American Studies Commons^™

Diamond Based-Materials: Synthesis, Characterization And Applications, Qiang Hu

USF Tampa Graduate Theses and Dissertations

The studies covered in this dissertation concentrate on the various forms of diamond films synthesized by chemical vapor deposition (CVD) method, including microwave CVD and hot filament CVD. According to crystallinity and grain size, a variety of diamond forms primarily including microcrystalline (most commonly referred to as polycrystalline) and nanocrystalline diamond films, diamond-like carbon (DLC) films were successfully synthesized. The as-grown diamond films were optimized by changing deposition pressure, volume of reactant gas hydrogen (H2) and carrier gas argon (Ar) in order to get high-quality diamond films with a smooth surface, low roughness, preferred growth orientation and high sp3 bond …

Techniques For Enhancing Reliability In Vlsi Circuits, Ransford Morel Hyman Jr

USF Tampa Graduate Theses and Dissertations

Reliability is an important issue in very large scale integration(VLSI) circuits. In the absence of a focus on reliability in the design process, a circuit’s functionality can be compromised. Since chips are fabricated in bulk, if reliability issues are diagnosed during the manufacturing of the design, the faulty chips must be tossed, which reduces product yield and increases cost. Being aware of this situation, chip designers attempt to resolve as many issues dealing with reliability on the front-end of the design phase (architecture or systemlevel modeling) to minimize the cost of errors in the design which increases as the design …

Fabrication And Characterization Of Novel 2sss Cigs Thin Film Solar Cells For Large-Scale Manufacturing, Keshavanand Jayadevan

USF Tampa Graduate Theses and Dissertations

A novel 2SSS (2 Step Solid Selenization) CIGS (Cu, In, Ga, Se) thin film solar cell recipe was developed which can be a replacement to the conventional co-deposition process usually employed for large-scale manufacturing. The co-deposition procedure is faced with multiple problems such as selenium incorporation, effective gallium incorporation in the absorber. It is a 2-step proprietary procedure with better control over growth mechanisms and material utilization for the absorber layer for the CIGS thin film solar cells. It makes use of solid selenium source as preferred by manufacturers. Each step of the 2-step procedure was dealt with separately for …

Growth And Characterization Of Thermoelectric Ba8Ga16Ge30 Type-I Clathrate Thin-Films Deposited By Pulsed Dual-Laser Ablation, Robert Harry Hyde

USF Tampa Graduate Theses and Dissertations

The on-going interest in thermoelectric (TE) materials, in the form of bulk and films, motivates investigation of materials that exhibit low thermal conductivity and good electrical conductivity. Such materials are phonon-glass electron-crystals (PGEC), and the multi-component type-I clathrate Ba₈Ga₁₆Ge₃₀ is in this category. This work reports the first investigation of Ba₈Ga₁₆Ge₃₀ films grown by pulsed laser deposition (PLD).

This dissertation details the in-situ growth of polycrystalline type-I clathrate Ba₈Ga₁₆Ge₃₀ thin-films by pulsed laser ablation. Films deposited using conventional laser ablation produced films that contained a …

Minimal And Symmetric Global Partition Polynomials For Reproducing Kernel Elements, Mario Jesus Juha

USF Tampa Graduate Theses and Dissertations

The Reproducing Kernel Element Method is a numerical technique that combines finite element and meshless methods to construct shape functions of arbitrary order and continuity, yet retains the Kronecker-δ property. Central to constructing these shape functions is the construction of global partition polynomials on an element. This dissertation shows that asymmetric interpolations may arise due to such things as changes in the local to global node numbering and that may adversely affect the interpolation capability of the method. This issue arises due to the use in previous formulations of incomplete polynomials that are subsequently non-affine invariant. This dissertation lays out …

A Remotely Operated Multi-Tracked Vehicle For Subterranean Exploration Of Gopher Tortoise Burrows, William Keese

USF Tampa Graduate Theses and Dissertations

The gopher tortoise is a land tortoise living in the southeastern United States. It is a species in decline and is listed as threatened or endangered in six different states. The gopher (as commonly referred) digs burrows that it uses for many reasons and spends most of its time underground. Problems occur when trying to estimate a population because a gopher tortoise digs more than one burrow. This thesis demonstrates an innovative way to survey and investigate a gopher tortoise burrow hole by using a multi-tracked remotely operated vehicle. The vehicle carried two cameras (fore and aft) and was equipped …

