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Multi-Factor Optimization Of Bio-Methanol Production Through Gasification Process Via Statistical Methodology Coupled With Genetic Algorithm, Amin Hedayati Moghaddam, Morteza Esfandyari, Dariush Jafari, Hossein Sakhaeinia Oct 2023

Multi-Factor Optimization Of Bio-Methanol Production Through Gasification Process Via Statistical Methodology Coupled With Genetic Algorithm, Amin Hedayati Moghaddam, Morteza Esfandyari, Dariush Jafari, Hossein Sakhaeinia

Department of Civil and Environmental Engineering: Faculty Publications

This work innovatively explores the bio-methanol production process, conducts comprehensive analyses, develops statistical models, and optimizes operational conditions, contributing valuable insights to the field of sustainable energy production from biomass. Accordingly, bio-methanol production from biomass through gasification route was investigated and simulated using Aspen Plus software. The effects of operational parameters on energy duty of gasification reactor and the methanol production rate in syngas to methanol reactor were investigated. The parameters affecting the process performance including temperature, pressure, and steam/feed ratio were examined using the response surface methodology (RSM) by central composite design (CCD) technique. Analysis of variance (ANOVA) was …


Multi-Factor Optimization Of Bio-Methanol Production Through Gasification Process Via Statistical Methodology Coupled With Genetic Algorithm, Amin Hedayati Moghaddam, Morteza Esfandyari, Dariush Jafari, Hossein Sakhaeinia Oct 2023

Multi-Factor Optimization Of Bio-Methanol Production Through Gasification Process Via Statistical Methodology Coupled With Genetic Algorithm, Amin Hedayati Moghaddam, Morteza Esfandyari, Dariush Jafari, Hossein Sakhaeinia

Department of Civil and Environmental Engineering: Faculty Publications

This work innovatively explores the bio-methanol production process, conducts comprehensive analyses, develops statistical models, and optimizes operational conditions, contributing valuable insights to the field of sustainable energy production from biomass. Accordingly, bio-methanol production from biomass through gasification route was investigated and simulated using Aspen Plus software. The effects of operational parameters on energy duty of gasification reactor and the methanol production rate in syngas to methanol reactor were investigated. The parameters affecting the process performance including temperature, pressure, and steam/feed ratio were examined using the response surface methodology (RSM) by central composite design (CCD) technique. Analysis of variance (ANOVA) was …


Single-Step Hydrothermal Synthesis Of Biochar From H3po4-Activated Lettucewaste For Efficient Adsorption Of Cd(Ii) In Aqueous Solution, Quyun Chen, Tian C. Zhang, Like Ouyang, Shaojun Yuan Jan 2021

Single-Step Hydrothermal Synthesis Of Biochar From H3po4-Activated Lettucewaste For Efficient Adsorption Of Cd(Ii) In Aqueous Solution, Quyun Chen, Tian C. Zhang, Like Ouyang, Shaojun Yuan

Department of Civil and Environmental Engineering: Faculty Publications

Developing an ideal and cheap adsorbent for adsorbing heavy metals from aqueous solution has been urgently need. In this study, a novel, effective and low-cost method was developed to prepare the biochar from lettuce waste with H3PO4 as an acidic activation agent at a low-temperature (circa 200°C) hydrothermal carbonization process. A batch adsorption experiment demonstrated that the biochar reaches the adsorption equilibrium within 30 min, and the optimal adsorption capacity of Cd(II) is 195.8 mg⋅g-1at solution pH 6.0, which is significantly improved from circa 20.5 mg⋅g-1 of the original biochar without activator. The fitting …


Combining Electrochemical Nitrate Reduction And Anammox For Treatment Of Nitrate-Rich Wastewater: A Short Review, Xinyi Zou, Chongjun Chen, Changhong Wang, Qun Zhang, Zhuowei Yu, Haiping Wu, Chao Zhuo, Tian C. Zhang Jan 2021

Combining Electrochemical Nitrate Reduction And Anammox For Treatment Of Nitrate-Rich Wastewater: A Short Review, Xinyi Zou, Chongjun Chen, Changhong Wang, Qun Zhang, Zhuowei Yu, Haiping Wu, Chao Zhuo, Tian C. Zhang

