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Full-Text Articles in Engineering

The Use Of Embedded Sensors For The Monitoring Of Adhesive Joints In Marine Environments, Scott T. Mcgovern, Geoffrey M. Spinks, G G. Wallace Mar 2013

The Use Of Embedded Sensors For The Monitoring Of Adhesive Joints In Marine Environments, Scott T. Mcgovern, Geoffrey M. Spinks, G G. Wallace

Gordon Wallace

A copolymer incorporating polyaniline was used as a sensing medium in the construction of a resistance based humidity sensor. Aniline monomer was polymerised in the presence of poly (butyl acrylate / vinyl acetate) and a copolymer containing polyaniline emeraldine salt was obtained. The sensing medium was then developed by redissolving 1-2 w/w% of the resulting polymer residue in dichloromethane to produce a processable polymer blend solution. Some of this polymer residue was also de-doped in a solution of ammonia, and then washed with distilled water until the waste water had a neutral pH. This residue was then redissolved at 1-2 …


Highly Processable Method For The Construction Of Miniature Conducting Polymer Moisture Sensors, Scott T. Mcgovern, Geoffrey M. Spinks, G G. Wallace Mar 2013

Highly Processable Method For The Construction Of Miniature Conducting Polymer Moisture Sensors, Scott T. Mcgovern, Geoffrey M. Spinks, G G. Wallace

Gordon Wallace

A polymer blend incorporating polyaniline (PAn) was used as a sensing medium in the construction of a resistance based humidity sensor. Aniline monomer was polymerised to PAn emeraldine salt (ES) in the presence of poly (butyl acrylate-co-vinyl acetate) and the processable blend was developed by redissolving 1-2 w/w% of the resulting sensing polymer residue in dichloromethane (DCM). Some of this residue was washed in ammonia solution to de-dope the PAn to emeraldine base (EB) to act as a protective layer on the surface of the sensing polymer. This residue was then washed with distilled water until a neutral pH was …


Flexible Free-Standing Graphene-Silicon Composite Film For Lithium-Ion Batteries, Jiazhao Wang, Chao Zhong, Shulei Chou, Hua Liu Feb 2013

Flexible Free-Standing Graphene-Silicon Composite Film For Lithium-Ion Batteries, Jiazhao Wang, Chao Zhong, Shulei Chou, Hua Liu

Shulei Chou

Flexible, free-standing, paper-like, graphene-silicon composite materials have been synthesized by a simple, one-step, in-situ filtration method. The Si nanoparticles are highly encapsulated in a graphene nanosheet matrix. The electrochemical results show that graphene-Si composite film has much higher discharge capacity beyond 100 cycles (708 mAh g− 1) than that of the cell with pure graphene (304 mAh g− 1). The graphene functions as a flexible mechanical support for strain release, offering an efficient electrically conducting channel, while the nanosized silicon provides the high capacity.


Nanocrystalline Nio Hollow Spheres In Conjunction With Cmc For Lithium-Ion Batteries, Chao Zhong, Jiazhao Wang, Shulei Chou, Konstantin Konstantinov, Mokhlesur Rahman, Hua Liu Feb 2013

Nanocrystalline Nio Hollow Spheres In Conjunction With Cmc For Lithium-Ion Batteries, Chao Zhong, Jiazhao Wang, Shulei Chou, Konstantin Konstantinov, Mokhlesur Rahman, Hua Liu

Shulei Chou

Hollow spherical NiO particles were prepared using the spray pyrolysis method with different concentrations of precursor. The electrochemical properties of the NiO electrodes, which contained a new type of binder, carboxymethyl cellulose (CMC), were examined for comparison with NiO electrodes with polyvinylidene fluoride (PVDF) binder. The electrochemical performance of NiO electrodes using CMC binder was significantly improved. For the cell made from 0.3 mol L−1 precursor, the irreversible capacity loss between the first discharge and charge is about 43 and 24% for the electrode with PVDF and CMC binder, respectively. The cell with NiO–CMC electrode has a much higher discharge …