Biodegradation Of Bisphenol-A And 17b-Estradiol In Soil Mesocosms Under Alternating Aerobic/Anoxic/Anaerobic Conditions, Won-Seok Kim

USF Tampa Graduate Theses and Dissertations

Soil-aquifer treatment (SAT) has been proposed as a method for reusing treated municipal wastewater. SAT is characterized by alternating cycles of aerobic and anaerobic conditions in the subsurface, in response to alternating cycles of flooding and drainage of a surface impoundment. It is not yet known how these alternating redox conditions affect the removal of potentially harmful endocrine-disrupting compounds (EDCs) from treated effluent.

The overall objective of my doctoral research is to determine the fate of EDCs in alternating aerobic/anoxic/anaerobic conditions under simulated SAT conditions. To assess the fate of EDCs in simulated SAT conditions, I first had to develop …

Performance Enhancement Using Cross Layer Approaches In Wireless Ad Hoc Networks, Murad Khallid

USF Tampa Graduate Theses and Dissertations

Ad hoc network is intrinsically autonomous and self-configuring network that does not require any dedicated centralized management. For specialized applications such as, military operations, search-and-rescue missions, security and surveillance, patient monitoring, hazardous material monitoring, 4G (4th Generation) coverage extension, and rural communication; ad hoc networks provide an intelligent, robust, flexible and costeffective solution for the wireless communication needs.

As in centralized wireless systems, ad hoc networks are also expected to support high data rates, low delays, and large node density in addition to many other QoS (Quality of Service) requirements. However, due to unique ad hoc network characteristics, spectrum scarcity, …

Oxygen Diffusion Characterization Of Frp Composites Used In Concrete Repair And Rehabilitation, Chandra K. Khoe

USF Tampa Graduate Theses and Dissertations

Many independent studies have conclusively demonstrated that fiber reinforced polymers (FRP) slow down chloride-induced corrosion of steel in concrete. The mechanism for this slow down is not well understood but it has been hypothesized that FRP serves as a barrier to the ingress of chloride, moisture, and oxygen that sustain electrochemical corrosion of steel.

This dissertation presents results from an experimental study that determined the oxygen permeation rates of materials used in infrastructure repair. In the study, the oxygen permeation constants for epoxy, carbon and glass fiber laminates, concrete, epoxy-concrete and FRP-concrete systems were determined and a method developed to …

Approaches To Arc Flash Hazard Mitigation In 600 Volt Power Systems, Curtis Thomas Latzo

USF Tampa Graduate Theses and Dissertations

Federal regulations have recognized that arc flash hazards are a critical source of potential injury. As a consequence, in order to work on some electrical equipment, the energy source must be completely shut-down. However, power distribution systems in mission critical facilities such as hospitals and data centers must sometimes remain energized while being maintained. In recent years the Arc Flash Hazard Analysis has emerged as a power system tool that informs the qualified technician of the incident energy at the equipment to be maintained and recommends the proper protective equipment to wear. Due to codes, standards and historically acceptable design …

Design Issues In Magnetic Field Coupled Array: Clock Structure, Fabrication Defects And Dipolar Coupling, Anita Kumari

USF Tampa Graduate Theses and Dissertations

Even though silicon technology is dominant today, the physics (quantum electron tunneling effect), design (power dissipation, wire delays) and the manufacturing (lithography resolution) limitations of CMOS technology are pushed towards the scaling end. These issues motivated us towards a new paradigm that contributes to a continued advancement in terms of performance, density, and cost. The magnetic field coupled computing (MFC) paradigm, which is one of the regimes where we leverage and utilize the neighbor interaction of the nanomagnets to order the single-domain magnetic cells to perform computational tasks. The most important and attractive features of this technology are: 1) room …

A Study On The Miniaturization Of Microstrip Square Open Loop Resonators, Luis Manuel Ledezma

USF Tampa Graduate Theses and Dissertations

A miniaturization technique that allows the size of microstrip square open loop resonators to be reduced by more than 80% is presented and studied. The technique is based on the loading of the resonator with a series surface mount capacitor. It is shown that this technique allows the design of microwave bandpass filters with a wider stopband when compared with conventional designs. It is also proved that the insertion loss of the miniaturized filter is not degraded, but in fact can be maintained or even enhanced by the miniaturization process; this is true whenever the quality factor of the lumped …

