Engineering Commons^™

Structural, Optical And Electrical Properties Of Yttrium-Doped Hafnium Oxide Nanocrystalline Thin Films, Abhilash Kongu

Open Access Theses & Dissertations

Hafnium oxide (HfO2) has emerged as the most promising high-k dielectric for Metal-Oxide-Semiconductor (MOS) devices and has been highlighted as the most suitable dielectric materials to replace silicon oxide because of its comprehensive performance. In the present research, yttrium-doped HfO2 (YDH) thin films were fabricated using RF magnetron sputter deposition onto Si (100) and quartz with a variable thickness. Cross-sectional scanning electron microscopy coupled with Filmetrics revealed that film thickness values range from 700 A° to 7500 A°. Electrical properties such as AC Resistivity and current-voltage (I-V) characteristics of YDH films were studied. YDH films that were relatively thin (<1500 A°) crystallized in monoclinic phase while thicker films crystallized in cubic phase. The band gap (Eg) of the films was calculated from the optical measurements. The band gap was found to be ∼5.60 eV for monoclinic while it is ∼6.05 eV for cubic phase of YDH films. Frequency dependence of the electrical resistivity (ρac) and the total conductivity of the films were measured. Resistivity decreased (by three orders of magnitude) with increasing frequency from 100 Hz to 1 MHz, attributed due to the hopping mechanism in YDH films. Whereas, while ρac∼1Ω-m at low frequencies (100 Hz), it decreased to ∼ 104 Ω-cm at higher frequencies (1 MHz). Aluminum (Al) metal electrodes were deposited to fabricate a thin film capacitor with YDH layer as dielectric film thereby employing Al-YDH-Si capacitor structure. The results indicate that the capacitance of the films decrease with increasing film thickness. A detailed analysis of the electrical characteristics of YDH films is presented.

Photovoltaic Device, Jinsong Huang, Bin Yang, Yongbo Yuan

Department of Mechanical and Materials Engineering: Faculty Publications

An apparatus includes a substrate; and a photoactive layer disposed on the substrate. The photoactive layer includes an electron acceptor material; an electron donor material; and a material having dipoles.

Analysis Of Electrically-Forced Vibrations Of Piezoelectric Mesa Resonators, Huijing He, Guo-Quan Nie, Jin-Xi Liu, Jiashi Yang

Department of Mechanical and Materials Engineering: Faculty Publications

We study the electrically forced thickness-shear and thickness-twist vibrations of stepped thickness piezoelectric plate mesa resonators made of polarized ceramics or 6-mm class crystals. A theoretical analysis based on the theory of piezoelectricity is performed, and an analytical solution is obtained using the trigonometric series. The electrical admittance, resonant frequencies, and mode shapes are calculated, and strong energy trapping of the modes is observed. Their dependence on the geometric parameters of the resonator is also examined.

Effects Of Mode Coupling On The Admittance Of An At-Cut Quartz Thickness-Shear Resonator, Huijing He, Jiashi Yang, Wei-Ping Zhang, Ji Wang

Department of Mechanical and Materials Engineering: Faculty Publications

We study the effects of couplings to flexure and face-shear modes on the admittance of an AT-cut quartz plate thickness-shear mode resonator. Mindlin’s two-dimensional equations for piezoelectric plates are employed. Electrically forced vibration solutions are obtained for three cases: pure thickness-shear mode alone; two coupled modes of thickness shear and flexure; and three coupled modes of thickness shear, flexure, and face shear. Admittance is calculated and its dependence on the driving frequency and the length/thickness ratio of the resonator is examined. Results show that near the thickness-shear resonance, admittance assumes maxima, and that for certain values of the length/thickness ratio, …

Review Of Electrochemical And Electrodischarge Machining, Kamlakar P. Rajurkar, M. M. Sundaram, A. P. Malshe

Department of Mechanical and Materials Engineering: Faculty Publications

Electrochemical and electro-discharge machining processes are the two major electro-machining processes with unique capabilities. Electrical Discharge Machining (EDM) and Electrochemical Machining (ECM) offer a better alternative or sometimes the only alternative in generating accurate 3-D complex shaped macro, micro and nano features and components of difficult–to-machine materials. Technological advances reported in electrochemical and electro discharge machining processes, which reflect the state of the art in academic and industrial research and applications, are briefly reviewed in this paper.