Reducing Wave-Based Teleoperator Reflections For Unknown Environments, Laurence Bate, Christopher Cook, Zheng Li Feb 2013

Reducing Wave-Based Teleoperator Reflections For Unknown Environments, Laurence Bate, Christopher Cook, Zheng Li

Christopher Cook

Wave variables guarantee stability for delayed teleoperation. They also introduce reflections which can prove very disorientating for an operator. This paper presents a new method for reducing the wave reflections when operating in unknown environments. The new method does not only guarantee stability but also laboratory experiments show it also reduces wave reflections allowing for improved velocity tracking and force feedback in complex and unknown operating environments.


Simultaneous Activated Carbon Adsorption Within A Membrane Bioreactor For An Enhanced Micropollutant Removal, Xueqing Li, Faisal I. Hai, Long Nghiem Dec 2012

Simultaneous Activated Carbon Adsorption Within A Membrane Bioreactor For An Enhanced Micropollutant Removal, Xueqing Li, Faisal I. Hai, Long Nghiem

Long D Nghiem

Significant adsorption of sulfamethoxazole and carbamazepine to powdered activated carbon (PAC) was confirmed by a series of adsorption tests. In contrast, adsorption of these micropollutants to the sludge was negligible. The removal of these compounds in membrane bioreactor (MBR) was dependent on their hydrophobicity and loading as well as the PAC dosage. Sulfamethoxazole exhibited better removal rate during operation under no or low (0.1 g/L) PAC dosage. When the PAC concentration in MBR was raised to 1.0 g/L, a sustainable and significantly improved performance in the removal of both compounds was observed – the removal efficiencies of sulfamethoxazole and carbamazepine …


Treatment Of Coal Seam Gas Produced Water For Beneficial Use In Australia: A Review Of Best Practices, Long Nghiem, Ting Ren, Najdat Aziz, Ian Porter, Gyanendra Regmi Dec 2012

Treatment Of Coal Seam Gas Produced Water For Beneficial Use In Australia: A Review Of Best Practices, Long Nghiem, Ting Ren, Najdat Aziz, Ian Porter, Gyanendra Regmi

Long D Nghiem

There has been an exponential increase in both the production and exploration of coal seam gas (CSG) in Australia and many other regions in the world. A major issue associated with the production of CSG is the management of produced water. CSG is usually mixed with water in the coal seam, to recover the gas, the water must be first extracted from the coal seam to reduce pressure. This water — known as co-produced water or CSG water — is typically quite saline, large in volume and may contain heavy metals and other trace elements of concern. The management of …


Membrane Bioreactor Technology For Decentralised Wastewater Treatment, Nichanan Tadkaew, Long Nghiem, Muttucumaru Sivakumar Dec 2012

Membrane Bioreactor Technology For Decentralised Wastewater Treatment, Nichanan Tadkaew, Long Nghiem, Muttucumaru Sivakumar

Long D Nghiem

Driven by stricter environmental regulations and legalisation on wastewater discharge and shrinking fresh water resources, water treatment has become an area of significant concern while at the same time there is a growing interest in utilising non-traditional water resources by means of water reclamation and water recycling.


Transmitter Diversity Antenna Selection Techniques For Wireless Channels Utilizing Differential Space-Time Block Codes, Jennifer Seberry, A. Mertins, Tadeusz Wysocki, Le Chung Tran Dec 2012

Transmitter Diversity Antenna Selection Techniques For Wireless Channels Utilizing Differential Space-Time Block Codes, Jennifer Seberry, A. Mertins, Tadeusz Wysocki, Le Chung Tran

Dr Le Chung Tran

No abstract provided.


