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Articles 31 - 60 of 842
Full-Text Articles in Engineering
Switching Of Control Mechanisms During The Rapid Solidification Of A Melt Pool, Yijia Gu, Jiandong Yuan, Lianyi Chen
Switching Of Control Mechanisms During The Rapid Solidification Of A Melt Pool, Yijia Gu, Jiandong Yuan, Lianyi Chen
Materials Science and Engineering Faculty Research & Creative Works
The Solidification of Alloys is Typically Controlled by Solute Diffusion Due to the Solute Partitioning Happening at the Solid-Liquid Interface. in This Study, We Show that the Switching from Solute Diffusion-Controlled Growth to Thermal Diffusion-Controlled Growth May Happen at the Solidification Front during Rapid Solidification Processes of Alloys Such as Additive Manufacturing using a Phase-Field Model. the Switching is Found to Be Triggered by the Cooling of the Solid-Liquid Interface When It Becomes Colder Than the Solidus Temperature. the Switching Introduces a Sudden Jump of Growth Velocity, an Increase in Solute Concentration, and the Refining of the Resulting Microstructures. All …
Large-Scale Cascading Of First-Order Fbg Array In A Highly Multimode Coreless Fiber Using Femtosecond Laser For Distributed Thermal Sensing, Farhan Mumtaz, Bohong Zhang, Ronald J. O'Malley, Jie Huang
Large-Scale Cascading Of First-Order Fbg Array In A Highly Multimode Coreless Fiber Using Femtosecond Laser For Distributed Thermal Sensing, Farhan Mumtaz, Bohong Zhang, Ronald J. O'Malley, Jie Huang
Electrical and Computer Engineering Faculty Research & Creative Works
This research focuses on the performance analysis and characterization of a fiber Bragg gratings (FBGs) array, consisting of 10 first order FBGs inscribed by a femtosecond (FS) laser in a highly multimode coreless fiber. The study evaluates the FBG array's ability to function as a distributed thermal sensing (DTS) platform, with the coreless fiber chosen as the sensing element due to its immunity to dopant migration at high temperatures. The design of a large cascaded first-order FBG array effectively eliminates unwanted harmonic peaks across a wide spectrum range. In contrast, higher-order FBGs introduce limitations due to the overlapping of Bragg …
Electrosteric Control Of The Aggregation And Yielding Behavior Of Concentrated Portlandite Suspensions, Sharu Bhagavathi Kandy, Narayanan Neithalath, Mathieu Bauchy, Aditya Kumar, Edward Garboczi, Torben Gaedt, Samanvaya Srivastava, Gaurav Sant
Electrosteric Control Of The Aggregation And Yielding Behavior Of Concentrated Portlandite Suspensions, Sharu Bhagavathi Kandy, Narayanan Neithalath, Mathieu Bauchy, Aditya Kumar, Edward Garboczi, Torben Gaedt, Samanvaya Srivastava, Gaurav Sant
Materials Science and Engineering Faculty Research & Creative Works
Portlandite (calcium hydroxide: CH: Ca (OH)2) suspensions aggregate spontaneously and form percolated fractal aggregate networks when dispersed in water. Consequently, the viscosity and yield stress of portlandite suspensions diverge at low particle loadings, adversely affecting their processability. Even though polycarboxylate ether (PCE)-based comb polyelectrolytes are routinely used to alter the particle dispersion state, water demand, and rheology of similar suspensions (e.g., ordinary portland cement suspensions) that feature a high pH and high ionic strength, their use to control portlandite suspension rheology has not been elucidated. This study combines adsorption isotherms and rheological measurements to elucidate the role of PCE composition …
A Spike-Shaped Anchorage For Steel Reinforced Polymer (Srp)-Strengthened Concrete Structures, Xingxing Zou, Keenan L. Mcburney, Lesley H. Sneed
A Spike-Shaped Anchorage For Steel Reinforced Polymer (Srp)-Strengthened Concrete Structures, Xingxing Zou, Keenan L. Mcburney, Lesley H. Sneed
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
Steel reinforced polymer (SRP) composite has recently emerged as an effective and economical solution for strengthening of reinforced concrete (RC) structures. Premature debonding failure of unanchored SRP at low load levels generally governs the performance of RC structures strengthened with externally bonded SRP. Therefore, a novel yet simple spike-shaped anchorage system was proposed in this study to prevent the debonding failure of SRP and to improve the interfacial shear capacity. Experimental investigation through single-lap shear tests of SRP-concrete joints showed that the anchorage system changed the failure mode from composite debonding to fiber rupture. In addition, the anchorage system substantially …
