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Articles 1 - 16 of 16
Full-Text Articles in Engineering
Size-Induced Lattice Relaxation In Ceo₂ Nanoparticles, X.-D. Zhou, Wayne Huebner
Size-Induced Lattice Relaxation In Ceo₂ Nanoparticles, X.-D. Zhou, Wayne Huebner
Materials Science and Engineering Faculty Research & Creative Works
Size-induced lattice relaxation was observed for nanoscale CeO2 single crystals with an average size from 4 to 60 nm. Results showed the finest crystallites exhibited no strain-induced line broadening, while high temperature annealing resulted in larger grain sizes and significant strains. The observed shift in the x-ray diffraction lattice parameters was assumed to be due to the formation of defects on the lattice, specifically oxygen vacancies. Modeling revealed that the oxygen vacancy concentration ([V••O]) was found to be ≈4 x 1020/cm3 for the 4 nm crystallites, and decreased two orders of magnitude for …
Ultrasonic Characterization Of Poling In Lead Zirconate Titanate Ceramics, James R. Friend, Eric Jamieson, Marvin Pennell, Wayne Huebner
Ultrasonic Characterization Of Poling In Lead Zirconate Titanate Ceramics, James R. Friend, Eric Jamieson, Marvin Pennell, Wayne Huebner
Materials Science and Engineering Faculty Research & Creative Works
A method for measuring the spatial variation of the macroscopic poling state of a piezoelectric material using an ultrasonic transducer is described. The relatively simple method clearly indicates the distribution of poling within the material, demonstrated by the testing of a collection of partially poled lead zirconate titanate samples.
Highly Plasma Etch-Resistant Photoresist Composition Containing A Photosensitive Polymeric Titania Precursor, Tony D. Flaim, Douglas J. Guerrero, Michelle R. Fowler, William Joseph James, Vladimir Petrovsky, Harlan U. Anderson
Highly Plasma Etch-Resistant Photoresist Composition Containing A Photosensitive Polymeric Titania Precursor, Tony D. Flaim, Douglas J. Guerrero, Michelle R. Fowler, William Joseph James, Vladimir Petrovsky, Harlan U. Anderson
Chemistry Faculty Research & Creative Works
A composition is derived from an addition polymerizable organotitanium polymer which upon exposure to an oxygen plasma or baking in air, is converted to titanium dioxide (titania) or is converted to a mixed, titanium-containing metal oxide. The metal oxide formed in situ imparts etch- resistant action to a patterned photoresist layer. The composition may also be directly deposited and patterned into permanent metal oxide device features by a photolithographic process.
Ni-Induced Local Distortions In La₁.₈₅Sr₀.₁₅Cu1-YNiYO₄ And Their Relevance To Tc Suppression, Daniel Haskel, Edward A. Stern, Victor Polinger, Fatih Dogan
Ni-Induced Local Distortions In La₁.₈₅Sr₀.₁₅Cu1-YNiYO₄ And Their Relevance To Tc Suppression, Daniel Haskel, Edward A. Stern, Victor Polinger, Fatih Dogan
Materials Science and Engineering Faculty Research & Creative Works
We present results from angular-resolved x-ray-absorption fine-structure (XAFS) measurements at the Ni, La, and Sr K edges of oriented powders of La1.85Sr0.15Cu1-yNiyO4, with y=0.01, 0.03, 0.06. A special magnetic alignment procedure allowed us to measure pure ĉ- and ab-oriented XAFS at the Ni K edge in identical fluorescence geometries. Both the x-ray-absorption near-edge structure and the XAFS unequivocally show that the NiO6 octahedra are contracted along the c axis by ≈0.32Å relative to CuO6 octahedra while the in-plane distances of NiO6 and CuO6 octahedra are the same within 0.01Å. The NiO6 octahedral contraction drives the average ĉ axis contraction measured …
Observation Of Magnetic Moments In The Superconducting State Of Yba₂Cu₃O₆.₆, Herbert A. Mook, Pengcheng Dai, Fatih Dogan
Observation Of Magnetic Moments In The Superconducting State Of Yba₂Cu₃O₆.₆, Herbert A. Mook, Pengcheng Dai, Fatih Dogan
Materials Science and Engineering Faculty Research & Creative Works
Neutron scattering measurements for YBa2Cu3O6.6 have identified small magnetic moments that increase in strength as the temperature is reduced below T* and further increase below Tc. An analysis of the data shows the moments are antiferromagnetic between the Cu-O planes with a correlation length of longer than 195 Å in the a-b plane and about 35 Å along the c axis. The origin of the moments is unknown, and their properties are discusssed both in terms of Cu spin magnetism and orbital bond currents.