Contextual Effects In Modeling For Small Domain Estimation, Mohammad-Reza Namazi-Rad, David G. Steel Dec 2012

Contextual Effects In Modeling For Small Domain Estimation, Mohammad-Reza Namazi-Rad, David G. Steel

Professor David Steel

Many different Small Area Estimation (SAE) methods have been proposed to overcome the challenge of findingreliable estimates for small domains. Often, the required data for various research purposes are available at differentlevels of aggregation. Based on the available data, individual-level or aggregated-level models are used in SAE.However, parameter estimates obtained from individual and aggregated level analysis may be different, in practice.This may happen due to some substantial contextual or area-level effects in the covariates which may be misspecifiedin individual-level analysis. If small area models are going to be interpretable in practice, possible contextualeffects should be included. Ignoring these effects leads …


Linear Predictive Perceptual Filtering For Acoustic Vector Sensors: Exploiting Directional Recordings For High Quality Speech Enhancement, Muawiyath Shujau, Christian Ritz, Ian Burnett Dec 2012

Linear Predictive Perceptual Filtering For Acoustic Vector Sensors: Exploiting Directional Recordings For High Quality Speech Enhancement, Muawiyath Shujau, Christian Ritz, Ian Burnett

Dr Muawiyath Shujau

This paper investigates the performance of a new technique for speech enhancement which combines Linear Predictive (LP) spectrum-based perceptual filtering to the recordings obtained from an Acoustic Vector Sensor (AVS). The technique takes advantage of the directional polar responses of the AVS to obtain a significantly more accurate representation of the LP spectrum of a target speech signal in the presence of noise when compared to single channel, omni-directional recordings. Comparisons between the speech quality obtained from the proposed technique and existing beamforming-based speech enhancement techniques for the AVS are made through Perceptual Evaluation of Speech Quality (PESQ) tests and …


Coupling Biophysical And Socioeconomic Models For Coral Reef Systems In Quintana Roo, Mexican Caribbean, Deborah Cleland, Jess Melbourne-Thomas, Craig Johnson, Pascal Perez, Jeremy Eustache, Elizabeth Fulton Nov 2012

Coupling Biophysical And Socioeconomic Models For Coral Reef Systems In Quintana Roo, Mexican Caribbean, Deborah Cleland, Jess Melbourne-Thomas, Craig Johnson, Pascal Perez, Jeremy Eustache, Elizabeth Fulton

Professor Pascal Perez

No abstract provided.


Verification Of The Plan Dosimetry For High Dose Rate Brachytherapy Using Metal-Oxide-Semiconductor Field Effect Transistor Detectors, Zhen-Yu Qi, Xiao-Wu Deng, Shao-Min Huang, Jie Lu, Michael Lerch, Dean Cutajar, Anatoly Rosenfeld Nov 2012

Verification Of The Plan Dosimetry For High Dose Rate Brachytherapy Using Metal-Oxide-Semiconductor Field Effect Transistor Detectors, Zhen-Yu Qi, Xiao-Wu Deng, Shao-Min Huang, Jie Lu, Michael Lerch, Dean Cutajar, Anatoly Rosenfeld

Dean Cutajar

The feasibility of a recently designed metal–oxide–semiconductor field effect transistor (MOSFET) dosimetry system for dose verification of high dose rate (HDR) brachytherapy treatment planning was investigated. MOSFET detectors were calibrated with a 0.6 cm3 NE-2571 Farmer-type ionization chamber in water. Key characteristics of the MOSFET detectors, such as the energy dependence, that will affect phantom measurements with HDR 192Ir sources were measured. The MOSFET detector was then applied to verify the dosimetric accuracy of HDR brachytherapy treatments in a custom-made water phantom. Three MOSFET detectors were calibrated independently, with the calibration factors ranging from 0.187 to 0.215 cGy∕mV. A distance …


In Vivo Verification Of Superficial Dose For Head And Neck Treatments Using Intensity-Modulated Techniques, Zhen-Yu Qi, Xiao-Wu Deng, Shao-Min Huang, Li Zhang, Zhi-Chun He, X. Allen Li, Ian Kwan, Michael Lerch, Dean Cutajar, Peter Metcalfe, Anatoly Rosenfeld Nov 2012