Calibration Of The Johnson–Cook Model At High Temperatures For An Ultra-High Strength Crnimov Steel, Mario F. Buchely, S. Chakraborty, V. Athavale, Laura Bartlett, Ronald J. O'Malley, D. Field, K. Limmer, K. Sebeck
Calibration Of The Johnson–Cook Model At High Temperatures For An Ultra-High Strength Crnimov Steel, Mario F. Buchely, S. Chakraborty, V. Athavale, Laura Bartlett, Ronald J. O'Malley, D. Field, K. Limmer, K. Sebeck
Materials Science and Engineering Faculty Research & Creative Works
This paper presents a study on the thermo-mechanical behavior of an ultra-high strength CrNiMoV steel at high temperatures and medium strain rates through hot tensile tests. The material was examined in two conditions: as-cast/heat-treated (AC/HT) and as-rolled (AR). Tensile tests were conducted at temperatures of 800,900,1000,1100, and 1200°C, and strain rates of 0.1,1, and 10s−1. Inclusion and porosity analysis was also performed on the tensile specimens. The results revealed that the flow stress decreased by approximately 70% on average from 800°C to 1200°C, while increasing by approximately 32% on average from 0.1s−1 to 10s−1 in strain rate. The elongation exhibited …
A Strong And Ductile Cobalt-Free Solid-Solution Fe30ni30mn30cr10 Multi-Principal Element Alloy From Hot Rolling, Hans Pommerenke, Jiaqi Duan, Nathan Curtis, Victor Delibera, Adam Bratten, Andrew Hoffman, Mario F. Buchely, Ronald J. O'Malley, Haiming Wen
A Strong And Ductile Cobalt-Free Solid-Solution Fe30ni30mn30cr10 Multi-Principal Element Alloy From Hot Rolling, Hans Pommerenke, Jiaqi Duan, Nathan Curtis, Victor Delibera, Adam Bratten, Andrew Hoffman, Mario F. Buchely, Ronald J. O'Malley, Haiming Wen
Materials Science and Engineering Faculty Research & Creative Works
Most of the Face-Centered Cubic (FCC) Multi-Principal Element Alloys (MPEAs) Developed Thus Far Contain Cobalt. for Many Applications, it is Either required or Beneficial to Avoid Cobalt, Since Cobalt Has Long-Term Activation Issue (For Nuclear Applications), is Expensive, and is Considered a Critical Material. in Addition, FCC Structured Solid-Solution MPEAs Tend to Have Relatively Low Strength. a FCC Solid-Solution Fe30Ni30Mn30Cr10 (At %) MPEA Was Fabricated Via Arc Melting, Followed by Homogenization at 1100 °C for 12 H. the Alloy Was Hot Rolled at 1100 °C with a Total Reduction of Up to 97 %. the Microstructure Was Characterized and Mechanical …
Engineering Heterogeneous Nucleation During Solidification Of Multiphase Cast Alloys: An Overview, Simon (Semen) N. Lekakh, Jingjing Qing
Engineering Heterogeneous Nucleation During Solidification Of Multiphase Cast Alloys: An Overview, Simon (Semen) N. Lekakh, Jingjing Qing
Materials Science and Engineering Faculty Research & Creative Works
The theory of heterogeneous nucleation was initially developed as a part of condensed matter physics, and later it was used as an important engineering tool to design metallurgical processes. This success has led to wide applications of the theory in metallurgical practice. For example, engineering heterogeneous nucleation in ductile iron has been used to reduce shrinkage defects, suppress cementite formation, and modify the size and shape of microstructural constituencies. This demonstrates how theoretical knowledge could benefit industry practice. This overview aims to summarize the authors' published studies in co-authorship with colleagues and students, which covers different aspects of engineering heterogeneous …
Nonmonotonic Effect Of Chemical Heterogeneity On Interfacial Crack Growth At High-Angle Grain Boundaries In Fe-Ni-Cr Alloys, Yuchu Wang, Bita Ghaffari, Christopher Taylor, Simon Lekakh, Carlos Engler-Pinto, Larry Godlewski, Yang Huo, Mei Li, Yue Fan
Nonmonotonic Effect Of Chemical Heterogeneity On Interfacial Crack Growth At High-Angle Grain Boundaries In Fe-Ni-Cr Alloys, Yuchu Wang, Bita Ghaffari, Christopher Taylor, Simon Lekakh, Carlos Engler-Pinto, Larry Godlewski, Yang Huo, Mei Li, Yue Fan
Electrical and Computer Engineering Faculty Research & Creative Works
An intermittent pattern is observed in the modeling of interfacial cyclic-loading crack growth at high-angle grain boundaries in ternary Fe-Ni-Cr alloys. Different from conventional wisdom of stress-intensity factor, the abrupt crack advances are found driven by extreme value statistics - namely, the aggregation of atoms with most compressive residual stresses. In addition, inherently non-affine atomic stress fluctuations are discovered, and the fluctuations peak at intermediate level of chemical heterogeneity, causing the fastest crack growth. Implications of such nonmonotonic mechanism in regard to the origin of intermediate-temperature embrittlement phenomena are also discussed.
