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Insights Into The Adsorption Of Pb(Ii) Over Trimercapto-S-Triazine Trisodium Salt-Modified Lignin In A Wide Ph Range, Qiaorui Wang, Chunli Zheng, Fei He, Yuan Yao, Tian C. Zhang, Chi He
Insights Into The Adsorption Of Pb(Ii) Over Trimercapto-S-Triazine Trisodium Salt-Modified Lignin In A Wide Ph Range, Qiaorui Wang, Chunli Zheng, Fei He, Yuan Yao, Tian C. Zhang, Chi He
Department of Civil and Environmental Engineering: Faculty Publications
A novel fabrication method for modifying alkaline lignin (AL) was reported, in which trimercapto-s-triazine trisodium salt was used as a modifier to tune surface properties of AL. Molecular structure of modified AL (FAL) was determined by 3D-EEM, synchronous fluorescence, FTIR, 13C MAS NMR and XPS. Two-dimensional correlation spectroscopy and electron localization function demonstrated that both of electrostatic and coordinate bonds formed between these functional groups and Pb(II) at higher pH of 3.0 to 6.0 while only coordinate bond at lower pH of 0.2 to 1.2. The higher the solution pH was, the stronger the adsorption capacity of FAL had. The …