In Vivo Verification Of Superficial Dose For Head And Neck Treatments Using Intensity-Modulated Techniques, Zhen-Yu Qi, Xiao-Wu Deng, Shao-Min Huang, Li Zhang, Zhi-Chun He, X. Allen Li, Ian Kwan, Michael Lerch, Dean Cutajar, Peter Metcalfe, Anatoly Rosenfeld

Dean Cutajar

Skin dose is one of the key issues for clinical dosimetry in radiation therapy. Currently planning computer systems are unable to accurately predict dose in the buildup region, leaving ambiguity as to the dose levels actually received by the patient’s skin during radiotherapy. This is one of the prime reasons why in vivo measurements are necessary to estimate the dose in the buildup region. A newly developed metal-oxide-semiconductor-field-effect-transistor (MOSFET) detector designed specifically for dose measurements in rapidly changing dose gradients was introduced for accurate in vivo skin dosimetry. The feasibility of this detector for skin dose measurements was verified in …


Silicon/Single-Walled Carbon Nanotube Composite Paper As A Flexible Anode Material For Lithium Ion Batteries, Shulei Chou, Yue Zhao, Jiazhao Wang, Zhixin Chen, Hua-Kun Liu, S. X. Dou Nov 2012

Silicon/Single-Walled Carbon Nanotube Composite Paper As A Flexible Anode Material For Lithium Ion Batteries, Shulei Chou, Yue Zhao, Jiazhao Wang, Zhixin Chen, Hua-Kun Liu, S. X. Dou

Shulei Chou

Flexible silicon/single-walled carbon nanotube (Si/SWCNT) composite paper was prepared using the pulsed laser deposition (PLD) method to deposit Si onto SWCNT paper. In the composite, Si mainly shows nanoworm-like morphology. Increasing deposition time results in an increased amount of Si microspheres. Electrochemical measurements show that the capacity of the composite paper is improved by the presence of Si. The Si/SWCNT composite with only 2.2% Si shows a capacity of 163 mA h g−1 at a current density of 25 mA g−1 up to 50 cycles, which is more than 60% improvement of the capacity of pristine CNT paper. The Si …


Rapid Synthesis Of Li4ti5o12 Microspheres As Anode Materials And Its Binder Effect For Lithium-Ion Battery, Shulei Chou, Jiazhao Wang, Hua Liu, S. Dou Nov 2012

Rapid Synthesis Of Li4ti5o12 Microspheres As Anode Materials And Its Binder Effect For Lithium-Ion Battery, Shulei Chou, Jiazhao Wang, Hua Liu, S. Dou

Shulei Chou

Li4Ti5O12 microspheres composed of nanoflakes were synthesized within 1 h by a combination of a microwave-assisted hydrothermal method and a microwave postannealing process. The Li4Ti5O12 microspheres were characterized by X-ray diffraction, Brunauer–Emmett–Teller N2 adsorption, scanning electron microscopy, Raman spectroscopy, and transmission electron microscopy. Sodium carboxymethyl cellulose (CMC) was also investigated as a low-cost green binder. The electrochemical tests, including constant current charge–discharge, cyclic voltammetry, and electrochemical impedance spectroscopy, demonstrated that the electrode using CMC as binder had better high-rate capability than the one with polyvinylidene fluoride (PVDF) binder. The electrode using CMC and PVDF as binder had the same lithium …


Silver-Coated Tio2 Nanostructured Anode Materials For Lithium Ion Batteries, - Md. Mokhlesur Rahman, Jiazhao Wang, David Wexler, Yuyuan Zhang, Xinjun Li, Shulei Chou, Hua Liu Nov 2012