Dopant Structural Distortions In High-Temperature Superconductors: An Active Or A Passive Role?, Daniel Haskel, Edward A. Stern, Fatih Dogan, Arnie R. Moodenbaugh
Dopant Structural Distortions In High-Temperature Superconductors: An Active Or A Passive Role?, Daniel Haskel, Edward A. Stern, Fatih Dogan, Arnie R. Moodenbaugh
Materials Science and Engineering Faculty Research & Creative Works
The parent compounds of high-temperature superconductors, such as YBa2Cu3O6 and La2CuO4, are strongly interacting electron systems, rendering them insulators with Mott-Hubbard gaps of a few electronvolts. Charge carriers (holes) are introduced by chemical doping, causing an insulator-metal (IM) transition and, at low temperatures, superconductivity. the role of dopants is widely seen as limited to the introduction of holes into the CuO2 planes (i.e. occupying electronic states derived from Cu and O 2px,y atomic orbitals). Most theories of high-Tc superconductivity deal with pairing interactions between these planar holes. Local distortions around dopants are poorly understood, because of the experimental difficulty in …
Network Formalism For Modeling Functionally Gradient Piezoelectric Plates And Stacks And Simulations Of Rainbow Ceramic Actuators, Robert W. Schwartz, A. Ballato, John Ballato
Network Formalism For Modeling Functionally Gradient Piezoelectric Plates And Stacks And Simulations Of Rainbow Ceramic Actuators, Robert W. Schwartz, A. Ballato, John Ballato
Mechanical and Aerospace Engineering Faculty Research & Creative Works
A simple network representation is given for a stack of thin, homogeneous piezoelectric plates, executing a single thickness mode of motion. All plates may differ in thickness and material properties, including dielectric loss, ohmic conductivity, and viscous loss. Each plate is driven by a thickness-directed electric field, and all stack elements are connected electrically in series. Functionally gradient single plates and composites are readily modeled by the network, to a desired precision, using a sequence of circuit elements representing stepwise variations in material properties and layer thicknesses. Simulations of RAINBOW (reduced and internally biased oxide wafer) ceramics are given.
Agglomerated Die Casting Lubricant, Mary R. Reidmeyer
Agglomerated Die Casting Lubricant, Mary R. Reidmeyer
Materials Science and Engineering Faculty Research & Creative Works
A lubricant for use in lubricating the shot sleeve of a machine for die casting molten metals is in the form of agglomerated particles. The particles have an inorganic high pressure lubricant agglomerated, with a binder material and with an organic material. The solid lubricant is resistant to dusting, caking and breakage, can be fed through an automatic dispensing machine, and combines inorganic and organic materials to achieve excellent lubrication properties. The product has low flash and low smoke release into the environment.
Chemical Plating Method, Electrolytic Cell And Automotive Oxygen Sensor Using It, Mary R. Reidmeyer, Matthew J. Donelon, Robert F. Killion
Chemical Plating Method, Electrolytic Cell And Automotive Oxygen Sensor Using It, Mary R. Reidmeyer, Matthew J. Donelon, Robert F. Killion
Materials Science and Engineering Faculty Research & Creative Works
An automotive lambda oxygen sensor is formed by electroless plating of a thin, catalytically active, conductive electrode uniformly on the outer surface of a zirconia thimble. The process includes forming a pristine zirconia solid electrolyte thimble and drilling out a cylindrical cavity in it. A porous outer surface suitable for producing crystallization sites is formed by dipping the unfired thimble in a zirconia slurry containing spray-dried microspheres and firing the coated thimble to densify the thimble and the microspheres and to produce cavities on the surface of the thimble. An inner platinum electrode is formed by conventional conductive ink painting …
Dynamics Of Poly(Vinyl Acetate)-D₃ On Silica, Robert D. O'Connor, Frank D. Blum, Gu Xu
Dynamics Of Poly(Vinyl Acetate)-D₃ On Silica, Robert D. O'Connor, Frank D. Blum, Gu Xu
Mechanical and Aerospace Engineering Faculty Research & Creative Works
Poly(vinyl acetate) (PVAc) is an important polymer in applications because of both its bulk and surface characteristics. Its chain architecture gives it a low Tg and, generally, good qualities for processing and applications, which include paints, adhesives, thin films and surface coatings. In this study, we investigate the surface dynamics of PVAc absorbed onto silica with deuterium nuclear magnetic resonance (2H NMR). For dynamics studies, 2H NMR is an excellent technique because it uses an innocuous probe that can report on correlation times (τc) from approximately 10-8 s to 10 s. We report the use of two-dimensional exchange NMR (2D-X) …
Evolution Of The Resonance And Incommensurate Spin Fluctuations In Superconducting Yba₂Cu₃O₆₊ₓ, Pengcheng Dai, Herbert A. Mook, Rodney Dale Hunt, Fatih Dogan
Evolution Of The Resonance And Incommensurate Spin Fluctuations In Superconducting Yba₂Cu₃O₆₊ₓ, Pengcheng Dai, Herbert A. Mook, Rodney Dale Hunt, Fatih Dogan
Materials Science and Engineering Faculty Research & Creative Works
