Engineering Commons^™

Micro-Mechanical Analysis Of Corrosion Products Formed During Long-Term Carbonation Induced Corrosion Of Steel, Marijana Serdar, Dubravka Bjegovic, Valérie L’Hostis, Stéphane Poyet, Damien Féron

International Conference on Durability of Concrete Structures

During corrosion distinct types of corrosion products form, composed of different ratios of ferrous ions and oxide, hydroxides. Corrosion products have different physical and mechanical properties, mainly density, resistivity, volume and modulus of elasticity compared to iron. Knowing properties of corrosion products is indispensable for service life modelling of structures and can give valuable insight into the long-term corrosion propagation process. In this study micro-indentation method was used to evaluate mechanical properties of different layers formed during long-term carbonation induced corrosion of steel in concrete. Investigation was performed on three sets of reinforced concrete samples, that underwent corrosion during 50, …

Comparison Data Between Hybrid And Galvanic Anode Installation In The Arousa Island Bridge, José Antonio Becerra Mosquera, Diego Carro López, José Enrique Pardo Landrove, José Manuel Millán Pérez

International Conference on Durability of Concrete Structures

The Arousa Island Bridge, with its 1980 m is the only road access to the Arousa Island. Built in 1985, this single-cell box girder divided in 40 spans runs entirely on the sea. The deck is between 2 to 12 m above sea level, so after 25 years in a marine environment, the structure showed reinforcement corrosion, especially in piles and deck bottom. Attending to the corrosion damages, caused simply from a chloride attack, the local government decided to intervene with an ambitious repair project. This decision has been taken only after an exhaustive cost analysis to determine the feasibility …

Effect Of Time-Dependent Chloride Profile And Temperature Variation On Chloride Diffusion In Concrete, Feras Alsheet, A. Ghani Razaqpur

International Conference on Durability of Concrete Structures

Reinforcement corrosion due to chlorides diffusion is one of the main problems in reinforced concrete structures exposed to certain environments. The diffusion rate is function of chloride surface concentration, concrete temperature, humidity, composition and microstructure. The intruded chlorides are partially chemically bound by the concrete and it is the unbound or free chloride which upon exceeding a defined threshold initiates corrosion. The time to corrosion initiation depends on the above variables; therefore, it is important to model their spatial and temporal variations in a manner that will yield a realistic estimate of the actual initiation period. In this study, the …

Durability Design Of Segmental Linings For Intended Service Life Of Tunnels, Mehdi Bakhshi, Verya Nasri

International Conference on Durability of Concrete Structures

In one-pass lining systems, the durability of tunnel structure is directly related to durability of concrete segments acting as both the initial support and the tunnel final lining. In this paper, most-frequent degradation mechanisms of concrete linings are discussed including chloride- and carbonation- induced corrosions, sulfate, acid and freeze-and-thaw attacks, and alkali-aggregate reactions. Mitigation method for each specific degradation mechanism is explained. A durability factor specific to railway and subway tunnel known as stray current corrosion is presented. Mitigation methods for this specific corrosion together with coupling effects with other conventional damage mechanisms are explained. Prescriptive approaches for durability design …

Sustainable Concrete With Seawater And Corrosion Resistant Reinforcement: Results Of Monitoring Of Corrosion Behaviour, Elena Redaelli, Maddalena Carsana, Federica Lollini, Matteo Gastaldi, Forood Torabian Isfahani

International Conference on Durability of Concrete Structures

The use of seawater for mixing concrete for reinforced concrete structures is prohibited, since it can promote steel corrosion. However, the use of seawater would contribute to decrease the environmental impact of concrete, in particular in those regions of the world where potable water is a precious resource. The project SEACON-INFRAVATION between University of Miami and Politecnico di Milano, with various industrial partners, aims at investigating the use of seawater for the construction of sustainable and durable reinforced concrete structures and infrastructures. Within the project, that included a vast campaign of laboratory tests, also two demo projects – one in …

Climate Resilient Concrete Structures In Marine Environment Of Bangladesh, Sudarshan Srinivasan, Ian Gibb

International Conference on Durability of Concrete Structures

Bangladesh has a vast coastal infrastructure seriously affected by climate change and associated extreme environmental conditions. The rural construction sector in Bangladesh will be undergoing rapid growth in the next 10 years through rural infrastructure development programmes funded by the Asian Development Bank and the World Bank. The Local Government Engineering Department (LGED in Bangladesh), owns the rural concrete infrastructure, maintains around 380, 000 linear metres of concrete bridges or culverts in the rural coastal areas and are planning to build more than 200,000 linear metres during the next ten years. In order to design and construct durable concrete structures …