Dissolution Rates Of Borophosphate Glasses In Deionized Water And In Simulated Body Fluid, Parker T. Freudenberger, Rebekah L. Blatt, Richard K. Brow
Dissolution Rates Of Borophosphate Glasses In Deionized Water And In Simulated Body Fluid, Parker T. Freudenberger, Rebekah L. Blatt, Richard K. Brow
Materials Science and Engineering Faculty Research & Creative Works
Particles of Borophosphate Glasses with the Nominal Molar Compositions 16Na2O-(24-Y)CaO-YSrO-XB2O3-(60-X)P2O5 (Mol%), Where 0 ≤ X ≤ 60 and Y = 0, 12, and 24, Were Reacted in Deionized Water and in Simulated Body Fluid (SBF) at 37 °C. for the Dissolution Experiments in Water, the PH of the Solution at the Conclusion of the Experiments Increased Systematically, from 2.1 to 9.5, for Y = 0 Glasses When 'x' Increased from 0 to 60. the Reaction Rates over the First 8–24 H of Dissolution in Both SBF and Deionized Water Followed Linear …
Experimental And Machine Learning Studies On Chitosan-Polyacrylamide Copolymers For Selective Separation Of Metal Sulfides In The Froth Flotation Process, Keitumetse Monyake, Taihao Han, Danish Ali, Lana Z. Alagha, Aditya Kumar
Experimental And Machine Learning Studies On Chitosan-Polyacrylamide Copolymers For Selective Separation Of Metal Sulfides In The Froth Flotation Process, Keitumetse Monyake, Taihao Han, Danish Ali, Lana Z. Alagha, Aditya Kumar
Mining Engineering Faculty Research & Creative Works
The froth flotation process is extensively used for the selective separation of valuable base metal sulfides from uneconomic associated minerals. However, in this complex multiphase process, various parameters need to be optimized to ensure separation selectivity and peak performance. In this study, two machine learning (ML) models, artificial neural network (ANN) and random forests (RF), were used to predict the efficiency of in-house synthesized chitosan-polyacrylamide copolymers (C-PAMs) in the depression of iron sulfide minerals (i.e., pyrite) while valuable base metal sulfides (i.e., galena and chalcopyrite) were floated using nine flotation variables as inputs to the models. The prediction performance of …
Erratum To “Structure Of Tin Phosphate Glasses By Neutron And X-Ray Diffraction” [Journal Of Non Crystalline Solids:X 2c (2019) 100017] (Journal Of Non-Crystalline Solids: X (2019) 2, (S2590159119300305), (10.1016/J.Nocx.2019.100017)), U. Hoppe, Richard K. Brow, A. C. Hannon, M. V. Zimmermann
Erratum To “Structure Of Tin Phosphate Glasses By Neutron And X-Ray Diffraction” [Journal Of Non Crystalline Solids:X 2c (2019) 100017] (Journal Of Non-Crystalline Solids: X (2019) 2, (S2590159119300305), (10.1016/J.Nocx.2019.100017)), U. Hoppe, Richard K. Brow, A. C. Hannon, M. V. Zimmermann
Materials Science and Engineering Faculty Research & Creative Works
The publisher regrets the following conflict of interest text was not published. • All the authors listed in this article have made Substantial contributions to the conception or design of the work; or the acquisition, analysis, or interpretation of data for the work; AND drafting the work or revising it critically for important intellectual content; AND Final approval of the version to be published. • I also undertake that the article represents valid work. Neither this article nor any part of it has been copied or plagiarized from other works. • That the article has not been published so far …
Effect Of Cr And Ni Concentrations On Resilience Of Cast Nb-Alloyed Heat Resistant Austenitic Steels At Extreme High Temperatures, Simon N. Lekakh, Mario F. Buchely, Mei Li, Larry Godlewski
Effect Of Cr And Ni Concentrations On Resilience Of Cast Nb-Alloyed Heat Resistant Austenitic Steels At Extreme High Temperatures, Simon N. Lekakh, Mario F. Buchely, Mei Li, Larry Godlewski
Materials Science and Engineering Faculty Research & Creative Works
