Digital Commons Network^™

Elucidation Of Active Site And Mechanism Of Metal Catalysts Supported In Nu-1000, Hafeera Shabbir

All Dissertations

Advances in extraction of shale oil and gas has increased the production of geographically stranded natural gas (primarily consisting of methane (C1) and ethane (C2)) that is burned on site. A potential utilization strategy for shale gas is to convert it into fuel range hydrocarbons by catalytic dehydrogenation followed by oligomerization by direct efficient catalysts. This work focuses on understanding metal cation catalysts supported on metal-organic framework (MOF) NU-1000 that will actively and selectively do this transformation under mild reaction conditions, while remaining stable to deactivation (via metal agglomeration or sintering). I built computational models validated by experimental methods to …

Identity Tensions And Negotiations Of English Teachers In Costa Rica Through Narrative Inquiry, Hazel Vega Quesada

All Dissertations

This study examined the identity tensions and negotiations of novice three English teachers in Costa Rica, and English as a foreign language context. Grounded in a Communities of Practice framework, this research describes how teachers’ identities are constrained and enabled in complicated academic, social, and political settings. In this study, identity tensions referred to dilemmas that juxtaposed internal and external expectations, values, and practices. Negotiations referred to teachers’ choices, proposals, and changes that denoted their appropriation or contestation of practices and meanings of their communities of practice. I used narrative inquiry to collect and analyze teachers’ experiences learning English and …

Lindley Processes With Correlated Changes, John Grant

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This dissertation studies a Lindley random walk model when the increment process driving the walk is strictly stationary. Lindley random walks govern customer waiting times in many queueing models and several natural and business processes, including snow depths, frozen soil depths, inventory quantities, etc. Probabilistic properties of a Lindley process with time-correlated stationary changes are explored. We provide a streamlined argument that the process admits a limiting stationary distribution when the mean of the incremental changes is negative and that the Lindley process is strictly stationary when starting from this stationary distribution. The Markov characteristics of the process are explored …

X-Ray Interrogated Implantable Chemical And Strain Sensors For Monitoring Implant Associated Infections And Fracture Healing, Apeksha Rajamanthrilage

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Bone fracture healing includes complex and sequence of dynamic events to restore the integrity and biomechanical properties of the bone. While most of the fractures heal without any problem, healing is sometimes compromised. Two significant fracture healing complications are orthopedic implant-associated infections and non-unions/delayed union. These can be interrelated causes as well. Implant-associated infection can cause implant loosening, and as a result, it can delay the fracture healing process. Herein, we describe two different types of sensors that can be used in monitoring biochemical and biomechanical processes of fracture healing using X-rays.

We developed a XELCI (X-ray Excited Luminescence Chemical …

Cohen-Macaulay Type Of Weighted Path Ideals, Shuai Wei

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In this dissertation we give a combinatorial characterization of all the weighted $r$-path suspensions for which the $f$-weighted $r$-path ideal is Cohen-Macaulay. In particular, it is shown that the $f$-weighted $r$-path ideal of a weighted $r$-path suspension is Cohen-Macaulay if and only if it is unmixed. Type is an important invariant of a Cohen-Macaulay homogeneous ideal in a polynomial ring $R$ with coefficients in a field. We compute the type of $R/I$ when $I$ is any Cohen-Macaulay $f$-weighted $r$-path ideal of any weighted $r$-path suspension, for some chosen function $f$. In particular, this computes the type for all weighted trees …

Understanding Movement, Habitat Use, And Habitat Selection By Largemouth Bass (Micropterus Nigricans X Salmoides) And Alabama Bass (Micropterus Henshalli) On Lake Hartwell, South Carolina, Deon Kerr

All Theses

Alabama Bass (Micropterus henshalli) were illegally introduced into the upper Savannah River Basin 15-20 years ago and have since become abundant as well as problematic ecologically. Acoustic telemetry was used to quantify diel movement, habitat use, and habitat selection of Alabama Bass and Largemouth Bass in Lake Hartwell, SC across seasons (June 2021-July 2022) with the goal of informing ongoing habitat enhancement efforts. Across all seasons, Alabama Bass conducted diel horizontal migrations from deeper offshore habitats during the day to nearshore, shallow habitats at night. Daytime Alabama Bass movement rates in offshore waters were higher than nighttime movement rates. Largemouth …