A Comparative Study Of The Dry And Wet Nano-Scale Electro-Machining, M. P. Jahan, K. R. Virwani, Kamlakar P. Rajurkar, A. P. Malshe

Department of Mechanical and Materials Engineering: Faculty Publications

In recent years, a nano-electromachining (nano-EM) process based on a scanning tunneling microscope (STM) platform has been demonstrated. Nano-EM is capable of machining nano-features, under both, liquid dielectric (wet nano-EM) and air dielectric (dry nano-EM) media. The objective of this paper is to present a comparative study between the wet and dry nano-EM processes based on process mechanism, machining performance, consistency and dimensional repeatability of these two processes. The comparison of the two processes has been conducted at near field nano-EM, where the gap between the tool electrode and workpiece is 2 nm and the machining is performed at room …

Wire Electro-Discharge Machining Of Titanium Alloy, Farnaz Nourbakhsh, Kamlakar P. Rajurkar, Ajay P. Malshe, Jian Cao

Department of Mechanical and Materials Engineering: Faculty Publications

This paper presents an experimental investigation of wire electro-discharge machining (WEDM) of titanium alloy. The objective is to investigate the effect of seven process parameters including pulse width, servo reference voltage, pulse current, and wire tension on process performance parameters (such as cutting speed, wire rupture and surface integrity). A Taguchi L18 design of experiment (DOE) has been applied. All experiments have been conducted using Charmilles WEDM. It was also found that the cutting speed increases with peak current and pulse interval. Surface roughness was found to increase with pulse width and decrease with pulse interval. The Analysis of Variance …

Selective Detection And Automated Counting Of Fluorescently-Labeled Chrysotile Asbestos Using A Dual-Mode High-Throughput Microscopy (Dm-Htm) Method, Myoung-Ock Cho, Hyo Mi Chang, Donghee Lee, Yeon Gyu Yu, Hwataik Han, Jung Kyung Kim

Department of Mechanical and Materials Engineering: Faculty Publications

Phase contrast microscopy (PCM) is a widely used analytical method for airborne asbestos, but it is unable to distinguish asbestos from non-asbestos fibers and requires time-consuming and laborious manual counting of fibers. Previously, we developed a high-throughput microscopy (HTM) method that could greatly reduce human intervention and analysis time through automated image acquisition and counting of fibers. In this study, we designed a dual-mode HTM (DM-HTM) device for the combined reflection and fluorescence imaging of asbestos, and automated a series of built-in image processing commands of ImageJ software to test its capabilities. We used DksA, a chrysotile-adhesive protein, for selective …

Inducing Neurite Outgrowth By Mechanical Cell Stretch, Suzanne Higgins, Jeong Soon Lee, Ligyeom Ha, Jung Yul Lim

Department of Mechanical and Materials Engineering: Faculty Publications

Establishing extracellular milieus to stimulate neuronal regeneration is a critical need in neuronal tissue engineering. Many studies have used a soluble factor (such as nerve growth factor or retinoic acid [RA]), micropatterned substrate, and electrical stimulation to induce enhanced neurogenesis in neuronal precursor cells. However, little attention has been paid to mechanical stimulation because neuronal cells are not generally recognized as being mechanically functional, a characteristic of mechanoresponsive cells such as osteoblasts, chondrocytes, and muscle cells. In this study, we performed proof-of-concept experiments to demonstrate the potential anabolic effects of mechanical stretch to enhance cellular neurogenesis. We cultured human neuroblastoma …

Reducing Metal Alloy Powder Costs For Use In Powder Bed Fusion Additive Manufacturing: Improving The Economics For Production, Fransisco Medina