Austenitic Cr–Ni Alloyed Heat Resistant Steels with Nb Additions Are Used for Intensively Thermo-Mechanically Loaded Cast Components Working in Extreme High Temperature Oxidizing Environment. their Performance during Static Oxidation and Transient Thermo-Mechanical Loading Was Investigated to Recommend an Optimal Cost-Effective Cr/Ni Composition of Nb-Alloyed Austenitic Class Steels. the Static Oxidation and Transient Thermo-Mechanical Behavior of Three Austenitic Steels with Different Cr/Ni Alloying Levels Were Investigated and Compared for Variety of Working Conditions. Static Oxidation Was Performed between 900 °C and 1000 °C in Air for 400 H. the Critical Temperature Which Increases Spallation during Static Oxidation Was Determined for Each …
A Prediction Of Young's Modulus For Tin Containing Phosphate Glasses Using Quantitative Structural Information, Tatsuki Shimizu, Akira Saitoh, Uwe Hoppe, Grégory Tricot, Richard K. Brow
A Prediction Of Young's Modulus For Tin Containing Phosphate Glasses Using Quantitative Structural Information, Tatsuki Shimizu, Akira Saitoh, Uwe Hoppe, Grégory Tricot, Richard K. Brow
Materials Science and Engineering Faculty Research & Creative Works
A Rigid Unit Packing Fraction (RUPF) Model Was Used to Better Understand the Influence of Local Structural Units on the Young's Elastic Modulus (E) of Binary and Ternary Tin Phosphate Glasses. Quantitative Analyses of the Units that Constitute the Glass Structure, Obtained from X-Ray/neutron Diffraction and 31P MAS-NMR Spectroscopy, Were Used to Calculate Polyhedral Packing Fractions that, with Tabulated Bond Dissociation Energies, Were Used to Predict E based on a Modification of the Makashima-Mackenzie Relationship, Which Uses Ion Sizes to Calculate Packing Fractions. Predictions based on the RUPF Model Are Better Than Those based on Ion Sizes, and Extending the …
A Hyperbaric Aerodynamic Levitator For Containerless Materials Research, Sydney E. Boland, Stephen K. Wilke, Jonathan A. Scott, Sarah M. Schlossberg, Alex Ivaschenko, Richard J.K. Weber, David W. Lipke
A Hyperbaric Aerodynamic Levitator For Containerless Materials Research, Sydney E. Boland, Stephen K. Wilke, Jonathan A. Scott, Sarah M. Schlossberg, Alex Ivaschenko, Richard J.K. Weber, David W. Lipke
Materials Science and Engineering Faculty Research & Creative Works
A hyperbaric aerodynamic levitator has been developed for containerless materials research at specimen temperatures exceeding 2000 °C and pressures up to 10.3 MPa (1500 psi). This report describes the prototype instrument design and observations of the influence of specimen size, density, pressure, and flow rate on levitation behavior. The effect of pressure on heat transfer was also assessed by studying the heating and cooling behavior of levitated Al2O3 liquids. A threefold increase in the convective heat transfer coefficient was estimated as pressure increased to 10.3 MPa. The results demonstrate that hyperbaric aerodynamic levitation is a promising technique for containerless materials …
Review Of Magnetic Properties And Texture Evolution In Non-Oriented Electrical Steels, Yizhou Du, Ronald J. O'Malley, Mario F. Buchely
Review Of Magnetic Properties And Texture Evolution In Non-Oriented Electrical Steels, Yizhou Du, Ronald J. O'Malley, Mario F. Buchely
Materials Science and Engineering Faculty Research & Creative Works
Electrical steels can be classified into two groups: grain-oriented (GO) and non-oriented (NGO) electrical steel. NGO electrical steels are mainly considered as core materials for different devices, such as electric motors, generators, and rotating machines. The magnetic properties and texture evolution of NGO electrical steels depend on multiple factors (such as chemical content, heat-treatment, and rolling process) making the development of new products a complex task. In this review, studies on the magnetic properties of NGO electrical steels and the corresponding texture evolution are summarized. The results indicate that further research is required for NGO electrical steels to ensure high …
A High-Strength Precipitation Hardened Cobalt-Free High-Entropy Alloy, Matthew Luebbe, Jiaqi Duan, Fan Zhang, Jonathan Poplawsky, Hans Pommeranke, Maalavan Arivu, Andrew Hoffman, Mario F. Buchely, Haiming Wen
A High-Strength Precipitation Hardened Cobalt-Free High-Entropy Alloy, Matthew Luebbe, Jiaqi Duan, Fan Zhang, Jonathan Poplawsky, Hans Pommeranke, Maalavan Arivu, Andrew Hoffman, Mario F. Buchely, Haiming Wen