An Economic Impact And Investment Analysis Of Armillaria Root Rot In The United States Peach Industry, Gracie Herrin

All Theses

Peach production in the United States has decreased over the last decade due to increased disease prevalence. Armillaria root rot (ARR) is a lethal root fungus that affects many stone fruits, including peaches, often leading to rapid decline/death of trees and abandonment of orchards. This thesis is divided into four chapters which focus on answering four key questions that, to the best of my knowledge, have not been addressed in previous industry research.

The second chapter determines the magnitude of ARR disease prevalence in the United States and producers’ maximum willingness to pay (WTP) for a theoretical ARR-resistant rootstock. Results …

Flexural Bond Strength Of Masonry Assemblies With Lightweight Grout, Benjamin L. Hiner

All Theses

Lightweight grout has many potential benefits in masonry construction, including minimizing mass, improving thermal performance, and potentially reducing shrinkage cracking via internal curing. However, insufficient testing of masonry assemblies with lightweight grout has been conducted to suggest appropriate design modification factors akin to the lambda factor in ACI 318-19. The objective of this paper is to study the tensile bond behavior of masonry assemblies grouted with lightweight grout and to suggest appropriate equations for predicting design capacity. A moment couple test is designed specifically for grouted masonry assemblies and has additional capacity compared to the traditional ASTM 1072 bond wrench …

Barriers And Facilitators In Implementing Multiplatform Remote Patient Monitoring Of Heart Failure Patients In Clinical Settings, Zachary Andrew Reilly

All Theses

Remote patient monitoring (RPM), which provides continuous monitoring of vital signs, has become increasingly utilized in patients with heart failure (HF). As this condition impacts more than 26 million Americans each year, it is important to determine the barriers and facilitators of RPM to both improve patient care and help medical professionals make more informed medical decisions. To determine these barriers and facilitators, our research team partnered with Prisma Health-Upstate to interview healthcare professionals working at Carolina Cardiology Consultants--Greenville, which uses multiple RPM systems to monitor heart failure patients.

The twelve interviews conducted support that healthcare professionals would benefit from …

Designing The House Of The Future: Social Commentary On Retrofuturism, Alyssa Woodruff

All Theses

This project explores the aesthetics of retrofuturism and the historical context of the house of the future. Retrofuturism captures how people perceived the future during previous eras in history. Conceptions of the future reflect the time period in which they are created. I designed and implemented a 3D model of a house of the future to express the aesthetics of mid-century modernism. I created the models in ZBrush and Maya. I took inspiration from The Jetsons cartoon, the New York World’s Fair of 1964-65, and Disneyland’s original Tomorrowland theme park. This project also incorporates contemporary features to reflect modern concerns. …

The Greek Merchant Marine: A Unique Combination Of Nautical Skill And Commercial Savvy, Alexander Billinis

All Theses

The Greek-owned merchant fleet remains the world’s largest, and while plenty of histories have been written about this fleet, there is a definite absence in the historiography about why the Greeks’ relation to the sea is unique, and how this fleet came into existence. The author argues that the Greek merchant fleet is a successful hybridization of a commercial middleman minority ethos born out of conditions in the Ottoman Empire and post-independence Greece, combined with the shipping skills of a littoral people who invested in this expertise.