The Performance Of Concrete In A Marine Environment, Michael D. Thomas, Edward G. Moffatt

International Conference on Durability of Concrete Structures

This paper presents a summary of data from wide range of concretes following periods of marine exposure ranging up to 25 years. Data are presented from more than 100 different concrete mixtures. The various types of concrete include fibre-reinforced concrete (FRC), ultra-high performance concrete (UHPC), concrete with a range of supplementary cementing materials (SCM such as fly ash, slag, and silica fume) and replacement levels (e.g. up to 58% fly ash and 80% slag), lightweight-aggregate concrete (LWAC) and concrete containing alkali-silica reactive aggregate. Testing included measuring chloride concentration profiles, electrochemical corrosion measurements (for steel-reinforced concrete), and various electrical and mechanical …

Development Of Local And Global Corrosion Sensing Technique To Monitor Structural Behavior Of Prestressed Concrete Structures, Dewan Z. Hossain

FIU Electronic Theses and Dissertations

Corrosion of steel rebar in reinforced concrete structures is a concern for highway bridge owners. According to 2002 study by the Federal Highway Administration, ~15% of the highway bridges in the US are structurally deficient due to corrosion and have an estimated annual direct cost of $8.3 billion. Generally, in post-tensioned bridges, ducts filled with poor or incomplete grouting can allow the tendons to come into contact with water, leading to corrosion and fracture. Although new and improved procedures of grouting have been developed to reduce the instances of poor grouting, the problem of how to reliably inspect tendons on …

Corrosion Durability Of A Nano-Particle Enriched Zinc-Rich Coating System For Highway Steel Bridges, Saiada Fuadi Fancy

FIU Electronic Theses and Dissertations

Corrosion is a major concern for the long-term durability and structural integrity of steel components of highway bridges when unprotected. The application of protective coatings has been widely used for corrosion mitigation of atmospherically exposed structural steel. At present, the zinc-rich primer (ZRP) based three-coat system is widely used in the United States. The metallic zinc pigment ideally would provide corrosion resistance by sacrificial as well as barrier protection. The life of these coating systems is at best only half of the bridge design life. Furthermore, premature degradation may occur if there are flaws in the system due to improper …

The Influence Of Incorporation Of Mn On The Pitting Corrosion Performance Of Crfeconi High Entropy Alloy At Different Temperatures, H. Torbati-Sarraf, Mitra Shabani, Paul D. Jablonski, Garrett J. Pataky, A. Poursaee

Publications

The electrochemical behavior and susceptibility to pitting corrosion of CrFeCoNi and CrMnFeCoNi high entropy alloys were studied in a 0.1 M NaCl solution at temperatures ranging from 25 to 75 °C. Electrochemical measurements revealed that CrMnFeCoNi is more susceptible to oxide film breakdown and localized corrosion compared to CrFeCoNi. Post corrosion microscopic observations showed severe pitting corrosion for CrMnFeCoNi in higher temperatures compared to CrFeCoNi. Based on in-depth XPS profile measurements on the remaining oxide films, this behavior was attributed to the depletion of Cr in the oxide film and detrimental presence of Mn in the matrix solid solution of …

Simulation And Behavior Of Corrosion Deteriorated Reinforced Concrete Members, M. A. Shayanfar, Amir Safiey

Amir Safiey

Several reinforced concrete (RC) infrastructures are now crumbling from corrosion of steel bars in concrete. The paper presents the recent advancements in analytical simulation of corrosion aftereffects on behavior of RC members. The model juxtaposes the experimental findings with analytical relationships. The implementation of the model into a nonlinear finite element formulation as well as the experimental and analytical backgrounds are discussed. The abilities of the resulted program have been studied by modeling some experimental specimens showing a reasonable agreement between the analytical and experimental findings.