Polarized and unpolarized neutron triple-axis spectrometry was used to study the dynamical magnetic susceptibility Χ″(q, ω) as a function of energy (ℏ ω) and wave vector (q) in a wide temperature range for the bilayer superconductor YBa2Cu3O6+x with oxygen concentrations, x, of 0.45, 0.5, 0.6, 0.7, 0.8, 0.93, and 0.95. The most prominent features in the magnetic spectra include a spin gap in the superconducting state, a pseudogap in the normal state, the much-discussed resonance, and incommensurate spin fluctuations below the resonance. We establish the doping dependence of the spin gap in the superconducting state, …
Dynamics Of Polyacrylates In Concentrated Chloroform Solutions, Frank D. Blum, Raj B. Durairaj
Dynamics Of Polyacrylates In Concentrated Chloroform Solutions, Frank D. Blum, Raj B. Durairaj
Chemistry Faculty Research & Creative Works
The dynamics of polymers in polymer solutions have not been probed in great enough detail to provide a coherent picture of the behavior of these polymers, especially in more concentrated solutions. To help understand this behavior further, we have prepared a series of backbone-labeled polymers including poly(n-butyl acrylate)-d1 (PNBA). These provide a basis for comparison of the behavior among a group of related polymers. The dynamics have been probed by using deuterium relaxation times. Since the relaxation times are relatively fast and the quadrupolar relaxation mechanism is well understood, data from this technique provide a convenient means for comparison of …
Development Of Transparent Lsco And Lscno Conductors For Optical Shutter Systems, Robert W. Schwartz, M. T. Sebastian, M. Charoenwongsa, H. D. Dobberstein
Development Of Transparent Lsco And Lscno Conductors For Optical Shutter Systems, Robert W. Schwartz, M. T. Sebastian, M. Charoenwongsa, H. D. Dobberstein
Mechanical and Aerospace Engineering Faculty Research & Creative Works
We have prepared lanthanum strontium cobalt oxide (La0.50Sr0.50CoO3; LSCO 50/50) and lanthanum strontium cobalt nickel oxide (La0.50Sr0.50Co0.50Ni0.50O3; LSCNO) as candidate transparent electrodes for use in a shutter-based infrared sensor protection device. The shutter device requires that the electrode be transparent (80% transmission) and have moderate sheet resistance (300 Ω/sq.). Because of the effects of film thickness on intrinsic material properties, such as resistivity and extinction coefficient, and simple engineering issues (i.e., the relationship between film thickness, resistance and transmission), films of various thicknesses were prepared to achieve an optimal balance of electrical and optical performance. van der Pauw measurements and …
Glass Transition Behavior Of Pmma Thin Films, Moses T. Kabomo, Frank D. Blum
Glass Transition Behavior Of Pmma Thin Films, Moses T. Kabomo, Frank D. Blum
Chemistry Faculty Research & Creative Works
In the last decade there has been an increased interest in the study of the properties of supported thin polymer films. This has been prompted by the incorporation of thin films into device applications and many other technologies. Although not without controversy, a large body of experimental work indicates departures from bulk behavior by thin films. Strong evidence from both theoretical and experimental work shows that the interaction of polymer with a substrate alters the polymer conformation and mobility. A variety of techniques has been employed to probe the mobility of thin supported polymer films. Some of these techniques indirectly …
Graduated Segmental Mobility In Polymer Layers On Silica, Frank D. Blum, Crystal E. Porter, Wuu-Yung Lin
Graduated Segmental Mobility In Polymer Layers On Silica, Frank D. Blum, Crystal E. Porter, Wuu-Yung Lin
Chemistry Faculty Research & Creative Works
The behavior of thin polymer layers on oxide substrates has gotten a great deal of attention as the size of materials, and hence polymer films, has gotten smaller. Indeed, the properties of adsorbed polymers are such that they can be different from those of bulk polymers, especially when the films are very thin. A wide variety of studies have been made on adsorbed polymers and sometimes the results seem contradictory. One of the properties often measured in thin films is the apparent glasstransition temperature, Tg. In principle, many techniques are sensitive to phenomenological changes occurring around Tg and, therefore, can …
Thermal Analysis Of Ultrathin Ps-R-Pmma Copolymer Films On Silica, Bing Zhang, Frank D. Blum
Thermal Analysis Of Ultrathin Ps-R-Pmma Copolymer Films On Silica, Bing Zhang, Frank D. Blum
Chemistry Faculty Research & Creative Works
Composite materials represent a major part of man-made materials that are used in many applications. The interaction of polymers with surfaces plays a crucial role in the final properties of these materials and, by understanding the surface processes and adsorption mechanisms, better systems can be designed. Therefore, the behavior of polymer molecules at interfaces has been the topic of many studies in recent years and a rough picture has been obtained. Keddie et al. Obtained experimental results showing the dependence of the glass transition temperature (Tg) on the thickness of supported polystyrene films using ellipsometry. Later, they also investigated supported …