Materials Science and Engineering Faculty Research & Creative Works
Recent Studies on Precipitation-Hardened High-Entropy Alloys (HEAs) Demonstrate their High Strength and Thermal Stability, Making Them Promising Materials for High-Temperature Structural Applications Such as Nuclear Reactors. However, Many Existing HEAs Contain Cobalt (Co), Which is Unsuitable for Nuclear Applications Because of the Long-Term Activation Issue of Co. Co is Also Expensive and Considered a Critical Material for Other Applications. Therefore, It is Desired to Exclude Co from the Composition. a Co-Free (Fe0.3Ni0.3Mn0.3Cr0.1)88Ti4Al8 HEA Was Developed and Studied in This Work. in Contrast to Previous Co-Free HEAs, This Alloy is …
Anisotropic Thermal Expansion In High-Entropy Multicomponent Alb2-Type Diboride Solid Solutions, Frédéric Monteverde, Mattia Gaboardi, Federico Saraga, Lun Feng, William Fahrenholtz, Gregory Hilmas
Anisotropic Thermal Expansion In High-Entropy Multicomponent Alb2-Type Diboride Solid Solutions, Frédéric Monteverde, Mattia Gaboardi, Federico Saraga, Lun Feng, William Fahrenholtz, Gregory Hilmas
Materials Science and Engineering Faculty Research & Creative Works
High-entropy (HE) ultra-high temperature ceramics have the chance to pave the way for future applications propelling technology advantages in the fields of energy conversion and extreme environmental shielding. Among others, HE diborides stand out owing to their intrinsic anisotropic layered structure and ability to withstand ultra-high temperatures. Herein, we employed in-situ high-resolution synchrotron diffraction over a plethora of multicomponent compositions, with four to seven transition metals, with the intent of understanding the thermal lattice expansion following different composition or synthesis process. As a result, we were able to control the average thermal expansion (TE) from 1.3 x 10−6 to …
Anisotropic Thermal Expansion In High-Entropy Multicomponent Alb2-Type Diboride Solid Solutions, Frédéric Monteverde, Mattia Gaboardi, Federico Saraga, Lun Feng, William Fahrenholtz, Gregory Hilmas
Anisotropic Thermal Expansion In High-Entropy Multicomponent Alb2-Type Diboride Solid Solutions, Frédéric Monteverde, Mattia Gaboardi, Federico Saraga, Lun Feng, William Fahrenholtz, Gregory Hilmas
Materials Science and Engineering Faculty Research & Creative Works
High-entropy (HE) ultra-high temperature ceramics have the chance to pave the way for future applications propelling technology advantages in the fields of energy conversion and extreme environmental shielding. Among others, HE diborides stand out owing to their intrinsic anisotropic layered structure and ability to withstand ultra-high temperatures. Herein, we employed in-situ high-resolution synchrotron diffraction over a plethora of multicomponent compositions, with four to seven transition metals, with the intent of understanding the thermal lattice expansion following different composition or synthesis process. As a result, we were able to control the average thermal expansion (TE) from 1.3 x 10−6 to 6.9 …
Particle Migration In Large Cross-Section Ceramic On-Demand Extrusion Components, Austin J. Martin, Wenbin Li, Jeremy Lee Watts, Gregory E. Hilmas, Ming-Chuan Leu, Tieshu Huang
Particle Migration In Large Cross-Section Ceramic On-Demand Extrusion Components, Austin J. Martin, Wenbin Li, Jeremy Lee Watts, Gregory E. Hilmas, Ming-Chuan Leu, Tieshu Huang
Materials Science and Engineering Faculty Research & Creative Works
Ceramic On-Demand Extrusion (CODE) is a direct ink writing process which allows for the creation of near theoretically dense ceramic components with large cross-sections due to oil-assisted drying. Yttria-stabilized zirconia (YSZ) colloidal pastes (∼d50 ≲ 1 µm) were used in CODE to produce dense (multi-road infill and ≳ 98% relative density), large continuous volume (> 1 cm3), and high fidelity (nozzle diameters ≲ 1 mm) structural ceramic components. However, many of these printed components underwent significant particle migration after forming. The reason for this particle migration defect was investigated using the coffee-ring effect for dilute solutions and rheological methods for …