A New Approach For Nonlinear Finite Element Analysis Of Reinforced Concrete Structures With Corroded Reinforcements, Mohsen A. Shayanfar, Amir Safiey

Amir Safiey

A new approach for nonlinear finite element analysis of corroded reinforcements in reinforced concrete (RC) structures is elaborated in the article. An algorithmic procedure for producing the tension-stiffening curve of

RC elements taking into consideration most of effective parameters, e.g.: the rate of steel bar corrosion, bond-slip behavior, concrete cover and amount of reinforcement, is illustrated. This has been established on both experimental and analytical bases. This algorithm is implemented into a nonlinear finite element analysis program. The abilities of the resulted program have been studied by modeling some experimental specimens showing a reasonable agreement between the analytical and experimental …

Corrosion Effects On Tension Stiffening Behavior Of Reinforced Concrete, M. A. Shayanfar, M. Ghalehnovi, Amir Safiey

Amir Safiey

The investigation of corrosion effects on the tensile behavior of reinforced concrete (RC) members is very important in region prone to high corrosion conditions. In this article, an experimental study concerning corrosion effects on tensile behavior of RC members is presented. For this purpose, a comprehensive experimental program including 58 cylindrical reinforced concrete specimens under various levels of corrosion is conducted. Some of the specimens (44) are located in large tub containing water and salt (5% salt solution); an electrical supplier has been utilized for the accelerated corrosion program. Afterwards, the tensile behavior of the specimens was studied by means …

Retrofitting Of Bridge Elements Subjected To Predominantly Axial Load Using Uhpc Shell, Mahsa Farzad

FIU Electronic Theses and Dissertations

In the United States, ~30% of the ~600,000 highway bridges are categorized as structurally deficient or functionally obsolete. These bridges should be replaced or upgraded to sustain the transportation needs of the growing public and private sectors of the U.S. economy. It is not uncommon for structures to have advanced levels of corrosion-induced damage where major repair and maintenance works are required. However, the transportation infrastructure may undergo disruption during rehabilitation causing interruption to critical economic public, civil and commercial activities. This mandates the development of new techniques and materials for accelerated rehabilitation and resilience. To address this issue, a …

Ductile Corrosion-Free Self-Centering Concrete Elements, Maged Youssef, Mohamed E. Meshaly, Ahmed Elansary

Civil and Environmental Engineering Publications

Corrosion is a major factor in the deterioration of reinforced concrete (RC) structures. To mitigate this problem, steel bars can be replaced with glass-fiber-reinforced-polymer (GFRP) bars. However, the lack of ductility of GFRP-RC elements has prevented their use in many structural applications, especially in seismic areas. Superelastic shape memory alloy (SMA) bars have been proposed to be used in seismic areas because of their self-centering characteristics. Also, they have the added advantage of being corrosion resistant. This paper examines the combined use of SMA and GFRP bars to achieve ductile self-centering and corrosion-free elements. The first challenge for such a …

Flexural Behaviour Of Superelastic Shape Memory Alloy Reinforced Concrete Beams During Loading And Unloading Stages, Yamen Ibrahim Elbahy, Maged Youssef

Civil and Environmental Engineering Publications

Trend of using smart structures, which can adjust when exposed to severe unexpected loading, is increasing. One of the methods to achieve such structures relies on smart materials. For example, replacing conventional steel reinforcing bars in Reinforced Concrete (RC) structures with superelastic Shape Memory Alloy (SMA) bars significantly reduces the residual deformations caused by post-yielding behaviour. This paper provides in-depth understanding of the flexural behaviour of SMA RC beams. A sectional analysis method, which predicts the flexural behaviour of SMA RC beams during both loading and unloading stages, is adopted and validated using available experimental data. An extensive parametric study …

Sustainability-Based Long-Term Management Of Bridges Under Multi-Hazard Exposure, Mohamed Soliman

Data

Corresponding data set for Tran-SET Project No. 17STOKS01. Abstract of the final report is stated below for reference:

"Bridges are under deterioration due to various mechanical and environmental stressors. Hydraulic-related hazards (e.g., flood and scour), aggressive environmental conditions, and seismic events (e.g., earthquake) are recognized as the most significant threats to the safety of bridges. In traditional risk assessment methods for structures susceptible to damage due to floods and other natural hazards (e.g., corrosion and seismic events), future hazard predictions are conducted using historic return periods and climate records. However, recent increase in flood intensity in central-southern states indicate that …

Self-Healing Microcapsules As Concrete Aggregates For Corrosion Inhibition In Reinforced Concrete, Homero Castaneda, Marwa Hassan, Miladin Radovic, Jose Milla

Data

Corresponding data set for Tran-SET Project No. 17CLSU08. Abstract of the final report is stated below for reference:

"Reinforced Concrete (RC) structures are vital to the US’s civil infrastructure for their strength and versatility. Unfortunately, RC elements deteriorate rapidly when exposed to corrosive environments. One possible solution is to extend the life of RC elements and systems using microencapsulated corrosion inhibitors to reduce the rebar corrosion rate. The capsules house an anodic corrosion inhibitor agent including calcium nitrate (CN) and triethanolamine (TEA). The integration of such microencapsulated materials will enhance the durability and extend the useful life by controlling the …