Decision Support Models For Design Of Fortified Distribution Networks, Qingwei Li

USF Tampa Graduate Theses and Dissertations

Lean distribution networks have been facing an increased exposure to the risk of unpredicted disruptions causing significant economic forfeitures. At the same time, the existing literature contains very few studies that examine the impact of fortification of facilities for improving network reliability. This dissertation presents three related classes of models that support the design of reliable distribution networks. The models extend the uncapacitated P-median and fixed-charge location models by considering heterogeneous facility failure probabilities, supplier backups, and facility fortification within a finite budget. The first class of models considers binary fortification via linear fortification functions. The second class of models …

Self-Alignment Of Silicon Microparts On A Hexadecane-Water Interface By Surface Tension, Caroline Elizabeth Liberti

USF Tampa Graduate Theses and Dissertations

Mechanical assembly of systems and structures on the micro-scale can be inefficient as particles of sub-millimeter dimensions are difficult to manipulate. Cutting edge manufacturing methods implement self-assembly as an approach to ordering micro and nano-sized parts into a desired arrangement. This thesis studies a technique utilizing surface tension as a method of actuating microparts on a liquid-liquid interface via lateral capillary interactions. Preliminary experimentation is conducted to investigate the feasibility of developing a new method for self-alignment of microparts by observing the influence of interfacial geometry on the movement of silicon tiles along a hexadecanewater interface. Different surface geometries are …

Stress-Strain Management Of Heteroepitaxial Polycrystalline Silicon Carbide Films, Christopher William Locke

USF Tampa Graduate Theses and Dissertations

Silicon carbide (SiC) is one of the hardest known materials and is also, by good fortune, a wide bandgap semiconductor. While the application of SiC for high-temperature and high-power electronics is fairly well known, its utility as a highly robust, chemically-inert material for microelectrical mechanical systems (MEMS) is only beginning to be well recognized. SiC can be grown on both native SiC substrates or on Si using heteroepitaxial growth methods which affords the possibility to use Si micromachining methods to fabricate advanced SiC MEMS devices.

The control of film stress in heteroepitaxial silicon carbide films grown on polysilicon-on-oxide substrates has …

Operational Performance Evaluation Of Four Types Of Exit Ramps On Florida's Freeways, Linjun Lu

USF Tampa Graduate Theses and Dissertations

This research focuses primarily on the analysis of exit ramp performance related to safety and operations. The safety analysis focuses on the impacts of different exit ramp types for freeway diverge areas and different factors contributing to the crashes that occur on the exit ramp sections. The operational analysis is based mainly on simulations by TSIS-CORSIM. Different ramp effects and guidance for selecting optimal exit ramp type are concluded. Issues related to ramp sections and crossroad sections are also demonstrated. Minimum ramp length and minimum distance between ramp terminal and downstream or upstream intersections are calculated. The operational analysis was …

Thermo-Mechanical Beam Element For Analyzing Stresses In Functionally Graded Materials, Simon Caraballo

USF Tampa Graduate Theses and Dissertations

Modeling at the structural scale most often requires the use of beam and shell elements. This simplification reduces modeling complexity and computation requirements but sacrifices the accuracy of through-the-thickness information. Several studies have reported various design approaches for analyzing functionally graded material structures. One of these studies proposed a two-node beam element for functionally graded materials (FGMs) based on first order shear deformable (FOSD) theory. The derivation of governing equations included spatial temperature variation. However, only the constant temperature case was carried through in the element formulation. This investigation explore the effects of spatial temperature variation in the axial and …

Supercritical Fluid Aided Microencapsulation Of Dry Powders, Raquel Carvallo

USF Tampa Graduate Theses and Dissertations

Coating of fine particles to produce tailored surface properties is currently a key development for supercritical fluids applications, in different areas such as: pharmaceutical, nutraceutical, cosmetic, agrochemical, electronic and specialty chemistry industries. During the encapsulation process the particles surface can be designed with specific properties by spreading a thin film coating material over the surface of the particles.

