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Two-Photon Excitation Of Cesium Alkali Metal Vapor 72D, 82D Kinetics And Spectroscopy, Ricardo C. Davila

Theses and Dissertations

Pulsed excitation on the two-photon Cs 6²S_½ → 7²D_3/2,5/2 transition results in time-resolved fluorescence at 697 nm and 672 nm. The rates for fine structure mixing between the 7²D_3/2,5/2 states have been measured for helium and argon rare gas collision partners. The mixing rates are very fast, 1.26 ± 0.05 x 10^-9 cm³/(atom sec) for He and 1.52 ± 0.05 x 10^-10 cm³ /(atom sec) for Ar, driven by the small energy splitting and large radial distribution for the valence electron. …