Department of Civil and Environmental Engineering: Faculty Publications

Treatment of nitrate-rich wastewater is important but challenging for the conventional biological denitrification process. Here, we propose combining the electrochemical reduction and anaerobic ammonium oxidation (anammox) processes together for treatment of nitrate-rich wastewater. This article reviews the mechanism and current research status of electrochemical reduction of nitrate to ammonium as well as the mechanism and applicability of the anammox process. This article discusses the principles, superiorities, and challenges of this combined process. The feasibility of the combined process depends on the efficiency of electrochemical nitrate reduction to ammonium and the conditions in the anammox process to use the reduced ammonium …


Insights Into The Adsorption Of Pb(Ii) Over Trimercapto-S-Triazine Trisodium Salt-Modified Lignin In A Wide Ph Range, Qiaorui Wang, Chunli Zheng, Fei He, Yuan Yao, Tian C. Zhang, Chi He Jun 2020

Insights Into The Adsorption Of Pb(Ii) Over Trimercapto-S-Triazine Trisodium Salt-Modified Lignin In A Wide Ph Range, Qiaorui Wang, Chunli Zheng, Fei He, Yuan Yao, Tian C. Zhang, Chi He

Department of Civil and Environmental Engineering: Faculty Publications

A novel fabrication method for modifying alkaline lignin (AL) was reported, in which trimercapto-s-triazine trisodium salt was used as a modifier to tune surface properties of AL. Molecular structure of modified AL (FAL) was determined by 3D-EEM, synchronous fluorescence, FTIR, 13C MAS NMR and XPS. Two-dimensional correlation spectroscopy and electron localization function demonstrated that both of electrostatic and coordinate bonds formed between these functional groups and Pb(II) at higher pH of 3.0 to 6.0 while only coordinate bond at lower pH of 0.2 to 1.2. The higher the solution pH was, the stronger the adsorption capacity of FAL had. The …


Fate And Transport Of Antibiotics And Antibiotic Resistance Genes In Runoff And Soil As Affected By The Timing Of Swine Manure Slurry Application, Renys Enrique Barrios, Himanshu Khuntia, Shannon L. Bartelt-Hunt, John E. Gilley, Amy M. Schmidt Schmidt, Daniel D. Snow, Xu Li Apr 2020

Fate And Transport Of Antibiotics And Antibiotic Resistance Genes In Runoff And Soil As Affected By The Timing Of Swine Manure Slurry Application, Renys Enrique Barrios, Himanshu Khuntia, Shannon L. Bartelt-Hunt, John E. Gilley, Amy M. Schmidt Schmidt, Daniel D. Snow, Xu Li

Department of Civil and Environmental Engineering: Faculty Publications

Land application of swine manure slurry is a common practice to supplement nutrients to soil for crop production. This practice can introduce antibiotic residues and antibiotic resistance genes (ARGs) into the environment. Field testing is critical in identifying manure management practices effective in minimizing the environmental impacts of manure-borne antibiotic and ARGs. The objective of this study was to determine how the timing of swine manure application relative to rainfall events impacts the fate and transport of antibiotics and ARGs in surface runoff and manure-amended soil. Swine manure slurry was either broadcast or injected on test plots in the field. …


Pine-Wood Derived Nanobiochar For Removal Of Carbamazepine From Aqueous Media: Adsorption Behavior And Influential Parameters, Mitra Naghdi, Mehrdad Taheran, Rama Pulicharla, Tarek Rouissi, Satinder K. Brar, M. Verma, R. Y. Surampalli Jan 2019

Pine-Wood Derived Nanobiochar For Removal Of Carbamazepine From Aqueous Media: Adsorption Behavior And Influential Parameters, Mitra Naghdi, Mehrdad Taheran, Rama Pulicharla, Tarek Rouissi, Satinder K. Brar, M. Verma, R. Y. Surampalli

Department of Civil and Environmental Engineering: Faculty Publications

In recent years, application of biochar for removal of pollutants from aqueous solutions has been of interest due to favorable physicochemical properties and availability of feedstock. However, adsorption behavior has been reported only for raw and micro biochar particles and taking advantage of biochar nanoparticles, which offer superior specific surface area, did not receive any attention. The objective of this study was to investigate the adsorption efficiency of produced nanobiochar from pinewood. For this purpose, removal of carbamazepine (CBZ), a globally prescribed pharmaceutical, at very low concentrations (0.5–20 ppb) on as-produced nanobiochar with average particle size of 60 nm was …


