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Engineering Physics Commons

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Theses and Dissertations

2018

Photoemission spectroscopy

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Electrical Characterization Of Crystalline Uo2, Tho2 And U0.71Th0.29O2, Christina L. Dugan Dec 2018

Electrical Characterization Of Crystalline Uo2, Tho2 And U0.71Th0.29O2, Christina L. Dugan

Theses and Dissertations

Uranium dioxide (UO2), thorium dioxide (ThO2), and UxTh1-xO2 alloys are characterized for suitability in uranium-based neutron detectors. ThO2 was studied for an envisioned UO2/ThO2 heterojunction. A U0.71Th0.29O2 alloy was studied because of its resistance to oxidation and potential use in surface passivation. The U0.71Th0.29O2 effective Debye temperature of 217± 24 K was measured using temperature-dependent x-ray photoemission spectroscopy (XPS). The specific heat capacity for the U0.71Th0.29O2 alloy was calculated from the Debye …