Particle Migration In Large Cross-Section Ceramic On-Demand Extrusion Components, Austin J. Martin, Wenbin Li, Jeremy Lee Watts, Gregory E. Hilmas, Ming-Chuan Leu, Tieshu Huang
Particle Migration In Large Cross-Section Ceramic On-Demand Extrusion Components, Austin J. Martin, Wenbin Li, Jeremy Lee Watts, Gregory E. Hilmas, Ming-Chuan Leu, Tieshu Huang
Mathematics and Statistics Faculty Research & Creative Works
Ceramic On-Demand Extrusion (CODE) is a direct ink writing process which allows for the creation of near theoretically dense ceramic components with large cross-sections due to oil-assisted drying. Yttria-stabilized zirconia (YSZ) colloidal pastes (∼d50 ≲ 1 µm) were used in CODE to produce dense (multi-road infill and ≳ 98% relative density), large continuous volume (> 1 cm3), and high fidelity (nozzle diameters ≲ 1 mm) structural ceramic components. However, many of these printed components underwent significant particle migration after forming. The reason for this particle migration defect was investigated using the coffee-ring effect for dilute solutions and rheological methods for …
Anisotropic Thermal Expansion In High-Entropy Multicomponent Alb2-Type Diboride Solid Solutions, Frédéric Monteverde, Mattia Gaboardi, Federico Saraga, Lun Feng, William Fahrenholtz, Gregory Hilmas
Anisotropic Thermal Expansion In High-Entropy Multicomponent Alb2-Type Diboride Solid Solutions, Frédéric Monteverde, Mattia Gaboardi, Federico Saraga, Lun Feng, William Fahrenholtz, Gregory Hilmas
Mathematics and Statistics Faculty Research & Creative Works
High-entropy (HE) ultra-high temperature ceramics have the chance to pave the way for future applications propelling technology advantages in the fields of energy conversion and extreme environmental shielding. Among others, HE diborides stand out owing to their intrinsic anisotropic layered structure and ability to withstand ultra-high temperatures. Herein, we employed in-situ high-resolution synchrotron diffraction over a plethora of multicomponent compositions, with four to seven transition metals, with the intent of understanding the thermal lattice expansion following different composition or synthesis process. As a result, we were able to control the average thermal expansion (TE) from 1.3 x 10−6 to 6.9 …
Novel Effects Of Grain Size And Ion Implantation On Grain Boundary Segregation In Ion Irradiated Austenitic Steel, Andrew K. Hoffman, Yongfeng Zhang, Maalavan Arivu, Li He, Kumar Sridharan, Yaqiao Wu, Rinat K. Islamgaliev, Ruslan Z. Valiev, Haiming Wen
Novel Effects Of Grain Size And Ion Implantation On Grain Boundary Segregation In Ion Irradiated Austenitic Steel, Andrew K. Hoffman, Yongfeng Zhang, Maalavan Arivu, Li He, Kumar Sridharan, Yaqiao Wu, Rinat K. Islamgaliev, Ruslan Z. Valiev, Haiming Wen
Materials Science and Engineering Faculty Research & Creative Works
Nuclear Reactor Environments Are Extreme in Nature Due to the Combination of Exposure to Corrosive Coolant, Mechanical Stresses, and Neutron Irradiation Damage. This Combination of Environments Can Lead to Irradiation Induced/assisted Precipitation, Segregation, and Embrittlement Coupled with Enhanced Creep and Stress Corrosion Cracking. While Nanostructured Materials Are of Interest in a Variety of Applications Due to their Unique Properties Including High Mechanical Strength, for Nuclear Applications Nanostructured Materials Have the Added Benefit of Irradiation Resistance Due to the High-Volume Density of Sinks for Irradiation-Induced Defects. in This Study, We Show Unique Radiation-Induced Segregation (RIS) Behavior in Nanocrystalline 304 Stainless Steel …
Particle Migration In Large Cross-Section Ceramic On-Demand Extrusion Components, Austin J. Martin, Wenbin Li, Jeremy Lee Watts, Gregory E. Hilmas, Ming-Chuan Leu, Tieshu Huang
Particle Migration In Large Cross-Section Ceramic On-Demand Extrusion Components, Austin J. Martin, Wenbin Li, Jeremy Lee Watts, Gregory E. Hilmas, Ming-Chuan Leu, Tieshu Huang
Materials Science and Engineering Faculty Research & Creative Works