Sustainability-Based Long-Term Management Of Bridges Under Multi-Hazard Exposure, Mohamed Soliman

Publications

Bridges are under deterioration due to various mechanical and environmental stressors. Hydraulic-related hazards (e.g., flood and scour), aggressive environmental conditions, and seismic events (e.g., earthquake) are recognized as the most significant threats to the safety of bridges. In traditional risk assessment methods for structures susceptible to damage due to floods and other natural hazards (e.g., corrosion and seismic events), future hazard predictions are conducted using historic return periods and climate records. However, recent increase in flood intensity in central-southern states indicate that future hazard occurrence rate may not necessarily follow past trends. Accordingly, current design, assessment, and management methodologies should …

Self-Healing Microcapsules As Concrete Aggregates For Corrosion Inhibition In Reinforced Concrete, Homero Castaneda, Marwa Hassan, Miladin Radovic, Jose Milla

Publications

Reinforced Concrete (RC) structures are vital to the US’s civil infrastructure for their strength and versatility. Unfortunately, RC elements deteriorate rapidly when exposed to corrosive environments. One possible solution is to extend the life of RC elements and systems using microencapsulated corrosion inhibitors to reduce the rebar corrosion rate. The capsules house an anodic corrosion inhibitor agent including calcium nitrate (CN) and triethanolamine (TEA). The integration of such microencapsulated materials will enhance the durability and extend the useful life by controlling the corrosion precursors and the corrosion process during damage evolution. Therefore, this work aims to develop and characterize the …

Spatial Delineation Of Corrosion Zones For Metal Culverts Based On Coastal Louisiana Soil Characteristics, Sanjay Tewari, Francis Manning

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Corrosion of metal pipes used as culverts is a problem that affect many agencies directly involved in designing and maintaining these culverts. The corrosive environment of soil types found in a region could vary in a significant way (mildly corrosive to extremely corrosive) based on soil characteristics. Environmental conditions such as high water table, acidity and presence of various salts could make a soil corrosive to metal pipes. In this article, authors have applied a methodology of processing readily available soil data such as spatial distribution of soil types and soil characteristics (e.g. pH and conductivity) in delineating spatial corrosion …

Evaluation Of Orthophosphate Based Corrosion Inhibitors In Treated Water For El Paso Region, Francisco Solis Jr

Open Access Theses & Dissertations

Corrosion is an electrochemical phenomenon that involves the deterioration of a metal by the reaction of itself with its surrounding environment. One of the greatest issues for water utilities around the country is to keep the water quality safe. Corrosion can affect the quality of the water that we use on a daily basis by adding a bad taste, increasing the concentration of heavy metals, and allowing outside contaminants to enter the distribution system. The use of phosphate based corrosion inhibitors was tested in two different metals: iron and copper. The phosphate in the inhibitors react with the calcium in …

Assessing Corrosivity Of Galvanized Soil Reinforcements From Electrochemical Tests, Diana Alejandra Cabrera

Open Access Theses & Dissertations

The accurate estimation of the service lives of mechanically stabilized earth (MSE) walls requires a proper evaluation of the corrosion potential through electrochemical test methods. Robust field tests are required to assess the corrosivity of galvanized metal used in MSE walls. To simulate an environment similar to an MSE wall, cylindrical soil specimens about 12 in. (300 mm) in diameter and 10 in. (250 mm) in height were constructed. For every specimen, two instruments were used. The first instrument measured the polarization resistance corrosion tests carried out on galvanized strips and meshes, as well as epoxy-coated rebars. The second instrument …

Detection Of Buried Non-Metallic (Plastic And Frp Composite) Pipes Using Gpr And Irt, Jonas Kavi

Graduate Theses, Dissertations, and Problem Reports

This research investigated alternative strategies for making buried non-metallic pipes (CFRP, GFRP, and PVC) easily locatable using Ground Penetrating Radar (GPR). Pipe diameters up to 12" and buried with up to 4 ft. of soil cover were investigated. The findings of this study will help address the detection problem of non-metallic pipelines and speed the adoption of composite pipes by the petroleum and natural gas industry. The research also investigated the possibility of locating buried pipes transporting hot fluids using Infrared Thermography (IRT).