To understand the how and why of the Greek merchant fleet, it is …

Supporting Us Army Next-Generation Ground Vehicle Simulation Modeling Using An Integrated Ontology Suite, Edward Louis

All Theses

The development of the US Army’s next-generation of ground vehicle systems is supported by simulations that predict vehicle performance and inform engineering design choices in the design and acquisition process. In this paper, we describe the development of an Integrated Ontology Suite to support modeling and simulation of next generation military ground vehicles. The ontology suite is intended to address model reuse challenges and increase the shared understanding of ground vehicle system simulations. It is intended to function in a Model Library structure that stores, documents, assembles, and executes vehicle simulations. The ontology suite consists of four domain ontologies: Vehicle …

Why Can't We Be Friends: A Training Evaluation Of Community Dialogues, Kyle Christenson

All Theses

Demographic and attitudinal diversity can be powerful tools within the team and organizational contexts. However, when not addressed effectively, diversity can greatly strain interpersonal relations and has been found to lead to a number of negative consequences at the individual, team, and organizational levels (Roth, Goldberg, & Thatcher, 2017; Harrison & Klein, 2007). Though there have been attempts to effectively mitigate these negative outcomes, few have found lasting success (Kessler, 2021). However, a training for students offered at a university nested in the southeastern region of the United States offers a relatively novel approach to handling these interpersonal differences. The …

When Advocacy Becomes (In)Voluntary: A Thematic Analysis Of Disability Focused Organizations, Michelle Brazeau

All Theses

Only 19.1% of people with disabilities are currently employed (Bureau of Labor Statistics, 2022b). Stigma associated with disability often forces people with disabilities to have limited options in terms of employment. This has caused organizations like Bitty & Beaus Coffee and The Prospector Theater to make it their mission to hire people with disabilities. To better understand how these organizations are communicating about disability online a thematic analysis of the Instagram pages of Bitty & Beaus Coffee and The Prospector Theater was conducted. The findings suggest that these organizations use the image and likeness of the employees with disabilities to …

Impact Of Housing And Management On Production, Behavior, And Welfare Of Dairy Cows In Automatic Milking Systems, Lindsey Eve Davis

All Theses

The overall objective of this research was to determine the impact of Automatic Milking System (AMS) housing and management practices on cow production, behavior, and welfare of Holstein dairy cows. The first objective was to identify factors at the farm and cow level associated with lameness on AMS farms through decision tree analysis to allocate probabilities to each input. Results indicated this novel multifactorial approach of data analysis enabled us to highlight critical points that can be focused on to lessen cow-level complications or enhance farm-level housing and management practices to reduce the incidence and severity of lameness in AMS …

Venomic Characterization Of A Medically Relevant Rear-Fanged Snake, Conophis Lineatus (Dipsadidae: Xenodontinae), From Middle America, Tristan Schramer

All Theses

Most traditional research on snake venoms has focused on front-fanged snake families (Viperidae, Elapidae, and Atractaspididae). However, venom is now generally accepted as being a much more broadly possessed trait within snakes, including species traditionally considered harmless. Unfortunately, due to historical inertia and methodological challenges, the toxin repertoires of non-front-fanged snake families (e.g., Colubridae, Dipsadidae, and Natricidae) have been heavily neglected despite the knowledge of numerous species capable of inflicting medically relevant envenomations. Integrating proteomic data for validation, we perform a de novo assembly and analysis of the Duvernoy’s venom gland transcriptome of the Central American Road Guarder (Dipsadidae: Xenodontinae: …

In Vitro Rooting Techniques In Prunus Spp. For Propagation And Disease Screening For Armillaria Root Rot (Arr) Resistance, John Lawson

All Theses

Prunus is a genus widely cultivated to produce edible fruit including almond (P. amygdalus), peach (P. persica (L.) Batsch), cherries (P. avium and P. cerasus), among others. The cultivation of Prunus is economically important for several regions of the United States and relies on appropriate cultivars and rootstocks that are adapted to a growing region. Encroaching plant pathogens are forcing breeders to use sexually compatible germplasm from related species for introgression of novel alleles that confer tolerance or resistance. This is especially true in the rootstock breeding where interspecific hybridization is often used …

Cover Cropping And Organic Amendments To Improve Sandy Soils Under Organic Vegetable Production, Charles Williamson