Feasibility Of Electromagnetic Soil Heating Using Magnetic Nanoparticle-Coated Geotextiles, Ijung Kim, Caroline Best, Seunghee Kim Jan 2019

Feasibility Of Electromagnetic Soil Heating Using Magnetic Nanoparticle-Coated Geotextiles, Ijung Kim, Caroline Best, Seunghee Kim

Department of Civil and Environmental Engineering: Faculty Publications

This paper reports a new way of soil heating using a woven and a non-woven geotextile coated with magnetic nanoparticles (MNPs) that generate heat when exposed to a magnetic field. The MNPs were synthesised in the presence of the geotextile, creating and simultaneously coating the MNPs onto the geotextile. The fixation of MNPs on the geotextile was confirmed by direct observation by way of scanning electromagnetic images and an induction heating test. When the prepared geotextile was placed inside a soil medium, heat was generated immediately as the geotextile was exposed to a high-frequency alternating magnetic field, subsequently transferring heat …


Adsorption Of Diclofenac Onto Different Biochar Microparticles: Dataset – Characterization And Dosage Of Biochar, Linson Lonappan, Tarek Rouissi, Satinder Kaur Brar, Mausam Verma, Rao Y. Surampalli Jan 2018

Adsorption Of Diclofenac Onto Different Biochar Microparticles: Dataset – Characterization And Dosage Of Biochar, Linson Lonappan, Tarek Rouissi, Satinder Kaur Brar, Mausam Verma, Rao Y. Surampalli

Department of Civil and Environmental Engineering: Faculty Publications

Due to its wide occurrence in water resources and toxicity, pharmaceuticals and personal care products are becoming an emerging concern throughout the world. Application of residual/waste materials for water remediation can be a good strategy in waste management as well as in waste valorization. Here in, this dataset provides information on biochar application for the removal of emerging contaminant, diclofenac from water matrices.The data presented here is an extension of there search article explaining the mechanisms of adsorption diclofenac on biochars(Lonappan et al., 2017[1]). This data article provides general information on the surface features of pine wood and pig manure …


Diclofenac And Its Transformation Products: Environmental Occurrence And Toxicity - A Review, Linson Lonappan, Satinder K. Brar, Ratul Kumar Das, Mausam Verma, Rao Y. Surampalli Sep 2016

Diclofenac And Its Transformation Products: Environmental Occurrence And Toxicity - A Review, Linson Lonappan, Satinder K. Brar, Ratul Kumar Das, Mausam Verma, Rao Y. Surampalli

Department of Civil and Environmental Engineering: Faculty Publications

Diclofenac (DCF) is a prevalent anti-inflammatory drug used throughout the world. Intensive researches carried out in the past few decades have confirmed the global ubiquity of DCF in various environmental compartments. Its frequent occurrence in freshwater environments and its potential toxicity towards several organisms such as fish and mussels makes DCF an emerging environmental contaminant. At typical detected environmental concentrations, the drug does not exhibit toxic effects towards living organisms, albeit chronic exposure may lead to severe effects. For DCF, about 30–70% removal has been obtained through the conventional treatment system in wastewater treatment plant being the major primary sink. …


Development Of Adsorptive Membranes By Confinement Of Activated Biochar Into Electrospun Nanofibers, Mehrdad Taheran, Mitra Naghdi, Satinder K. Brar, Emile Knystautas, Mausam Verma, Rao Y. Surampalli, Jose R. Valero Jan 2016

Development Of Adsorptive Membranes By Confinement Of Activated Biochar Into Electrospun Nanofibers, Mehrdad Taheran, Mitra Naghdi, Satinder K. Brar, Emile Knystautas, Mausam Verma, Rao Y. Surampalli, Jose R. Valero

Department of Civil and Environmental Engineering: Faculty Publications

Adsorptive membranes have many applications in removal of contaminants, such as heavy metals and organic contaminants from water. Recently, increasing concentrations of pharmaceutically active compounds, especially antibiotics, such as chlortetracycline in water and wastewater sources has raised concerns about their potentially adverse impacts on environment and human health. In this study, a series of polyacrylonitrile (PAN)/activated biochar nanofibrous membranes (NFMs) with different loadings of biochar (0–2%, w/w) were fabricated using electrospinning. The morphology and structure of fabricated membranes was investigated by scanning electron microscopy, Fourier transform infrared and thermogravimetric analysis. The results showed that at 1.5% of biochar loading, the …