Ceramic On-Demand Extrusion (CODE) is a direct ink writing process which allows for the creation of near theoretically dense ceramic components with large cross-sections due to oil-assisted drying. Yttria-stabilized zirconia (YSZ) colloidal pastes (∼d50 ≲ 1 µm) were used in CODE to produce dense (multi-road infill and ≳ 98% relative density), large continuous volume (> 1 cm3), and high fidelity (nozzle diameters ≲ 1 mm) structural ceramic components. However, many of these printed components underwent significant particle migration after forming. The reason for this particle migration defect was investigated using the coffee-ring effect for dilute solutions and rheological methods for …
Synthesizing Ti–Ni Alloy Composite Coating On Ti–6al–4v Surface From Laser Surface Modification, Yitao Chen, Joseph William Newkirk, Frank W. Liou
Synthesizing Ti–Ni Alloy Composite Coating On Ti–6al–4v Surface From Laser Surface Modification, Yitao Chen, Joseph William Newkirk, Frank W. Liou
Materials Science and Engineering Faculty Research & Creative Works
In This Work, a Ni-Alloy Deloro-22 Was Laser-Deposited on a Ti–6Al–4V Bar Substrate with Multiple Sets of Laser Processing Parameters. the Purpose Was to Apply Laser Surface Modification to Synthesize Different Combinations of Ductile TiNi and Hard Ti2Ni Intermetallic Phases on the Surface of Ti–6Al–4V in Order to Obtain Adjustable Surface Properties. Scanning Electron Microscopy, Energy Dispersion Spectroscopy, and X-Ray Diffraction Were Applied to Reveal the Deposited Surface Microstructure and Phase. the Effect of Processing Parameters on the Resultant Compositions of TiNi and Ti2Ni Was Discussed. the Hardness of the Deposition Was Evaluated, and Comparisons with …
Effect Of Class C And Class F Fly Ash On Early-Age And Mature-Age Properties Of Calcium Sulfoaluminate Cement Paste, Sukanta K. Mondal, Carrie Clinton, Hongyan Ma, Aditya Kumar, Monday Uchenna Okoronkwo
Effect Of Class C And Class F Fly Ash On Early-Age And Mature-Age Properties Of Calcium Sulfoaluminate Cement Paste, Sukanta K. Mondal, Carrie Clinton, Hongyan Ma, Aditya Kumar, Monday Uchenna Okoronkwo
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
To Promote the Sustainable Development of Eco-Efficient Calcium Sulfoaluminate (CSA) Cements through the Partial Replacement of the CSA Clinker with Supplementary Cementitious Waste Products, the Effects of Coal Fly Ashes on the Early-Age and Mature-Age Properties of a Calcium Sulfoaluminate (CSA)-Based Cement Paste Were Investigated. the Impacts of Both Class C and Class F Fly Ashes on the Rheological Properties, Hydration Kinetics, and Compressive Strength Development of CSA Cement Paste Were Studied. Rheology-Based Workability Parameters, Representing the Rate of Loss of Flowability, the Rate of Hardening, and the Placement Limit, Were Characterized for the Pastes Prepared with Fixed Water-To-Cement (W/c) …
Network Structures And The Properties Of Na-Ca-Sr-Borophosphate Glasses, Parker T. Freudenberger, Rebekah L. Blatt, Randall E. Youngman, Richard K. Brow
Network Structures And The Properties Of Na-Ca-Sr-Borophosphate Glasses, Parker T. Freudenberger, Rebekah L. Blatt, Randall E. Youngman, Richard K. Brow
Materials Science and Engineering Faculty Research & Creative Works
Borophosphate glasses were prepared with the nominal molar compositions 16Na2O-(24-y)CaO-ySrO-xB2O3-(60-x)P2O5 (mol%), where 0≤x≤60 and y=0, 12, and 24. Information about the compositional dependence of borate and phosphate site speciation and next nearest neighbor linkages was obtained by 11B and 31P MAS NMR and Raman spectroscopies, and by high pressure liquid chromatography (HPLC). With the initial replacement of P2O5 by B2O3, tetrahedral borate sites linked to four phosphate anions, B(ØP)4, are created in the glass structure, and the average phosphate anion …
Network Structures And The Properties Of Na-Ca-Sr-Borophosphate Glasses, Parker T. Freudenberger, Rebekah L. Blatt, Randall E. Youngman, Richard K. Brow
Network Structures And The Properties Of Na-Ca-Sr-Borophosphate Glasses, Parker T. Freudenberger, Rebekah L. Blatt, Randall E. Youngman, Richard K. Brow
Mathematics and Statistics Faculty Research & Creative Works
