSAR observation of snow …

Morphological And Material Effects In Van Der Waals Interactions, Jaime C. Hopkins

Doctoral Dissertations

Van der Waals (vdW) interactions influence a variety of mesoscale phenomena, such as surface adhesion, friction, and colloid stability, and play increasingly important roles as science seeks to design systems on increasingly smaller length scales. Using the full Lifshitz continuum formulation, this thesis investigates the effects of system materials, shapes, and configurations and presents open-source software to accurately calculate vdW interactions. In the Lifshitz formulation, the microscopic composition of a material is represented by its bulk dielectric response. Small changes in a dielectric response can result in substantial variations in the strength of vdW interactions. However, the relationship between these …

Synthesis And Applications Of Non-Migratory Metal Chelating Active Packaging, Maxine J. Roman

Doctoral Dissertations

Many packaged foods use synthetic chelators (e.g. ethylenediaminetetraacetic acid, EDTA) to inhibit metal promoted oxidation and/or microbial growth that may cause food spoilage. Consumer demand for foods without synthetic additives has prompted growing interest in alternative preservation methods. Our research group has previously developed non-migratory metal chelating active packaging materials by surface immobilization of polymeric chelators and demonstrated their ability to inhibit lipid oxidation in model food emulsions. The work presented in this dissertation investigates the synthesis, performance stability, and practical application of metal chelating surface modifications to optimize design of non-migratory metal chelating active packaging materials. Metal chelating active …

Synthesis And Characterization Of Polymeric Anion Exchange Membranes, Wenxu Zhang

Doctoral Dissertations

As alkaline anion exchange membrane fuel cells (AAEMFC) are regarded as promising and important energy devices, the development of high performance anion exchange membranes are in urgent need, as well as fundamental investigation on the structure-property relationship, which are the motivation of this dissertation. Three different polymer systems are presented and focused on polymer synthesis, material morphology, and ion transport phenomena. Crosslinked membranes are promising as practical materials, however, the understanding and further improvement of its performance is hindered by the lack of an ordered morphology or well-defined chemical structure. In Chapter 2, a series of crosslinked membranes were design …

Enzyme Stabilization In Hierarchical Biocatalytic Food Packaging And Processing Materials, Dana Erin Wong

Doctoral Dissertations

The partnership of biocatalysts and solid support materials provides many opportunities for bioactive packaging and bioprocessing aids beneficial to the agricultural and food industries. Biocatalysis, or reactions modulated by enzymes, allows bioactive materials to assist in bringing a substrate to product. Enzymes are proteins which catalyze reactions by lowering the activation energy required to drive the production of a desired product. Enzymes are commonly utilized in food processing as catalysts with specificity in order to enhance product quality through the production of beneficial food components, and to break down undesirable components that may be harmful or may decrease product quality. …

Development Of A Portable Cmos Time-Domain Fluorescence Lifetime Imager, Hongtao Wang

Doctoral Dissertations

Modern laboratory equipments to measure the excited-state lifetime of fluorophores usually include an expensive picosecond pulsed-laser excitation source, a fragile photomultiplier tube, and a large instrument body for optics. A portable and robust device to make fluorescence lifetime measurement in nanosecond scale is of great attraction for chemists and biologists. This dissertation reports the development of a portable LED time-domain fluorimeter from an all-solid-state discrete-component prototype to its advanced CMOS integrated circuit implementation. The motivation of the research is to develop a multiplexed fluorimeter for point-of-care diagnosis. Instruments developed by this novel method have higher fill factor, are more portable, …

Wind Farm Wake Modeling And Analysis Of Wake Impacts In A Wind Farm, Yujia Hao

Doctoral Dissertations

More and more wind turbines have been grouped in the same location during the last decades to take the advantage of profitable wind resources and reduced maintenance cost. However wind turbines located in a wind farm are subject to a wind field that is substantially modified compared to the ambient wind field due to wake effects. The wake results in a reduced power production, increased load variation on the waked turbine, and reduced wake farm efficiency. Therefore the wake has long been an important concern for the wind farm installation, maintenance, and control. Thus a wake simulation tool is required. …

Bioengineered Platforms To Study Carcinoma Cell Response To Drug Treatment, Thuy V. Nguyen

Doctoral Dissertations

The tumor extracellular matrix (ECM) plays an important role in facilitating tumor growth and mediating tumor cells' resistance to drugs. However, during drug development, potential chemotherapeutics are screened in plastic plates, which lack relevant ECM physicochemical cues. In order to improve drug development process, this dissertation includes the development of relevant 2D and 3D biomaterial systems that can be used to study carcinoma cell response to drug treatment. A novel poly(ethylene glycol)-phosphorylcholine (PEG-PC) high-throughput biomaterial platform was developed to study how the ECM mechanochemical properties affect cancer cells' response to drug. The PEG-PC biomaterial is optically transparent, has a mechanical …

Structure And Dynamics Of Charged Colloidal Disks In Colloid-Polymer Mixtures, Suhasini Kishore

Doctoral Dissertations

Complex fluid mixtures of colloids and polymers are extensively used in several conventional and emerging technological applications. Particles self-assemble under different conditions to form colloidal glasses and gels and it often leads to the development of unusual viscoelastic features. In the case of aspherical particles, shape anisotropy and physical aging effects add to the existing complexities so the implementation of a strategic formulation method to improve performance and stability remains a critical challenge. This thesis presents a comprehensive analysis of particle interactions in mixtures of charged disk-shaped colloids and weakly-adsorbing polymers like poly(ethylene oxide) (PEO). Here, we discuss the behavior …