All Theses

Coastal Plain soils in the Southeastern USA are typically sandy with poor soil structure, low soil organic carbon (SOC) content, and meager soil fertility that pose challenges to organic agriculture. Adding organic inputs is a strategy to improve these soils' physical, chemical, and biological characteristics. Here, we aim to investigate the impacts of Cover Cropping (CC) and manure inclusions on sandy soils under organic vegetable production. The experiment design was a randomized complete block with two treatments of manure application (with and without) and four CC treatments of cereal rye (Secale cereale), hairy vetch (Vicia villosa), …

Koopman Operator Theory And The Applied Perspective Of Modern Data-Driven Systems, Alex Krolicki

All Theses

Recent theoretical developments in dynamical systems and machine learning have allowed researchers to re-evaluate how dynamical systems are modeled and controlled. In this thesis, Koopman operator theory is used to model dynamical systems and obtain optimal control solutions for nonlinear systems using sampled system data. The Koopman operator is obtained using data generated from a real physical system or from an analytical model which describes the physical system under nominal conditions. One of the critical advantages of the Koopman operator is that the response of the nonlinear system can be obtained from an equivalent infinite dimensional linear system. This is …

If You Give A Beetle A Maple: Anoplophora Glabripennis Habitat Selection Patterns On An Island In South Carolina, Meredith Bean

All Theses

At the epicenter of the Asian longhorned beetle (Anoplophora glabripennis Motschulsky) quarantine zone in South Carolina, a small island containing an actively growing subpopulation of A. glabripennis had not completely killed its 37 host trees in 2020. Before these trees were removed and destroyed according to the USDA Eradication Program protocols, I performed an observational study to examine the microhabitat selection tendencies of the invasive A. glabripennis within this satellite infestation. After cataloging >14,000 oviposition sites and >1,600 exit holes created by A. glabripennis, I found dispersal trends according to a host’s stem status (single or multi-stemmed), vertical …

An Evaluation Of Bovine Reproductive Function From The Microrna Expression In The Female To Performance Testing In The Male, Erin Amiss

All Theses

Reproductive function is crucial to the success of a beef or dairy herd. Both the female and male play significant roles in the outcome of bovine reproduction. The bull contributes to reproductive success in many ways, such as genetics. The initial role that the bull has in reproductive success is fertilization, whether natural or by artificial insemination. One method of assessing bull performance are central bull test stations, which are traditionally administered by a university, extension center, or are privately owned. Central bull tests assess the performance of bulls from various management systems, breeds, and ages. Some measurements taken during …

The Serbian Orthodox Church As A Transnational Political Actor: A Case Study Of Regime Change In Montenegro, Dunja Arandjelovic

All Theses

Although many scholars have considered how religious institutions can affect democratic change, little attention has been given to the contemporary transnational potential of a church with a distinctively national identity. This study will explore the capacity of national churches to act transnationally by analyzing the Serbian Orthodox Church’s (SOC) recent political intervention in Montenegro, during which the church mobilized almost half of the Montenegrin population during the COVID pandemic in a movement that led to the defeat of Montenegro’s president in parliamentary elections for the first time in 30 years. My project is based on in-depth elite interviews with ten …

Transforming Character Faces Based On Perceived Personality Traits, Kara Porter

All Theses

The ability to read other human's faces is a crucial part of everyday life. Subconsciously, the human brain analyzes someone's face within the first few seconds of seeing it, making a variety of conclusions ~\cite{FacePerp} such as gathering information about emotional state and assuming character traits this person might possess. The purpose of this thesis is to create a tool that allows a user to alter features of a character's three dimensional (3D) face mesh to look increasingly or decreasingly like the character possesses certain personality traits. Using a sample set of randomly generated faces, a survey is conducted to …

Iron Phosphate Glass For The Immobilization Of Dehalogenated Salt Waste, Matthew Aaron Page

All Theses

Electrochemical reprocessing can be used to recycle presently stored nuclear fuel and consists of dissolving that used fuel in molten salt and the waste produced from these processes is a small amount of a high-level salt waste. Vitrification has been selected as the primary means of safely disposing high and low level radioactive waste. This is due to glass’ ability to incorporate many elements within its matrix, and it is chemically durable with the addition of network formers and other glass forming chemicals. With over 90,000 tonnes of nuclear waste in the United States, the avoidance of additional steps required …