Borophosphate glasses were prepared with the nominal molar compositions 16Na2O-(24-y)CaO-ySrO-xB2O3-(60-x)P2O5 (mol%), where 0≤x≤60 and y=0, 12, and 24. Information about the compositional dependence of borate and phosphate site speciation and next nearest neighbor linkages was obtained by 11B and 31P MAS NMR and Raman spectroscopies, and by high pressure liquid chromatography (HPLC). With the initial replacement of P2O5 by B2O3, tetrahedral borate sites linked to four phosphate anions, B(ØP)4, are created in the glass structure, and the average phosphate anion becomes smaller as bridging PØP bonds are replaced by bridging PØB bonds. With further increases in the B2O3 content, borate …
The Effects Of Phosphorus Pentoxide Additions On The Thermal, Rheological, And Structural Properties Of Sodium Borosilicate Glass, K. L. Skerratt-Love, J. L. George, A. M.T. Bell, F. Sweeney, D. Cutforth, C. (Charmayne) E. Lonergan, D. R. Dixon, A. A. Kruger, P. A. Bingham
The Effects Of Phosphorus Pentoxide Additions On The Thermal, Rheological, And Structural Properties Of Sodium Borosilicate Glass, K. L. Skerratt-Love, J. L. George, A. M.T. Bell, F. Sweeney, D. Cutforth, C. (Charmayne) E. Lonergan, D. R. Dixon, A. A. Kruger, P. A. Bingham
Materials Science and Engineering Faculty Research & Creative Works
This research has characterized the effects of P2O5 additions on the physical, chemical, thermal, rheological properties and the structure of SiO2-B2O3-Na2O glasses relevant to radioactive waste immobilization. Properties analyzed include high-temperature viscosity, glass transition temperature (Tg) and structure. X-ray diffraction (XRD) confirmed a solubility limit of between 3.0 and 4.0 mol% P2O5 for the onset of crystallinity with formation of Na3PO4 and Na4P2O7 in annealed bulk glasses; and between 4.0 and 5.0 mol% P2O …
Network Structures And The Properties Of Na-Ca-Sr-Borophosphate Glasses, Parker T. Freudenberger, Rebekah L. Blatt, Randall E. Youngman, Richard K. Brow
Network Structures And The Properties Of Na-Ca-Sr-Borophosphate Glasses, Parker T. Freudenberger, Rebekah L. Blatt, Randall E. Youngman, Richard K. Brow
Materials Science and Engineering Faculty Research & Creative Works
Borophosphate glasses were prepared with the nominal molar compositions 16Na2O-(24-y)CaO-ySrO-xB2O3-(60-x)P2O5 (mol%), where 0≤x≤60 and y=0, 12, and 24. Information about the compositional dependence of borate and phosphate site speciation and next nearest neighbor linkages was obtained by 11B and 31P MAS NMR and Raman spectroscopies, and by high pressure liquid chromatography (HPLC). With the initial replacement of P2O5 by B2O3, tetrahedral borate sites linked to four phosphate anions, B(ØP)4, are created in the glass structure, and the average phosphate anion becomes smaller as bridging PØP bonds are replaced by bridging PØB bonds. With further increases in the B2O3 content, borate …
Microstructure Evolution And Austenitic Grain Refinement Of Ti-Modified High Mn Steels During Solution Annealing Heat Treatment, Abhinav Karanam, Arnab Sarkar, Erik Nenzen, Viraj Ashok Athavale, Mark Watson, Laura Nicole Bartlett, Lukas Bichler
Microstructure Evolution And Austenitic Grain Refinement Of Ti-Modified High Mn Steels During Solution Annealing Heat Treatment, Abhinav Karanam, Arnab Sarkar, Erik Nenzen, Viraj Ashok Athavale, Mark Watson, Laura Nicole Bartlett, Lukas Bichler
Materials Science and Engineering Faculty Research & Creative Works
Austenitic high manganese (Mn) steels are often used in harsh environments due to their high toughness and wear resistance. Heat treatments are performed to engineer the microstructure of the steels and optimize their performance for the desired service conditions. This study investigated the effect of titanium (Ti) and heat treatment on the microstructure of cast high Mn steel (HMS) alloys. The results reveal that Ti addition contributed to grain refinement in the as cast and heat-treated conditions. In-situ observation of microstructure evolution up to 1125 °C confirmed the stability of precipitated TiC particles, while revealing a new mechanism of grain …