Chitosan, a natural polymer, was used in this work as the encapsulant material. Chitosan is biocompatible, biodegradable to normal body constituents, safe, non-toxic, bacteriostatic, anticancerogen, and versatile polymer. These attributes are among the properties that make Chitosan an attractive component of pharmaceutical …

Restoration Of Displaced Cast-In-Place Concrete Slabs On Grade With The Use Of The Isb-07 Subsurface Support Bracket, Jose Carlos Busquets

USF Tampa Graduate Theses and Dissertations

The restoration of foundations of residential and light commercial structures that have been affected by differential displacement resulting from problematic soil conditions has been an ongoing issue since early times. In Florida, the issue of structures being affected by subsidence of soils related to sinkhole activity has been a problem that has gained more interest and exposure within the last 20 years. Structures affected by sinkholes have been historically addressed by remediating the soil mechanism which caused the structure to displace and then structurally addressing the portions of the structure that have displaced with steel underpins installed on the foundation. …

Novel Magnetic Materials For Sensing And Cooling Applications, Anurag Chaturvedi

USF Tampa Graduate Theses and Dissertations

The overall goals of the present PhD research are to explore the giant magnetoimpedance (GMI) and giant magnetocaloric (GMC) effects in functional magnetic materials and provide guidance on the optimization of the material properties for use in advanced magnetic sensor and refrigeration applications.

GMI has attracted growing interest due to its promising applications in high-performance magnetic sensors. Research in this field is focused on the development of new materials with properties appropriate for practical GMI sensor applications. In this project, we have successfully set up a new magneto-impedance measurement system in the Functional Materials Laboratory at USF. We have established, …

The Impact Of Pharmacy Work Design On Pharmacist Productivity, Nicholas Allen Coblio

USF Tampa Graduate Theses and Dissertations

Healthcare costs in the United States continue to grow at an alarming rate. Concerning the cost of medications, there are a number of factors that drive these costs. While personnel costs are not the largest of these, they do contribute a significant portion. The cost of the cognitive component of order processing by pharmacists can range from three dollars to over six dollars per prescription depending on the production throughput of the pharmacist.

Studies at the organization which was the focus of the research, as well as reports in the literature, indicated that work disruption and other environmental factors could …

Analytical Methods To Support Risk Identification And Analysis In Healthcare Systems, Laila Nadime Cure Vellojin

USF Tampa Graduate Theses and Dissertations

Healthcare systems require continuous monitoring of risk to prevent adverse events. Risk analysis is a time consuming activity that depends on the background of analysts and available data. Patient safety data is often incomplete and biased. This research proposes systematic approaches to monitor risk in healthcare using available patient safety data. The methodologies combine traditional healthcare risk analysis methods with safety theory concepts, in an innovative manner, to allocate available evidence to potential risk sources throughout the system. We propose the use of data mining to analyze near-miss reports and guide the identification of risk sources. In addition, we propose …

Mechanistic Modeling Of Photocatalytic Water Disinfection, Omatoyo Kofi Dalrymple

USF Tampa Graduate Theses and Dissertations

The main goal of this research was to develop a mechanism-based model for photocatalytic disinfection of bacteria in water using suspended catalyst pthesiss in batch reactors. The photocatalytic disinfection process occurs as a semiconductor photocatalyst, most commonly titanium dioxide (TiO₂), is irradiated with light of wavelength less than 380 nm to produce hydroxyl radicals and other highly reactive oxidants which can inactivate microorganisms. Photocatalytic disinfection involves a complex interaction of many fundamental mechanisms such as light absorption and scattering by semiconductor pthesiss, electrochemical surface reactions, and heterogeneous colloidal stability. Current models, based largely on chemical reacting systems, do …

Smart Grid Functionality Of A Pv-Energy Storage System, Nenad Damnjanovic

USF Tampa Graduate Theses and Dissertations

Renewable Energy will be the key to preserving the Earth's remaining resources and continuing this surge of technological progress that we have experienced this past century. New philosophies of how/when/where energy should be consumed and produced are attempting to improve upon the current grid infrastructure. The massive advancement in communications, renewable and control systems will allow this new-age electric grid to maximize its efficiency while reducing cost. Renewable, "green" energy is now at the forefront of innovation. As the world population increases, there will be a need to free ourselves from natural resources as much as possible. Advanced Energy Storage …