Mysteerio: Multi-Regional Environmentally Extended Input-Output Model For United States, Yash Srivastava

All Theses

This research work titled My State Environmentally Extended Regional Input-Output (MYSTEERIO) is based on the concept of multi-regional environmentally extended input-output (MREEIO), which is a combination of lifecycle thinking and economics principles. Numerous studies have highlighted the advantages of using this methodology to determine the environmental impacts associated with economic activities for a region. However, no prior attempt has been made to conduct a state-level analysis for the US. This research work thus tries to estimate the impacts embodied due to the consumption of goods and services at the state level by using the MREEIO principles. Extensive coverage of the …

Aiii Sài Gòn Hông?, Jackie Ta, Ngoc Uyen Phuong Ta

All Theses

“Aiii Sài Gòn Hông?”

In Saigon, “Ai… hông?” is a phrase that street vendors often shout to advertise what they sell for the day. This body of work, “Aiii Sài Gòn Hông?” (Translates: “Saigon, anyone?”) invites the audience to take a glimpse into the vivid everyday life in contemporary Vietnam through a perspective of a Saigon local. Utilizing the modalities of painting and sculpture, I collect, accumulate and organize parts of the streets and marketplace by manipulating and amplifying certain key visual elements. The goal of the work is to reconstruct an experiential space that speaks not only to the …

A Study On The Environmental And Societal Impact Of Salad Packaging, Nathanael Stephens

All Theses

Packaged salads are becoming an increasingly popular segment of today’s fresh cut vegetables and salads market. This increased demand is leading to an increased need for packaging. This increase in packaging can lead to a potential increase in impact on the environment. With a large push for sustainability in the modern economy, this environmental impact is becoming more and more unacceptable. Several studies have been conducted to determine environmental impacts of packaging, but none have homed in on the salad packaging market segment in detail until this study. This study is also pioneering the way by pairing environmental impacts of …

To Be A Cloud, Huan Laplante

All Theses

The intersections between Buddhism, queerness, and art making support one another in their power to unveil the impermanent nature of the self. My work rests at these moments, taking refuge in the ability to simultaneously release and rebuild a sense of self that exists beyond the boundaries of individualism. To Be a Cloud documents my journey of looking into the origins of the self and reflecting upon the transience of body and mind. Utilizing a broad range of sensuous materials such as textiles, handmade paper, and charcoal, paired with the repetitive motions of stitching, tearing, and mark-making cultivate a rhythmic …

Large Genomes Assembly Using Mapreduce Framework, Yuehua Zhang

All Dissertations

Knowing the genome sequence of an organism is the essential step toward understanding its genomic and genetic characteristics. Currently, whole genome shotgun (WGS) sequencing is the most widely used genome sequencing technique to determine the entire DNA sequence of an organism. Recent advances in next-generation sequencing (NGS) techniques have enabled biologists to generate large DNA sequences in a high-throughput and low-cost way. However, the assembly of NGS reads faces significant challenges due to short reads and an enormously high volume of data. Despite recent progress in genome assembly, current NGS assemblers cannot generate high-quality results or efficiently handle large genomes …

Scalable Data-Driven Predictive Modeling And Analytics For Cho Process Development Optimization, Sarah Mbiki

All Dissertations

In 1982, the FDA approved the first recombinant therapeutic protein, and since then, the biopharmaceutical industry has continued to develop innovative and highly effective biological drugs for various illnesses¹. These drugs are produced using host organisms that are modified to hold the genetic encoding of the targeted protein¹. Of the many host organisms, Chinese hamster ovary (CHO) cells are often used due to capability to perform posttranslational modification (PTM): which allows human-like synthesis of proteins unlikely to invoke immunogenicity in humans ^1,2.

Despite all the positive attributes, many challenges are associated with CHO cell cultures, …