Results from the study have shown that, using carbon fabric and aluminum tape overlay on non‑metallic pipes …

Identifying Corrosion Zones In Coastal Regions For Metal Pipes -- A Gis Approach, Sanjay Tewari, Francis Manning

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Transportation agencies often allow metal pipes as an option for cross drains under/along roads and highways. Metal culverts can corrode over time at various rates based on their environmental conditions (e.g., corrosive nature of coastal soils, high water table and saltwater intrusion). This paper focuses on applying readily available soil data such as spatial distribution of soil types and soil characteristics (e.g., pH and conductivity) towards creating a geospatial information system (GIS) based approach to identifying corrosion zones in the coastal regions. A combination of data, obtained from field surveys provided by the Louisiana Transportation Research Center and Web Soil …

Corrosion Map For Metal Pipes In Coastal Louisiana, Sanjay Tewari

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Transportation agencies often allow metal pipes as an option for cross drains under/along roads and highways. Metal culverts can corrode over time at various rates based on their environmental conditions (e.g., corrosive nature of coastal soils, high water table, and saltwater intrusion).

This project was focused on applying available soil data, such as spatial distribution of soil types and soil characteristics (e.g., pH and conductivity), towards creating a Geographic Information System (GIS) based map to identify corrosion zones in coastal Louisiana. The effect of the soil characteristics (pH and conductivity) was incorporated in to the published corrosion models for calculating …

Comparison Of Chemical-Use Between Hydraulic Fracturing, Acidizing, And Routine Oil And Gas Development, Mary Kay Camarillo, William T. Stringfellow, J. K. Domen, S. B. Shonkoff

All Faculty Articles - School of Engineering and Computer Science

The potential hazards and risks associated with well-stimulation in unconventional oil and gas development (hydraulic fracturing, acid fracturing, and matrix acidizing) have been investigated and evaluated and federal and state regulations requiring chemical disclosure for well-stimulation have been implemented as part of an overall risk management strategy for unconventional oil and gas development. Similar evaluations for chemicals used in other routine oil and gas development activities, such as maintenance acidizing, gravel packing, and well drilling, have not been previously conducted, in part due to a lack of reliable information concerning on-field chemical-use. In this study, we compare chemical-use between routine …

Nano-Channels Early Formation Investigation On Stainless Steel 316ti After Immersion In Molten Pb-Bi, Abu Khalid Rivai, Mardiyanto Mardiyanto, Annette Heinzel

Makara Journal of Technology

Development of fuel cladding and structural materials in Pb-Bi environment, especially at high temperature, is a critical issue for the deployment of LFR (Lead alloy-cooled Fast Reactor) and ADS (Accelerator Driven Transmutation System). This is because of the corrosive characteristic of Pb-Bi to metals as constituent materials of fuel cladding and structural of the reactors. Corrosion test of a high-chromium austenitic stainless steel i.e. SS316Ti in molten Pb-Bi at 550 ºC has been carried out for about 300 hours continuously. The characterization using SEM-EDS (Scanning Electron Microscopy - Energy Dispersive X-ray Spectroscopy) showed that an iron oxide as the outer …

Mechanism Of Cathodic Prevention Of Carbon Steel In Concrete, Krittin Rattakham

USF Tampa Graduate Theses and Dissertations

In this work, I aim to clarify the mechanism that allows steel to attain higher chloride threshold as it is cathodically polarized. Specifically, I seek to provide empirical information on whether an intrinsic (predominantly interfacial effects of polarization) or an extrinsic (predominantly concentration changes due to polarization) mechanism may be dominant in the beneficial effect of polarization. I carried out this experiment with 12 identical concrete specimens, each with a cast-in steel plate, constantly exposed them to high-chloride environment. The specimens were divided into 4 triplicates and polarized at 4 different level from OCP, -200, -300 to -400 mV_{SCE …}

Corrosion Degradation Mechanism Of Cbpc Coating System For Highway Bridge Steel Components, Md Ahsan Sabbir

FIU Electronic Theses and Dissertations

Coatings are widely used to mitigate corrosion of structural steel in aggressive humid environments. However, the service life is often diminished in aggressive environments. Repair of coatings can be costly due to materials, labor and environmental controls. So, in search for novel coatings, Chemically Bonded Phosphate Ceramic (CBPC) coating was investigated for marine bridge application. The research on CBPC coating considered various exposure environments such as inland, beach, salt-fog, wet and alternate wet and dry exposure to identify the degradation mechanism. To assess the corrosion damage, the coating was evaluated by visual inspection, thickness, adhesion, microscopy and X-ray diffraction.

The …