Modeling Roadside Safety Hazards To Predict Annual Crash Cost To Encroaching Vehicles In Rural Road Networks, Isidro Delgado

USF Tampa Graduate Theses and Dissertations

Roadside crashes account for a large portion of total fatal crashes that occur annually in the United States. About 30% of those fatalities are the result of single vehicle run-off-road crashes. A large proportion of these fatal crashes occur in rural roads when vehicles depart from the travel lane and collide with trees or other roadside safety hazards. Many of these run-off-road accidents occur in local roads that carry traffic volumes between 1,000 and 20,000 vehicles per day. Many of these roads are part of the jurisdiction of county authorities faced with the dilemma of having too many "potentially dangerous" …

Ultra-Low Power Electronics For Autonomous Micro-Sensor Applications, Rebeka Davidova

USF Tampa Graduate Theses and Dissertations

This thesis presented the research, design and fabrication associated with a unique application of rectenna technology combined with lock-in amplification. An extremely low-power harmonic transponder is conjoined with an interrogator base-station, and utilizing coherent demodulation the Remote Lock-In Amplifier (RLIA) concept is realized. Utilizing harmonic re-radiation with very low-power input, the 1^st generation transponder detects a transmitted interrogation signal and responds by retransmitting the second harmonic of the signal. The 1^st generation transponder performs this task while using no additional power besides that which accompanies the wireless signal. Demonstration of the first complete configuration provided proof of concept …

Theoretical And Experimental Analysis Of Power And Cooling Cogeneration Utilizing Low Temperature Heat Sources, Gökmen Demirkaya

USF Tampa Graduate Theses and Dissertations

Development of innovative thermodynamic cycles is important for the efficient utilization of low-temperature heat sources such as solar, geothermal, and waste heat sources. Binary mixtures exhibit variable boiling temperatures during the boiling process, which leads to a good thermal match between the heating fluid and working fluid for efficient heat source utilization. This study presents a theoretical and an experimental analysis of a combined power/cooling cycle, which combines the Rankine and absorption refrigeration cycles, uses ammonia-water mixture as the working fluid and produces power and refrigeration, while power is the primary goal. This cycle, also known as the Goswami Cycle, …

Anaerobic Membrane Bioreactor (Anmbr) For Treatment Of Landfill Leachate And Removal Of Micropollutants, Anh Tien Do

USF Tampa Graduate Theses and Dissertations

To date, most studies on the fate and removal of endocrine disrupting compounds (EDCs) and pharmaceutical and personal care products (PPCPs) in wastewater focus on their fate in municipal wastewater treatment plants, and mostly under aerobic condition. There are limited studies related to anaerobic condition and (to our knowledge) no study on the removal of EDCs in landfill leachate by AnMBR. Moreover, for most studies under anaerobic condition, the removal of EDCs was only reported in the liquid phase; solid phase extraction was not reported, thereby preventing mass balance in the studies.

This research was conducted to investigate the potential …

Apparent Total Evaporative Resistance Values From Human Trials Over A Range Of Metabolic And Heat Stress Levels, Matthew David Dooris

USF Tampa Graduate Theses and Dissertations

Failure to maintain thermal equilibrium can cause uncontrollable increases in body core temperature beyond critical upper limits. In selecting clothing, consideration must be given to the heat transfer properties of clothing that may restrict the cooling capacity of the human body under heat stress conditions, most importantly, apparent total evaporative resistance (R_e,T,_a). This study calculated and compared R_e,T,_a for five clothing ensembles under varying heat stress conditions, including three relative humidity (RH) levels and three stages of heat stress to determine if R_e,T,_a values varied or remained the same with …

Steady And Transient Heat Transfer For Jet Impingement On Patterned Surfaces, Mark Michael Dobbertean

USF Tampa Graduate Theses and Dissertations

Free liquid-jet impingement is well researched due to its high heat transfer ability and ease of implementation. This study considers both the steady state and transient heating of a patterned plate under slot-free-liquid jet impingement. The primary working fluid was water (H2O) and the plate material considered was silicon. Calculations were done for Reynolds number (Re) ranging from 500 to 1000 and indentation depths from 0.000125 to 0.0005 m for three different surface configurations. The effect of using different plate materials and R-134a as the working fluid were explored for the rectangular step case. The distributions of the local and …