Silver-Coated Tio2 Nanostructured Anode Materials For Lithium Ion Batteries, - Md. Mokhlesur Rahman, Jiazhao Wang, David Wexler, Yuyuan Zhang, Xinjun Li, Shulei Chou, Hua Liu

Shulei Chou

Anatase TiO2 nanoribbons/nanotubes (TiO2-NRTs) have been synthesised successfully via a reflux method followed by drying in a vacuum oven, and then, silver-coated TiO2 NRTs (Ag/TiO2-NRTs) were prepared by coating silver particles onto the TiO2-NRTs surface by the traditional silver mirror reaction. The physical properties of the synthesised products were examined in detail using X-ray diffraction, field emission gun scanning electron microscopy, energy-dispersive X-ray spectroscopy, and transmission electron microscopy, respectively. The results indicated that the Ag nanoparticles were uniformly deposited on the surface of the TiO2 nanoribbons/nanotubes. The electrochemical properties were investigated …


Nanocrystalline Porous A-Life02-C Composite-An Environmentally Friendly Cathode For The Lithium-Ion Battery, Md Mokhlesur Rahman, Jiazhao Wang, Mohd Faiz Hassan, Shulei Chou, Zhixin Chen, Hua Liu Nov 2012

Nanocrystalline Porous A-Life02-C Composite-An Environmentally Friendly Cathode For The Lithium-Ion Battery, Md Mokhlesur Rahman, Jiazhao Wang, Mohd Faiz Hassan, Shulei Chou, Zhixin Chen, Hua Liu

Shulei Chou

A novel nanocrystalline porous α-LiFeO2–C composite with a high surface area of around 115 m2 g−1 has been synthesized by a simple molten salt method, followed by a carbon coating process. The structure and morphology were confirmed by X-ray diffraction, field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM). FE-SEM observations demonstrated that the morphology consists of α-LiFeO2–C nanoclusters composed of very tiny nanoparticles joined together by a porous architecture. TEM investigations revealed that amorphous carbon was incorporated into the pores among the nanoparticles and that some nanoparticles were covered by a thin layer of carbon as well. …


Electrochemical Deposition Of Porous Vox And Mno2 Nanowires On Stainless Steel Mesh For Flexible Supercapacitors, Shulei Chou, Jiazhao Wang, Hua Liu, S Dou Nov 2012

Electrochemical Deposition Of Porous Vox And Mno2 Nanowires On Stainless Steel Mesh For Flexible Supercapacitors, Shulei Chou, Jiazhao Wang, Hua Liu, S Dou

Shulei Chou

Porous vanadium oxide (VOx) and MnO2 nanowires were synthesized by an electrochemical deposition method using stainless steel mesh as substrate. The as-prepared porous VOx and MnO2 nanowire films were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and Raman spectroscopy. The cyclic voltammetry (CV) results show that the MnO2 nanowire film shows specific capacitance of 195, 170, 158, and 91 F g-1 at scan rates of 5, 10, 20, and 50 mV s-1, respectively. The porous VOx film displays specific capacitance of 152, 124, 99, and 76 F g …


Electrodeposition Of Mno2 Nanowires On Carbon Nanotube Paper As Free-Standing, Flexible Electrode For Supercapacitors, Shulei Chou, Jia-Zhao Wang, Sau-Yen Chew, Hua Liu, S Dou Nov 2012

Electrodeposition Of Mno2 Nanowires On Carbon Nanotube Paper As Free-Standing, Flexible Electrode For Supercapacitors, Shulei Chou, Jia-Zhao Wang, Sau-Yen Chew, Hua Liu, S Dou

Shulei Chou

MnO2 nanowires were electrodeposited onto carbon nanotube (CNT) paper by a cyclic voltametric technique. The as-prepared MnO2 nanowire/CNT composite paper (MNCCP) can be used as a flexible electrode for electrochemical supercapacitors. Electrochemical measurements showed that the MNCCP electrode displayed specific capacitances as high as 167.5 F g-1 at a current density of 77 mA g-1. After 3000 cycles, the composite paper can retain more than 88% of initial capacitance, showing good cyclability. The CNT paper in the composite acted as a good conductive and active substrate for flexible electrodes in supercapacitors, and the nanowire structure of the MnO2 could facilitate …


