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Engineering Physics Commons

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Doctoral Dissertations

University of Massachusetts Amherst

Thin film

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Full-Text Articles in Engineering Physics

Reducing The Size Sale Of The Block Copolymer Microdomains And Morphology Study Of Brush Block Copolymers Containing Homopolymer, Gajin Jeong Mar 2017

Reducing The Size Sale Of The Block Copolymer Microdomains And Morphology Study Of Brush Block Copolymers Containing Homopolymer, Gajin Jeong

Doctoral Dissertations

Block copolymers (BCPs), due to their ability to self-assemble into periodic nanoscale morphologies, have been extensively studied over the past few decades. The thermodynamic parameters governing self-assembly of BCPs generally leads to periodic morphologies with characteristic length scales ranging from 10 to 100 nm. Several applications have been demonstrated utilizing BCPs as a template for the fabrication of nanostructured materials. Fabricating structures beyond the 10-100 nm range, remains a challenge and constitutes one of the goals of the proposed research. This dissertation is divided into two parts. The first focuses on the sub 10 nm length scale, when by chemically …


Magnetic Transport Properties Of Oriented Soft, Hard And Exchange-Coupled Magnetic Thin Films And Au25(Sc6H13)18 Spherical Nanocluster, Rukshan M. Thantirige Aug 2015

Magnetic Transport Properties Of Oriented Soft, Hard And Exchange-Coupled Magnetic Thin Films And Au25(Sc6H13)18 Spherical Nanocluster, Rukshan M. Thantirige

Doctoral Dissertations

This study was conducted with the aim of improving permanent magnetic properties of existing materials and exploring non-conventional ferromagnetic properties of gold-based nanoclusters. The first chapter of this dissertation gives an introduction to relevant fundamental concepts and proceeding chapters present findings of three projects. In the first project, shape anisotropy induced permanent magnetism in oriented magnetic thin films was investigated. Roll-to-roll nanoimprinting, a high-throughput fabrication method was utilized to fabricate densely packed Fe nanostripe-based magnetic thin films that exhibit large in-plane uniaxial anisotropy and nearly square hysteresis loops at room temperature. (BH)max exceeds 3 MGOe for samples of intermediate …