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Antarctic Moss Biflavonoids Show High Antioxidant And Ultraviolet-Screening Activity, Melinda J. Waterman, Ari Satia Nugraha, Rudi Hendra, Graham E Ball, Sharon A. Robinson, Paul A. Keller

Faculty of Science, Medicine and Health - Papers: part A

Ceratodon purpureus is a cosmopolitan moss that survives some of the harshest places on Earth: from frozen Antarctica to hot South Australian deserts. In a study on the survival mechanisms of the species, nine compounds were isolated from Australian and Antarctic C. purpureus. This included five biflavonoids, with complete structural elucidation of 1 and 2 reported here for the first time, as well as an additional four known phenolic compounds. Dispersion-corrected DFT calculations suggested a rotational barrier, leading to atropisomerism, resulting in the presence of diastereomers for compound 2. All isolates absorbed strongly in the ultraviolet (UV) spectrum, e.g., biflavone …