Nickel Sulfide Cathode In Combination With An Ionic Liquid-Based Electrolyte For Rechargeable Lithium Batteries, Jiazhao Wang, Shulei Chou, Sau Yen Chew, Jiazeng Sun, Maria Forsyth, Douglas Macfarlane, Hua Liu Nov 2012

Nickel Sulfide Cathode In Combination With An Ionic Liquid-Based Electrolyte For Rechargeable Lithium Batteries, Jiazhao Wang, Shulei Chou, Sau Yen Chew, Jiazeng Sun, Maria Forsyth, Douglas Macfarlane, Hua Liu

Shulei Chou

Nickel sulfides, pure Ni3S2 and a mixture of Ni7S6-NiS, were synthesized through a solvothermal process. The nickel sulphide powders were characterised by X-ray diffraction, scanning electron microscopy, and electrochemical testing. The results showed that the capacity of NiS-Ni7S6 is much higher than that of Ni3S2, when used as the cathode in a lithium cell with an organic solvent-based electrolyte, 1 M lithium bis (trifluoromethanesulfonyl)amide (LiNTf2) in poly(ethylene glycol) dimethyl either 500. The NiS-Ni7S6 electrodes were also tested with an ionic liquid electrolyte consisting of 1 M LiNTf2 in N-methyl-N-propyl pyrrolidinium bis(trifioromethanesulfonyl)amide ([C3mpyr][NTf2]) to compare with organic-solvent based electrolytes. The result …


Electrochemical Deposition Of Porous Co3o4 Nanostructured Thin Film For Lithium-Ion Battery, Shulei Chou, Jiazhao Wang, Hua Liu, S. Dou Nov 2012

Electrochemical Deposition Of Porous Co3o4 Nanostructured Thin Film For Lithium-Ion Battery, Shulei Chou, Jiazhao Wang, Hua Liu, S. Dou

Shulei Chou

Porous Co3O4 nanostructured thin films are electrodeposited by controlling the concentration of Co(NO3)2 aqueous solution on nickel sheets, and then sintered at 300C for 3 h. The as-prepared thin films are characterised by thermogravimetric analysis (TGA), X-ray diffraction (XRD), and scanning electron microscopy (SEM). The electrochemical measurements show that the highly porous Co3O4 thin film with the highest electrochemically active specific surface area (68.64 m2 g-1) yields the best electrochemical performance compared with another, less-porous film and with a non-porous film. The highest specific capacity (513 mAh g-1 after 50 cycles) is obtained from the thinnest film with Co3O4 loaded …


The Compatibility Of Transition Metal Oxide/Carbon Composite Anode And Ionic Liquid Electrolyte For The Lithium-Ion Battery, Shulei Chou, Lin Lu, Jiazhao Wang, Md Mokhlesur Rahman, Chao Zhong, Hua Liu Nov 2012

The Compatibility Of Transition Metal Oxide/Carbon Composite Anode And Ionic Liquid Electrolyte For The Lithium-Ion Battery, Shulei Chou, Lin Lu, Jiazhao Wang, Md Mokhlesur Rahman, Chao Zhong, Hua Liu

Shulei Chou

Three types of transition metal oxide/carbon composites including Fe2O3/C, NiO/C and CuO/Cu2O/C synthesized via spray pyrolysis were used as anode for lithium ion battery application in conjunction with two types of ionic liquid: 1 M LiN(SO2CF3)2 (LiTFSI) in 1-ethyl-3-methyl-imidazolium bis(fluorosulfonlyl)imide (EMI-FSI) or 1-methyl-1-propylpyrrolidinium bis(fluorosulfonyl)imide (Py13-FSI). From the electrochemical measurements, the composite electrodes using Py13-FSI as electrolyte show much better electrochemical performance than those using EMI-FSI as electrolyte in terms of reversibility. The Fe2O3/C composite shows the highest specific capacity and the best capacity retention (425 mAh g−1) under a current density of 50 mA g−1 for up to 50 cycles, …