Open Access Theses & Dissertations

Titanium and its associated alloys have been used in industry for over 50 years and have become more popular in the recent decades. Titanium has been most successful in areas where the high strength to weight ratio provides an advantage over aluminum and steels. Other advantages of titanium include biocompatibility and corrosion resistance. Electron Beam Melting (EBM) is an additive manufacturing (AM) technology that has been successfully applied in the manufacturing of titanium components for the aerospace and medical industry with equivalent or better mechanical properties as parts fabricated via more traditional casting and machining methods. As the demand for …

Process Study And Control Of Electron Beam Melting Technology Using Infrared Thermography, Jorge Mireles

Open Access Theses & Dissertations

An IR camera was installed in an Arcam A2 system (Arcam AB, Mölndal, Sweeden) and layer-by-layer image acquisition was achieved. The camera's capability to detect manufacturing defects was evaluated by implementing computer vision techniques using LabVIEW measurement and programming software (National Instruments, Austin, TX). Thermal maps acquired by the IR camera allowed layer-by-layer part temperature to be recorded. A core objective of this research was to study the impact of processing temperature on EBM-fabricated Ti-6Al-4V parts and achieve controlled mechanical properties. In this research, build variations were achieved by modifying parameters that change processing temperature from the standard processing temperature. …

Crystal Structure, Phase, And Optical Properties Of Yttrium-Doped Hafnium Oxide Nanocrystalline Thin Films, Alejandro Ortega

Open Access Theses & Dissertations

Yttrium-doped hafnium oxide (YDH) nanocrystalline films were produced by sputter-deposition at various substrate times and temperatures, to produce YDH films in a wide range of thicknesses, dYDH∼25 to 1100 nm. The deposition was made onto optical grade quartz and sapphire substrates. Samples deposited on sapphire were subject to post-deposition annealing (PDA) at various times (3-24 hr) and temperatures (1100 - 1500 °C). The effect of d[special characters omitted]YDH on the crystal structure, surface/interface morphology and optical properties of YDH films was investigated. X-ray diffraction analyses revealed the formation of monoclinic phase for relatively thin films (<150nm). The evolution towards stabilized cubic phase with increasing dYDH [special characters omitted]is observed. The scanning electron microscopy results indicate the dense, columnar structure of YDH films as a function of dYDH. Spectrophotometry analyses indicate that the grown YDH films are transparent and exhibit interference fringes. The band gap was found to be ∼ 5.60 eV for monoclinic YDH films while distinct separation and an increase in band gap to 6.03 eV is evident with increasing dYDH and formation cubic YDH films. The PDA films band gaps were found to be between 5.31 and 5.72 eV, all of which exhibit secondary gaps. A correlation between growth conditions, annealing, phase evolution, and optical properties of the YDH nanocrystalline thin films is established.

Comparative Characterization Of Ni-Base Superalloys Fabricated By Laser And Electron Beam Melting Technologies, Krista Amato

Open Access Theses & Dissertations

Nickel-base superalloys have been used in cast and wrought, and powder metallurgy forms for nearly four decades for industrial and automotive applications. One drawback of cast alloys is that upon solidification, there is minimal microstructural control. Another issue to be improved is to eliminate the limitations of shapes and forms of fabricated alloys.

Rapid prototyping is a new technology of additive manufacturing that shows to be promising for the freeform fabrication of novel superalloys, including nickel-base alloys. New rapid manufacturing technologies allow us to produce parts in any shape that can be designed by computer-aided design (CAD) software. Additionally, the …

New Topics On Nanoindentation Of Polymers And Composite Materials, Ricardo Martinez-Hernandez

Open Access Theses & Dissertations

In this study, nanoindentation was used to determine Young's modulus of homogeneous plastic materials as well as inhomogeneous epoxy woven fabric composites using various indenters. In the first part, homogeneous PMMA and polycarbonate were characterized using conical and spherical indenters. The conventional approach of the inverse analysis was modified in order to account for effects obtained during spherical nanoindentation. The experimental results were verified using FEA analysis in ABAQUS. It was found that viscous effects were present in conical nanoindentations which led to an overestimation of contact stiffness. The second part, the response of carbon and glass fiber woven fabric …