Sno2-Coated Multiwall Carbon Nanotube Composite Anode Materials For Rechargeable Lithium-Ion Batteries, Lukman Noerochim, Jiazhao Wang, Shulei Chou, Huijun Li, Hua Liu Nov 2012

Sno2-Coated Multiwall Carbon Nanotube Composite Anode Materials For Rechargeable Lithium-Ion Batteries, Lukman Noerochim, Jiazhao Wang, Shulei Chou, Huijun Li, Hua Liu

Shulei Chou

SnO2-coated multiwall carbon nanotube (MWCNT) nanocomposites were synthesized by a facile hydrothermal method. The as-prepared nanocomposites were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), and thermogravimetric analysis (TGA). The SnO2/MWCNT composites, when combined with carboxymethyl cellulose (CMC) as a binder, show excellent cyclic retention, with the high specific capacity of 473 mAh g−1 beyond 100 cycles, much greater than that of the bare SnO2 which was also prepared by the hydrothermal method in the absence of MWCNTs. The enhanced capacity retention could be mainly attributed to …


Electrochemical Deposition Of Porous Co(Oh)2 Nanoflake Films On Stainless Steel Mesh For Flexible Supercapacitors, Shulei Chou, Jiazhao Wang, Hua-Kun Liu, S. X. Dou Nov 2012

Electrochemical Deposition Of Porous Co(Oh)2 Nanoflake Films On Stainless Steel Mesh For Flexible Supercapacitors, Shulei Chou, Jiazhao Wang, Hua-Kun Liu, S. X. Dou

Shulei Chou

Flexible porous Co(OH)2 nanoflake films were prepared by galvanostatic electrodeposition on lightweight and inexpensive stainless steel mesh. The as-prepared porous Co(OH)2 nanoflake films were characterized by X-ray diffraction, thermogravimetric analysis, and scanning electron microscopy. Electrochemical tests including cyclic voltammetry, constant current charge-discharge, and electrochemical impedance spectroscopy were also used to investigate the electrochemical performance. The results show that the highest capacitance is 609.4 F g-1, the specific capacitance decreases by less than 5% as the mass loading of Co(OH)2 increases by more than 340%, and the specific capacitance only decreases by less than 15% when the current densities increase up …


Highly Flexible And Bendable Free-Standing Thin Film Polymer For Battery Application, Jiazhao Wang, Shulei Chou, Hao Liu, Guoxiu Wang, Chao Zhong, Sau Yen Chew, Hua Liu Nov 2012

Highly Flexible And Bendable Free-Standing Thin Film Polymer For Battery Application, Jiazhao Wang, Shulei Chou, Hao Liu, Guoxiu Wang, Chao Zhong, Sau Yen Chew, Hua Liu

Shulei Chou

Highly flexible and bendable free-standing polypyrrole (PPy) films were prepared using the electrochemical polymerization method. The paper-like films are soft, lightweight, mechanically robust, and highly electrically conductive. The morphologies and electrochemical behaviour of the free-standing pure PPy films were affected by the electrochemical polymerization conditions. The free-standing films show promise as cathodes for flexible and bendable batteries.


Basic Molten Salt Process-A New Route For Synthesis Of Nanocrystalline Li4ti5o12-Tio2 Anode Material For Li-Ion Batteries Using Eutectic Mixture Of Lino3-Lioh-Li2o2, Md Mokhlesur Rahman, Jiazhao Wang, Mohd Hassan, Shulei Chou, David Wexler, Hua Liu Nov 2012

Basic Molten Salt Process-A New Route For Synthesis Of Nanocrystalline Li4ti5o12-Tio2 Anode Material For Li-Ion Batteries Using Eutectic Mixture Of Lino3-Lioh-Li2o2, Md Mokhlesur Rahman, Jiazhao Wang, Mohd Hassan, Shulei Chou, David Wexler, Hua Liu

Shulei Chou

A nanocrystalline Li4Ti5O12–TiO2 duplex phase has been synthesized by a simple basic molten salt process (BMSP) using an eutectic mixture of LiNO3–LiOH–Li2O2 at 400–500 °C. The microstructure and morphology of the Li4Ti5O12–TiO2 product are characterized by means of X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and transmission electron microscopy (TEM). The sample prepared by heat-treating at 300 °C for 3 h (S-1) reveals dense agglomerates of ultra-fine nanocrystalline Li4Ti5O12; with heat treatment at …


Spray Pyrolyzed Nio-C Nanocomposite As An Anode Material For The Lithium-Ion Battery With Enhanced Capacity Retention, - Md. Mokhlesur Rahman, Shulei Chou, Chao Zhong, Jiazhao Wang, David Wexler, Hua Liu Nov 2012

Spray Pyrolyzed Nio-C Nanocomposite As An Anode Material For The Lithium-Ion Battery With Enhanced Capacity Retention, - Md. Mokhlesur Rahman, Shulei Chou, Chao Zhong, Jiazhao Wang, David Wexler, Hua Liu

Shulei Chou

NiO–C nanocomposite was prepared by a spray pyrolysis method using a mixture of Ni(NO3)2 and citric acid solution at 600 °C. The microstructure and morphology of the NiO–C composite were characterized by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS) mapping, and thermogravimetric analysis (TGA). The results showed that the NiO nanoparticles were surrounded by amorphous carbon. Electrochemical tests demonstrated that the NiO–C nanocomposites exhibited better capacity retention (382 mAh g− 1 for 50 cycles) than that of pure NiO (141 mAh g− 1 for 50 cycles), which was also prepared by spray pyrolysis using …


Rapid Synthesis Of Binary -Nisb-Nis By Microwave Autoclave For Rechargeable Lithium Batteries, Nurul Idris, - Md. Mokhlesur Rahman, Shulei Chou, Jiazhao Wang, David Wexler, Hua Liu Nov 2012

Rapid Synthesis Of Binary -Nisb-Nis By Microwave Autoclave For Rechargeable Lithium Batteries, Nurul Idris, - Md. Mokhlesur Rahman, Shulei Chou, Jiazhao Wang, David Wexler, Hua Liu

Shulei Chou

To reduce the reaction time, electrical energy consumption, and cost, binary α-NiS–β-NiS has been synthesized by a rapid, one-pot, hydrothermal autoclave microwave method within 15 min at temperatures of 160–180 °C. The microstructure and morphology of the α-NiS–β-NiS products were characterized by means of X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and transmission electron microscopy (TEM). At 140 °C, pure hexagonal NiAs-type α-NiS phase was identified from the XRD patterns. With increasing reaction temperature (160–180 °C), the XRD evidence indicates that an increasing fraction of rhombohedral millerite-like β-NiS is formed as a secondary phase. The α-NiS–β-NiS sample synthesized …


Reducing Wave-Based Teleoperator Reflections For Unknown Environments, Laurence Bate, Christopher Cook, Zheng Li Nov 2012

Reducing Wave-Based Teleoperator Reflections For Unknown Environments, Laurence Bate, Christopher Cook, Zheng Li

Laurence Bate Dr.

Wave variables guarantee stability for delayed teleoperation. They also introduce reflections which can prove very disorientating for an operator. This paper presents a new method for reducing the wave reflections when operating in unknown environments. The new method does not only guarantee stability but also laboratory experiments show it also reduces wave reflections allowing for improved velocity tracking and force feedback in complex and unknown operating environments.